CHAPTER 6 COVALENT COMPOUNDS 6 1 Covalent Compounds
- Slides: 70
CHAPTER 6: COVALENT COMPOUNDS
6. 1 Covalent Compounds
What is a covalent bond? • Sharing of electrons between atoms • Electron orbitals overlap to form molecular orbitals • Molecular orbitals are the region where the shared electrons move • Covalent bonds are also called molecular bonds.
How is a molecular bond different from an ionic bond? • Ionic Bond: Transfer of electrons • Covalent or Molecular Bond: Sharing of electrons
Bond Length • Average distance between nuclei of two atoms • Not Fixed: atoms vibrate; bond acts like a spring
Bond Energy • Energy needed to break a bond • As bond energy goes up, bond length goes down (inverse relationship) H Br 141. 1 pm Bond energy = 366 k. J/mol H F 91. 7 pm Bond energy = 570
Bond Type Electron Bond s Length Shared Single 2 Long Double 4 Triple 6 Short Bond Energy Low High
Electronegativity • Difference in electronegativities can be used to determine bond type
Predicting Bond Type from Electronegativity Difference • Nonpolar Covalent: Electronegativity Difference < 0. 5 • Polar Covalent: Electronegativity Difference ≥ 0. 5 and ≤ 2. 1 • Ionic: Electronegativity Difference > 2. 1
Types of Covalent Bonds 1. Nonpolar Covalent Bond • Bonding electrons shared evenly • Difference in electronegativity is less than 0. 5 • Examples: C–H H–H
Types of Covalent Bonds 2. Polar Covalent Bond • Bonding electrons not shared evenly • Difference in electronegativity is 0. 5 to 2. 1 • Tend to be stronger than nonpolar covalent bonds • Electrons tend to be closer to more electronegative atoms • Example: H – F
Polar Covalent Bonds • Polar covalent bonds have a dipole. • Dipole: one end has a partial positive charge and the other end has a partial negative charge. • δ+ is used to indicate a partial positive charge • δ- is used to indicate a partial negative charge • Examples:
Ionic Bonds • Metal + Nonmetal • Electronegativity difference is greater than 2. 1 • Example: Li – F
Summary • Nonpolar Covalent: Electronegativity Difference < 0. 5 • Polar Covalent: Electronegativity Difference ≥ 0. 5 and ≤ 2. 1 • Ionic: Electronegativity Difference > 2. 1
Determine if the following compounds are ionic, polar covalent, or nonpolar covalent: 1. Na – F 2. Ca – O 3. C – Cl 4. Al – Cl 5. Br – Br
Determine if the following compounds are ionic, polar covalent, or nonpolar covalent: 1. 2. 3. 4. 5. Na – F = ionic (electronegativity difference = 3. 1) Ca – O = ionic (electronegativity difference = 2. 4) C– Cl = polar covalent (electronegativity difference = 0. 6) Al – Cl = polar covalent (electronegativity difference = 1. 6) Br – Br = nonpolar covalent (electronegativity difference = 0)
Properties of Covalent Compounds 1. 2. 3. 4. 5. Low melting and boiling points Soft and squishy Tend to be flammable Do NOT conduct electricity in water Are NOT very soluble in water
6. 2 Drawing Covalent Compounds: Lewis Structures
Gilbert N. Lewis (1875 – 1946) • Gilbert N. Lewis created Lewis structures • Lewis structures (electron-dot diagrams) • Structural formula for drawing molecules • Dots = electrons • Lines = electron pairs/bonds • Only valence electrons are shown
Lewis Structures • These are examples of Lewis structures H Be C O
1. Lewis Structures of Atoms • A Lewis diagram consists of the element symbol in the center and dots going around it representing the valance electrons. • The dots representing the valance electrons must be evenly distributed around all 4 sides of the symbol. • Group 2 elements and Helium are the exception to the rule of even distribution.
• When placing dots around the element symbol, you should start on the left side and go clock wise until you run out of electrons. • Nitrogen has 5 Valence electrons N N N
Practice Questions Draw a dot diagram of the following elements: • Potassium • Boron • Chlorine • Neon • Lead • Oxygen
K Pb B Cl Ne O
Group 2 and Helium -Group 2 and Helium are the exceptions because their valence electrons are in the first shell. -Therefore the 2 valence electrons for Helium and Group 2 elements need to be put on the same side of the element symbol. He
Why do Lewis structures help us? • These diagrams allow us to understand how atoms will bind based on their valance electron configuration.
