Lecture 2 Chemical Reaction Engineering CRE is the
- Slides: 34
Lecture 2 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. 1
Chapter 2 Lecture 2 �Review of Lecture 1 �Definition of Conversion, X �Develop the Design Equations in terms of X �Size CSTRs and PFRs given –r. A= f(X) �Conversion for Reactors in Series �Review the Fall of the Tower of CRE 2
Review Lecture 1 Reactor Mole Balances Summary The GMBE applied to the four major reactor types (and the general reaction A B) Reactor Differential Algebraic Integral NA Batch t CSTR FA PFR V PBR 3 FA W
Review Lecture 1 CSTR – Example Problem Given the following information, Find V Liquid phase 4
Review Lecture 1 CSTR – Example Problem (1) Mole Balance: (2) Rate Law: (3) Stoichiometry: 5
Review Lecture 1 CSTR – Example Problem (4) Combine: (5) Evaluate: 6
Chapter 2 Define conversion, X Consider the generic reaction: Chose limiting reactant A as basis of calculation: Define conversion, X 7
Chapter 2 Batch 8
Chapter 2 Batch Integrating, The necessary t to achieve conversion X. 9
Chapter 2 CSTR Consider the generic reaction: Chose limiting reactant A as basis of calculation: Define conversion, X 10
Chapter 2 CSTR Steady State Well Mixed 11
Chapter 2 CSTR 12 CSTR volume necessary to achieve conversion X.
Chapter 2 PFR Steady State 13
Chapter 2 PFR Integrating, PFR volume necessary to achieve conversion X. 14
Reactor Mole Balances Summary Chapter 2 in terms of conversion, X Reactor Differential Algebraic Integral X Batch t CSTR PFR X PBR 15 W
Chapter 2 Levenspiel Plots Reactor Sizing Given –r. A as a function of conversion, -r. A= f(X), one can size any type of reactor. We do this by constructing a Levenspiel plot. Here we plot either (FA 0/-r. A) or (1/-r. A) as a function of X. For (FA 0/-r. A) vs. X, the volume of a CSTR and the volume of a PFR can be represented as the shaded areas in the Levenspiel Plots shown as: 16
Chapter 2 Levenspiel Plots 17
Chapter 2 CSTR Area = Volume of CSTR FA 0 -r. A X 1 � � 18
Chapter 2 PFR 19
Chapter 2 Levenspiel Plots 20
Numerical Evaluations of Integrals Chapter 2 �The integral to calculate the PFR volume can be evaluated using method as Simpson’s One-Third Rule: (See Appendix A. 4) 21 Other numerical methods are: �Trapezoidal Rule (uses two data points) �Simpson’s Three-Eight’s Rule (uses four data points) �Five-Point Quadrature Formula
Chapter 2 Reactors in Series Given: r. A as a function of conversion, one can also design any sequence of reactors in series by defining X: Only valid if there are no side streams. Molar Flow rate of species A at point i: 22
Chapter 2 Reactors in Series 23
Chapter 2 Reactors in Series Reactor 1: V 1 24
Chapter 2 Reactors in Series Reactor 2: V 2 25
Reactors in Series Reactor 3: V 3 26
Reactors in Series 27
Chapter 2 Reactors in Series Space time τ is the time necessary to process 1 reactor volume of fluid at entrance conditions. 28
Chapter 2 KEEPING UP �The tower of CRE, is it stable? 29
Algorithm Reaction Engineering Mole Balance Rate Laws Stoichiometry These topics build upon one another. 30
Algorithm Heat Effects Isothermal Design Stoichiometry Rate Laws Mole Balance CRE Algorithm 31
Algorithm Mole Balance Rate Laws Be careful not to cut corners on any of the CRE building blocks while learning this material! 32
Algorithm Heat Effects Isothermal Design Stoichiometry Rate Laws Mole Balance 33 Otherwise, your Algorithm becomes unstable.
End of Lecture 2 34
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