Alcohols Contain a hydroxyl OH group Intermolecular forces
![Alcohols • Contain a hydroxyl (-OH) group − + • Intermolecular forces: dipole-dipole, H-bonding Alcohols • Contain a hydroxyl (-OH) group − + • Intermolecular forces: dipole-dipole, H-bonding](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-1.jpg)
![Alcohol Nomenclature • Parent chain = longest chain containing C with -OH • Root Alcohol Nomenclature • Parent chain = longest chain containing C with -OH • Root](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-2.jpg)
![Alcohol Naming Practice 2 -propanol (isopropyl alcohol) 3, 5 -dimethyl-2, 4 -heptanediol 2, 4 Alcohol Naming Practice 2 -propanol (isopropyl alcohol) 3, 5 -dimethyl-2, 4 -heptanediol 2, 4](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-3.jpg)
![Classes of Alcohols 1 -butanol Primary (1°) alcohol OH C attached to 1 other Classes of Alcohols 1 -butanol Primary (1°) alcohol OH C attached to 1 other](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-4.jpg)
![Reactions of Alcohols Strong base • Reaction with strong bases alkoxide – alcohol as Reactions of Alcohols Strong base • Reaction with strong bases alkoxide – alcohol as](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-5.jpg)
![Dehydration Mechanism Step 1: electrophilic H+ catalyst attacks nucleophilic O atom Step 2: H Dehydration Mechanism Step 1: electrophilic H+ catalyst attacks nucleophilic O atom Step 2: H](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-6.jpg)
![Hydration and Dehydration H+ + H 2 O Hydration and dehydration are in equilibrium Hydration and Dehydration H+ + H 2 O Hydration and dehydration are in equilibrium](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-7.jpg)
![Possible Dehydration Products H+ ? Major product Least H’s on double bond The most-substituted Possible Dehydration Products H+ ? Major product Least H’s on double bond The most-substituted](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-8.jpg)
![Oxidation of Alcohols • Oxidation: increases oxidation number – More C-O bonds (add O) Oxidation of Alcohols • Oxidation: increases oxidation number – More C-O bonds (add O)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-9.jpg)
![Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid) Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-10.jpg)
![Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid) Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-11.jpg)
![Oxidation of Alcohols 0 2° alcohol 0 -2 +1 0 +1 -2 oxidizing agent Oxidation of Alcohols 0 2° alcohol 0 -2 +1 0 +1 -2 oxidizing agent](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-12.jpg)
![Naming aldehydes and ketones Parent chain = longest chain containing C=O (carbonyl) Aldehyde Ketone Naming aldehydes and ketones Parent chain = longest chain containing C=O (carbonyl) Aldehyde Ketone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-13.jpg)
![Naming Practice propanedial 2, 4 -pentanedione Aldehyde has priority Has both an aldehyde and Naming Practice propanedial 2, 4 -pentanedione Aldehyde has priority Has both an aldehyde and](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-14.jpg)
![Condensation of Alcohols Condensation reaction: two molecules combine to form a larger molecule (+ Condensation of Alcohols Condensation reaction: two molecules combine to form a larger molecule (+](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-15.jpg)
![Ethers − water H-bond acceptor No H-bond donor alcohol Two alkyl groups (C’s) bound Ethers − water H-bond acceptor No H-bond donor alcohol Two alkyl groups (C’s) bound](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-16.jpg)
![Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-17.jpg)
![Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-18.jpg)
![Reactions of Ethers • Formation of peroxides + peroxide O 2 diisopropyl ether • Reactions of Ethers • Formation of peroxides + peroxide O 2 diisopropyl ether •](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-19.jpg)
![Aldehydes and Ketones 120° aldehyde C and O both sp 2 hybridized 120° ketone Aldehydes and Ketones 120° aldehyde C and O both sp 2 hybridized 120° ketone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-20.jpg)
![Structural Isomers • Draw all the possible structural isomers for the following formulas: C Structural Isomers • Draw all the possible structural isomers for the following formulas: C](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-21.jpg)
![C 4 H 10 O Isomers 1 -butanol 2 -methyl-2 -propanol diethyl ether 2 C 4 H 10 O Isomers 1 -butanol 2 -methyl-2 -propanol diethyl ether 2](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-22.jpg)