Bonding of atoms • When you have unpaired electrons on a side of an atom that atom will want to bond/share electrons with other atoms • This is because all atoms want a full valance shell • Oxygen has two unpaired electrons • Hydrogen has one free electron so 2 H can bond with O, this make H O 2 O H H
2. Drawing Lewis Structures of Compounds • Step 1: Count the total number of valence electrons in the compound. Example: CH 3 I
• Step 2: Draw a Lewis structure for each atom in the compound. Example: CH 3 I 14 valence electrons
• Step 3: Arrange the atoms • Halogen and Hydrogen atoms often bond to only 1 other atom and are usually at the end of the molecule • Carbon is often in the center of the molecule • With the exception of carbon, the atom with the lowest electronegativity is often the central atom Example: CH 3 I 14 valence electrons
• Step 4: Distribute the dots • Distribute the electron dots so that each atom (except H, Be, and B) satisfy the octet rule Example: CH 3 I 14 valence electrons
• Step 5: Draw the bonds • Change each pair of dots that represent a shared pair of electrons to a long dash. Example: CH 3 I 14 valence electrons
• Step 6: Verify the structure • Count the electrons in your structure
Practice 1. ) H 2 S 2. ) NH 3 3. ) BF 3
More Practice 4. ) C 2 H 6 5. ) CH 2 Cl 2 6. ) CH 3 OH 7. ) SCl 2 8. ) CHF 3
3. Lewis Structures with Polyatomic Ions
More Practice
3. Lewis Structures of Compounds with Multiple Bonds C, O, N often form double bonds by sharing 2 pairs of electrons. C, N may even form triple bonds by sharing 3 pairs of electrons.
Practice 1. ) O 2 2. ) C 2 H 4 3. ) CO 2 4. ) N 2
More Practice 5. ) CO 6. ) C 2 H 2 7. ) HCN 8. ) HC 2 Cl 9. ) N 2 F 2
4. Resonance Structures -When a molecule has two or more possible Lewis structures, the two structures are called resonance structures. -Place double-headed arrows between the structure to show that the actual molecule is an average of the two possible states.
Practice 1. ) SO 2 2. ) O 3 3. ) NO 2 -
6. 3 Naming Covalent Molecules
WRITING FORMULAS Covalent Compounds
Covalent Compounds • Formed from 2 nonmetals or 1 metalloid and 1 nonmetal.
Prefix Mono Di Tri Tetra Penta Hexa Hepta Octa Nona Deca Number of Atoms 1 2 3 4 5 6 7 8 9 10
Writing Formulas for Covalent Compounds 1. Write the symbol for the cation. 2. From the prefix, write the number of atoms as a subscript behind the symbol. 3. Write the symbol of the anion. 4. From the prefix, write the number of atoms as a subscript behind the symbol. 5. DO NOT use charges.
Examples 1. Carbon Monoxide = CO 2. Tetraphosphorus decaoxide = P 4 O 10 3. Carbon dioxide 4. Sulfur dioxide
Examples 1. Carbon Monoxide = CO 2. Tetraphosphorus decoxide = P 4 O 10 3. Carbon dioxide = CO 2 4. Sulfur dioxide = SO 2
NAMING COMPOUNDS Covalent Compounds
Covalent Compounds • Formed from a metalloid and a nonmetal or two nonmetals.
Prefix Mono Di Tri Tetra Penta Hexa Hepta Octa Nona Deca Number of Atoms 1 2 3 4 5 6 7 8 9 10
1. Use prefixes: mono, di, tri, tetra, penta, hexa, hepta, octa, nona, and deca. 2. Add a prefix to the cation (from the number of atoms). Exception: the prefix mono is not added to the cation. 4. Add a prefix to the anion (from the number of atoms). 5. Change the ending of the anion to –ide.
Examples 1. P 4 S 10 = tetraphosphorus decasulfide 2. N 2 O = dinitrogen monoxide 3. P 2 O 3 4. IF 5
Examples 1. P 4 S 10 = tetraphosphorus decasulfide 2. N 2 O = dinitrogen monoxide 3. P 2 O 3 = diphosphorus trioxide 4. IF 5 = iodine pentafluoride
6. 4 Molecular Shapes: VSEPR • Objective: 1. To predict the shape of a molecule using VSEPR theory.
