Chemistry 142 Chapter 21 Organic Chemistry Outline I
- Slides: 63
Chemistry 142 Chapter 21: Organic Chemistry Outline I. Hydrocarbons A. Alkanes B. Alkenes C. Alkynes D. Aromatics E. Reactions II. Functions Groups A. Alcohols B. Aldehydes C. Ketones D. Carboxylic Acids E. Esters F. Ethers G. Amines H. Amides III. Polymers
Friedrich Wöhler
What are some common elements in organic compounds? 24. 1
What are some bond energies and reactivities? Tro, Chemistry: A Molecular Approach 4
How do polymers form? H H H C C Cl H Head H Tail Head Tail H H C C H Cl Cl Tail Head-to-Tail H Head-to-Head, Tail-to-Tail 7
Classification of Hydrocarbons 24. 1
Uses of Hydrocarbons Number of C atoms 1 -4 5 -7 6 -18 12 -24 18 -50 50+50+ State gas Major Uses heating andand cooking fuel solvents, liquids, solvents, gasoline (low boiling) gasoline liquids gasoline fuel; camp jetjetfuel; stove fuel diesel fuel, liquids, lubricants, (high boiling) heating oil petroleum jelly, petroleum solids paraffin wax 9 liquids
Acetylene torch HCCH Parafin wax 20+ carbons Mineral Oil 17 -50 carbon
What is optical activity? Tro, Chemistry: A Molecular Approach 11
Representing Organic Compounds • Molecular Formula - C 4 H 10 • Complete structural formula – • Condensed structural formula – • Line formula -
What are some simple cycloalkanes?
What is the structure of an organic halide? • Chloroform • Chlorobenzene • Carbon Tetrachloride
What makes a hydrocarbon unsaturated? Ethene used to ripen fruit.
Cis-Trans Isomerization in the Vision Process 24. 2
Addition reaction of bromine with alkenes
Addition Polymerization initiator H H C H H etc. C initiator Cl H H C C Cl H H H C C + Cl H H H C C • Cl H H H + H C C Cl H H H C Cl H C H H H C C • Cl H H H H C C C • Cl H
Polymers of Alkenes n CH 2=CH 2 ---> -[CH 2]-n
Where do we find polymers?
What do the symbols on plastics tell us about their chemical formulas?
What is the difference between low and high density polyethylene?
Aromatic Hydrocarbons H H H H C C C H H H 24. 3
What consumer products contain a benzene ring?
Aromatic Compound Nomenclature CH 2 CH 3 Cl NH 2 ethylbenzene chlorobenzene aminobenzene Br 1 6 2 5 3 4 NO 2 nitrobenzene Br Br Br 1, 2 -dibromobenzene ortho-dibromobenzene 1, 3 -dibromobenzene meta-dibromobenzene 1, 4 -dibromobenzene para-dibromobenzene 24. 3
Where aromatic compounds found?
Polycyclic Aromatic Hydrocarbons 24. 3
Polymers Containing Aromatic Rings
What is the structure of an alcohol? • Cyclohexanol • 1 -propanol
What is the structure of an ether? • 1, 4 -dioxane
Alcohols (R-OH) and Ethers (R-O-R) Methanol CH 3 OH (1 -methanol) Ethanol CH 3 CH 2 OH (1 -ethanol) 2 -propanol Dimethyl ether CH 3 OCH 3 Diethyl ether CH 3 CH 2 OCH 2 CH 3 Ethyl methyl ether CH 3 OCH 2 CH 3
Functional Groups Affect Physical Properties Molar Mass (g/mol) Bp (o. C) Solubility in Water (g/100 m. L at 20 o. C) 74 35 6. 9 72 36 0. 0038 74 117 7. 7 CH 3 CH 2 -O-CH 2 CH 3 Diethyl Ether CH 3 CH 2 CH 2 CH 3 n-Pentane CH 3 CH 2 CH 2 OH n-butanol
What is the structure of a phenol? • Phenol • Bisphenol-A, BPA
Where are compounds of phenols found?
Polymer of Alcohols and Ethers
Other Polymers
Carbonyl Groups
Alkene Aldehyde Alcohol Ether Amine
Carbonyl Group Tro, Chemistry: A Molecular Approach 50
What is the structure of an aldehyde? • ethanal
What is the structure of a ketone? • 2, 3 -butanedione • Raspberry ketone
Aldehydes and Ketones
Aldehydes (R-CO-H) and Ketones (R-CO-R) Methanal Ethanal Benzaldehyde 2 -Propanone 2 -Butanone
What is the structure of a carboxylic acid? • Hexanoic acid • Butanoic acid
What is the structure of an ester? • Methyl ethanoate • Octyl ethananoate
Carboxylic Acids (R-COOH) and Esters (R-COO-R) Methanoic acid Ethylbutanoate Ethanoic acid Ethylmethanoate
What is the structure of an amine? • 2 -propanamine • Methylamine
What is the structure of an amide? • ethanamide
Amines and Amides Aspartame (Nutra. Sweet)
Amines (R 2 -NH) and Amides (R-CO-NH 2) Triethylamine Methanamide Nicotine Ethanamide Propanamide
Amino Acids
How do organic functional groups compare? Functional Group Condensed Formula Hydrocarbon Suffix Major Intermolecular Force Polar when side chain is small? Boiling Point Water Soluble Similar to Cx. Hy London force Nonpolar Variable, based on molar mass Insoluble Organic Halide R-X Dipole Mostly nonpolar Low Insoluble Alcohol R-OH -ol Hydrogen Bonding Polar High Soluble Ether R-O-R -ether Dipole (hydrogen bond acceptor) Mostly nonpolar Low Insoluble Aldehyde R-CHO -al Dipole (hydrogen bond acceptor) Mostly nonpolar Lower than similar alcohols Not very soluble Ketone R-CO-R -one Dipole (hydrogen bond acceptor) Nonpolar unless ketone is small Lower than similar alcohols Not very soluble Carboxylic acid R-COOH -oic acid Hydrogen Bonding Polar High Soluble Ester R-COO-R -ester Dipole (hydrogen bond acceptor) Slightly polar Lower than similar alcohols Insoluble Amine R-NH 2 (1°) R 2 NH (2°) R 3 N (3°) -amine 1° hydrogen bonding 2° hydrogen bonding 3° Dipole (h-bond acceptor) Polar High Soluble Alcohols Amide R-CO-NH 2 (1°) R-CO-NHR (2°) R-CO-NR 2 (3°) -amide 1° hydrogen bonding 2° hydrogen bonding 3° Dipole (h-bond acceptor) Polar High Soluble Carboxylic acids Alcohols
Condensation Polymerization + HO HO + O O C C Tro, Chemistry: A Molecular Approach OH + HO O CH 2 65 CH 2 OH + H 2 O
Synthesis of Polyesters
What are some applications of PET fibers? Dacron, polyethylene terephthalate, PET, fiber. It is used in medicine to replace tissues because it is well tolerated by the body. Here, a Dacron patch is used to close a hole between the heart’s two upper chambers.
Synthesis of Polyamides
What is Kevlar?
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