![C 5 H 12 O Isomers 1 -pentanol 2 -methyl-1 -butanol 2 -pentanol 3 C 5 H 12 O Isomers 1 -pentanol 2 -methyl-1 -butanol 2 -pentanol 3](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-23.jpg)
![C 5 H 12 O Isomers butyl methyl ether isobutyl methyl ether tert-butyl methyl C 5 H 12 O Isomers butyl methyl ether isobutyl methyl ether tert-butyl methyl](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-24.jpg)
![C 4 H 8 O Isomers butanal 2 -butanone 2 -methylpropanal C 4 H 8 O Isomers butanal 2 -butanone 2 -methylpropanal](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-25.jpg)
![C 5 H 10 O Isomers pentanal 3 -methylbutanal 2, 2 -dimethylpropanal 2 -pentanone C 5 H 10 O Isomers pentanal 3 -methylbutanal 2, 2 -dimethylpropanal 2 -pentanone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-26.jpg)
![Reactions of Aldehydes and Ketones • Oxidation of aldehydes to carboxylic acids – Cr. Reactions of Aldehydes and Ketones • Oxidation of aldehydes to carboxylic acids – Cr.](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-27.jpg)
![Reduction of Aldehydes/Ketones Li. Al. H 4 3 -oxopentanal 1, 3 -pentanediol Na. BH Reduction of Aldehydes/Ketones Li. Al. H 4 3 -oxopentanal 1, 3 -pentanediol Na. BH](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-28.jpg)
![Carboxylic Acid Nomenclature • Parent chain: longest containing carboxyl group (COOH) • Name of Carboxylic Acid Nomenclature • Parent chain: longest containing carboxyl group (COOH) • Name of](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-29.jpg)
![aspirin Tylenol Can irritate your stomach Gentle on the stomach A carboxylic acid Just aspirin Tylenol Can irritate your stomach Gentle on the stomach A carboxylic acid Just](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-30.jpg)
![Carboxylic Acid Reactions • Reduction to 1° alcohols – Only Li. Al. H 4 Carboxylic Acid Reactions • Reduction to 1° alcohols – Only Li. Al. H 4](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-31.jpg)
![What are the products? 3 -oxo-4 -pentenoic acid H 2/Pt Na. BH 4 Li. What are the products? 3 -oxo-4 -pentenoic acid H 2/Pt Na. BH 4 Li.](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-32.jpg)
- Slides: 32
![Alcohols Contain a hydroxyl OH group Intermolecular forces dipoledipole Hbonding Alcohols • Contain a hydroxyl (-OH) group − + • Intermolecular forces: dipole-dipole, H-bonding](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-1.jpg)
Alcohols • Contain a hydroxyl (-OH) group − + • Intermolecular forces: dipole-dipole, H-bonding • H-bonds between alcohol molecules: high boiling points • H-bonds with water: up to 4 -carbon alcohols soluble in water • -OH group can act as a weak base or a weak acid + Strong base alkoxide alcohol oxonium ion
![Alcohol Nomenclature Parent chain longest chain containing C with OH Root Alcohol Nomenclature • Parent chain = longest chain containing C with -OH • Root](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-2.jpg)
Alcohol Nomenclature • Parent chain = longest chain containing C with -OH • Root name: replace –e with –ol • ethane ethanol, butene butenol, etc. • Give –OH the smallest possible number • –OH has priority over double bonds, alkyl groups • Two –OH groups -diol; three –OH groups -triol – Add to end of root name (propane propanediol) 5 -methyl-3 -hexanol 1, 2 -ethanediol (ethylene glycol) antifreeze
![Alcohol Naming Practice 2 propanol isopropyl alcohol 3 5 dimethyl2 4 heptanediol 2 4 Alcohol Naming Practice 2 -propanol (isopropyl alcohol) 3, 5 -dimethyl-2, 4 -heptanediol 2, 4](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-3.jpg)
Alcohol Naming Practice 2 -propanol (isopropyl alcohol) 3, 5 -dimethyl-2, 4 -heptanediol 2, 4 -dimethyl-3 -pentanol 4 -penten-2 -ol
![Classes of Alcohols 1 butanol Primary 1 alcohol OH C attached to 1 other Classes of Alcohols 1 -butanol Primary (1°) alcohol OH C attached to 1 other](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-4.jpg)
Classes of Alcohols 1 -butanol Primary (1°) alcohol OH C attached to 1 other C Secondary (2°) alcohol OH C attached to 2 other C’s 4 -phenyl-2 -hexanol Tertiary (3°) alcohol OH C attached to 3 other C’s 1 -methylcyclohexanol
![Reactions of Alcohols Strong base Reaction with strong bases alkoxide alcohol as Reactions of Alcohols Strong base • Reaction with strong bases alkoxide – alcohol as](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-5.jpg)