VSEPR • V • S • E • P • R Valence Shell Electron Pair Repulsion • VSEPR: theory that predicts some molecular shapes based on the idea that pairs of valence electrons surrounding an atom repel each other
How do we figure out the shape of a molecule? • The shape of a molecule is determined by the valence electrons surrounding the central atom.
The Molecular Shapes… Tetrahedral Bent Trigonal Pyramidal Linear Trigonal Planar
Examples
How do we determine the molecular shape? Step 1: Draw the Lewis structure for the molecule. Example: NH 3
Step 2: Count the number of “things” on the atom you’re interested in (the center atom) • Count atoms and lone pairs, NOT BONDS! Example: NH 3 three atoms one lone pair +________ 4 total “things”
Step 3: Count the number of lone pairs that are on the atom you’re interested in. • Lone pairs on other atoms aren’t important; only count what is directly stuck to the atom you’re interested in. Example: NH 3 one lone pair
VSEPR Flowchart
Practice 1. ) CH 4 2. ) CO 2 3. ) carbon tetrabromide 4. ) phosphorus trichloride 5. ) boron trichloride 6. ) sulfur difluoride
Practice 1. ) CH 4 tetrahedral 2. ) CO 2 linear 3. ) carbon tetrabromide: tetrahedral 4. ) phosphorus trichloride: trigonal pyramidal 5. ) boron trichloride: trigonal planar 6. ) sulfur difluoride: bent
Polarity • A molecule is polar if it has an overall dipole.
How does shape affect polarity? • Examples: • CO 2: linear • No molecular dipole: Not Polar • H 2 O: bent • Molecular dipole: Polar
Are the following molecules polar or nonpolar? 1. ) CF 4 2. ) SF 2 3. ) NF 3 4. ) Be. Cl 2
Are the following molecules polar or nonpolar? 1. ) CF 4 Nonpolar 2. ) SF 2 Polar 3. ) NF 3 Polar 4. ) Be. Cl 2 Nonpolar
- Ionic covalent and metallic bonding
- Electronegativity trend
- How many single covalent bonds can halogens form?
- Covalent molecular and covalent network
- Water is polar or nonpolar
- Covalent molecular and covalent network
- Silicon carbide covalent network
- Silicon carbide covalent bond
- Covalent bond hydrogen and chlorine
- Covalent vs coordinate covalent
- Is co a covalent bond
- Nature of covalent bonds
- Bonding and chemical formulas
- Physical state of covalent compounds
- Covalent bond
- Naming covalent compounds
- Covalent compound formula phosphorus pentafluoride
- Chemical formula covalent compounds
- Ionic vs covalent compounds
- What is the difference between molecule and compound
- How to name covalent compounds
- Characteristics of covalent bond
- Is mgs a binary molecular compound
- Covalent compound
- How to name covalent compounds
- Pentaboron nonahydride formula
- Carbon tetrabromide ionic or covalent
- Covalent compound hi
- Covalent salt
- Naming binary covalent compounds
- Is o2ionic or covalent
- Ionic compounds properties
- Chemistry chapter 7 ionic and metallic bonding
- Chapter 9 covalent bonding
- Compound vs molecule
- Ionic covalent names chapter 9
- Chapter 8 covalent bonding
- Chapter 8 covalent bonding
- Chapter 9 covalent bonding
- Chapter 9 covalent bonding
- Chapter 7 chemical formulas and chemical compounds test
- Trinitrogen monosulfide formula
- Ionic compounds and metals chapter 7
- Chapter 6 chemistry in biology
- Chapter 7 ionic compounds and metals assessment answer key
- Chapter 6 section 1 atoms elements and compounds
- Chapter 8 ionic compounds
- How do covalent bonds form
- Different types of chemical bonds
- Carbon covalent bonds
- Polar covalent bond in water molecule
- What is a covalent molecular substance
- Chemical bonding concept map
- Trinitrogen pentaiodide
- Difference between covalent bond and ionic bond
- Covalent bond naming
- Lewis dot structure ionic vs covalent
- Biochemical process
- Ionic covalent and metallic venn diagram
- Covalent bond vs hydrogen bond which is stronger
- Intermolecular force of attraction
- Lewis dot structure ionic vs covalent
- Covalent bond of ethanol
- Is potassium nitride ionic or covalent
- What is covalent catalysis
- What is covalent catalysis
- What is covalent catalysis
- Ionic covalent and metallic bonds
- Nnn lewis structure
- Dative covalent bond carbon monoxide
- Why do atoms want to bond