Reactions of Alcohols Strong base • Reaction with strong bases alkoxide – alcohol as proton donor (weak acid) Strong acid • Reaction with strong acids – alcohol as proton acceptor (weak base) • Dehydration oxonium ion H+ - H 2 O – reverse of hydration of alkenes – requires H+ catalyst • Oxidation – increase # of C-O bonds alkene oxidizing agent or aldehyde ketone
![Dehydration Mechanism Step 1 electrophilic H catalyst attacks nucleophilic O atom Step 2 H Dehydration Mechanism Step 1: electrophilic H+ catalyst attacks nucleophilic O atom Step 2: H](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-6.jpg)
Dehydration Mechanism Step 1: electrophilic H+ catalyst attacks nucleophilic O atom Step 2: H 2 O dissociates, leaving behind a carbocation + H 2 O Step 3: Electrons from neighboring C-H bond form bond, regenerating H+ catalyst +
![Hydration and Dehydration H H 2 O Hydration and dehydration are in equilibrium Hydration and Dehydration H+ + H 2 O Hydration and dehydration are in equilibrium](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-7.jpg)
Hydration and Dehydration H+ + H 2 O Hydration and dehydration are in equilibrium Can change [H 2 O] to favor one reaction or the other Change Favors Increase [H 2 O] Formation of Alcohol (hydration) Decrease [H 2 O] Formation of Alkene (dehydration)
![Possible Dehydration Products H Major product Least Hs on double bond The mostsubstituted Possible Dehydration Products H+ ? Major product Least H’s on double bond The most-substituted](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-8.jpg)
Possible Dehydration Products H+ ? Major product Least H’s on double bond The most-substituted alkene product is favored (most stable)
![Oxidation of Alcohols Oxidation increases oxidation number More CO bonds add O Oxidation of Alcohols • Oxidation: increases oxidation number – More C-O bonds (add O)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-9.jpg)
Oxidation of Alcohols • Oxidation: increases oxidation number – More C-O bonds (add O) or increases bond order – Fewer C-H bonds (remove H) • Needs an oxidizing agent – Cr. O 3, Cr 2 O 72 -, Mn. O 4 -, or PCC (pyridinium chlorochromate) PCC stops at aldehyde 1° alcohol +1 0 -1 -2 -2 +1 +1 oxidizing agent -2 +1 0 +1 aldehyde Cr. O 3 (Cr 6+) oxidizing agent Cr 3+ +3 0 -2 +1 carboxylic acid
![Breathalyzer Tests oxidized ethanol Cr 6 oxidized ethanal ethanoic acid acetaldehyde acetic acid Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-10.jpg)
Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid) + Cr 3+
![Breathalyzer Tests oxidized ethanol Cr 6 oxidized ethanal ethanoic acid acetaldehyde acetic acid Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid)](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-11.jpg)
Breathalyzer Tests oxidized ethanol + Cr 6+ oxidized ethanal ethanoic acid (acetaldehyde) (acetic acid) + Cr 3+ oxidized methanol oxidized methanal methanoic acid (formaldehyde) (formic acid)
![Oxidation of Alcohols 0 2 alcohol 0 2 1 0 1 2 oxidizing agent Oxidation of Alcohols 0 2° alcohol 0 -2 +1 0 +1 -2 oxidizing agent](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-12.jpg)
Oxidation of Alcohols 0 2° alcohol 0 -2 +1 0 +1 -2 oxidizing agent +2 0 0 ketone propanone 2 -propanol (acetone) 3° alcohol oxidizing agent No reaction
![Naming aldehydes and ketones Parent chain longest chain containing CO carbonyl Aldehyde Ketone Naming aldehydes and ketones Parent chain = longest chain containing C=O (carbonyl) Aldehyde Ketone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-13.jpg)
Naming aldehydes and ketones Parent chain = longest chain containing C=O (carbonyl) Aldehyde Ketone oxo Prefix –e becomes –al –e becomes –one Suffix Numbering C=O is always C #1 C=O is lowest possible number (don’t have to number it) (must number it) Naming Priority: Aldehydes > Ketones > Alcohols -OH (alcohol) substituent → “hydroxy” 3 -hydroxy-4 -methylpentanal 3 -chloro-2 -butanone
![Naming Practice propanedial 2 4 pentanedione Aldehyde has priority Has both an aldehyde and Naming Practice propanedial 2, 4 -pentanedione Aldehyde has priority Has both an aldehyde and](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-14.jpg)
Naming Practice propanedial 2, 4 -pentanedione Aldehyde has priority Has both an aldehyde and a ketone Ketone = oxo 3 -oxopentanal
![Condensation of Alcohols Condensation reaction two molecules combine to form a larger molecule Condensation of Alcohols Condensation reaction: two molecules combine to form a larger molecule (+](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-15.jpg)
Condensation of Alcohols Condensation reaction: two molecules combine to form a larger molecule (+ water) – Catalyzed by acid (H+) CH 3−OH + H-O−CH 3 alcohol + alcohol H 2 SO 4 catalyst CH 3−O−CH 3 + H 2 O ether + water
![Ethers water Hbond acceptor No Hbond donor alcohol Two alkyl groups Cs bound Ethers − water H-bond acceptor No H-bond donor alcohol Two alkyl groups (C’s) bound](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-16.jpg)
Ethers − water H-bond acceptor No H-bond donor alcohol Two alkyl groups (C’s) bound to oxygen • Intermolecular forces: – Dipole-dipole – No H-bonding between ether molecules • Lower boiling point than alcohols – Water or alcohols can H-bond to ether oxygen • Somewhat soluble in water and other polar solvents
![Naming Ethers Common names name both R groups add ether ethyl diethyl ether Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-17.jpg)
Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether (anesthetic)
![Naming Ethers Common names name both R groups add ether ethyl diethyl ether Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-18.jpg)
Naming Ethers • Common names: name both R groups, add “ether” ethyl diethyl ether (anesthetic) tert-butyl methyl ether (used as gasoline additive) tert-butyl methyl propyl people ether propyl ♫ “one-eyed, one-horned, flying. . . ” ♪
![Reactions of Ethers Formation of peroxides peroxide O 2 diisopropyl ether Reactions of Ethers • Formation of peroxides + peroxide O 2 diisopropyl ether •](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-19.jpg)
Reactions of Ethers • Formation of peroxides + peroxide O 2 diisopropyl ether • Reactions of peroxides: Explosive! diisopropyl ether peroxide Controlled detonation Resulting crater: 3 feet wide, one foot deep
![Aldehydes and Ketones 120 aldehyde C and O both sp 2 hybridized 120 ketone Aldehydes and Ketones 120° aldehyde C and O both sp 2 hybridized 120° ketone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-20.jpg)
Aldehydes and Ketones 120° aldehyde C and O both sp 2 hybridized 120° ketone • C=O group called a carbonyl group − Very polar C=O bond • Higher boiling point than alkanes + H-bond acceptor • Soluble in polar solvents No H-bond donor • Lower boiling point than alcohols
![Structural Isomers Draw all the possible structural isomers for the following formulas C Structural Isomers • Draw all the possible structural isomers for the following formulas: C](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-21.jpg)
Structural Isomers • Draw all the possible structural isomers for the following formulas: C 4 H 10 O C 5 H 12 O C 4 H 8 O C 5 H 10 O Alcohols and Ethers Aldehydes and Ketones (contain a double bond) Notice that all formulas contain one oxygen What functional groups do you know that contain one oxygen? Does the atom ratio of carbon to hydrogen make a difference?
![C 4 H 10 O Isomers 1 butanol 2 methyl2 propanol diethyl ether 2 C 4 H 10 O Isomers 1 -butanol 2 -methyl-2 -propanol diethyl ether 2](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-22.jpg)
C 4 H 10 O Isomers 1 -butanol 2 -methyl-2 -propanol diethyl ether 2 -methyl-1 -propanol methyl propyl ether isopropyl methyl ether
![C 5 H 12 O Isomers 1 pentanol 2 methyl1 butanol 2 pentanol 3 C 5 H 12 O Isomers 1 -pentanol 2 -methyl-1 -butanol 2 -pentanol 3](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-23.jpg)
C 5 H 12 O Isomers 1 -pentanol 2 -methyl-1 -butanol 2 -pentanol 3 -methyl-2 -butanol 2 -methyl-2 -butanol 3 -pentanol 3 -methyl-1 -butanol 2, 2 -dimethyl-1 -propanol
![C 5 H 12 O Isomers butyl methyl ether isobutyl methyl ether tertbutyl methyl C 5 H 12 O Isomers butyl methyl ether isobutyl methyl ether tert-butyl methyl](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-24.jpg)
C 5 H 12 O Isomers butyl methyl ether isobutyl methyl ether tert-butyl methyl ether sec-butyl methyl ether ethyl propyl ether ethyl isopropyl ether
![C 4 H 8 O Isomers butanal 2 butanone 2 methylpropanal C 4 H 8 O Isomers butanal 2 -butanone 2 -methylpropanal](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-25.jpg)
C 4 H 8 O Isomers butanal 2 -butanone 2 -methylpropanal
![C 5 H 10 O Isomers pentanal 3 methylbutanal 2 2 dimethylpropanal 2 pentanone C 5 H 10 O Isomers pentanal 3 -methylbutanal 2, 2 -dimethylpropanal 2 -pentanone](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-26.jpg)
C 5 H 10 O Isomers pentanal 3 -methylbutanal 2, 2 -dimethylpropanal 2 -pentanone 3 -methyl-2 -butanone 2 -methylbutanal
![Reactions of Aldehydes and Ketones Oxidation of aldehydes to carboxylic acids Cr Reactions of Aldehydes and Ketones • Oxidation of aldehydes to carboxylic acids – Cr.](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-27.jpg)
Reactions of Aldehydes and Ketones • Oxidation of aldehydes to carboxylic acids – Cr. O 3, Mn. O 4 - • Reduction of aldehydes and ketones to alcohols – Decrease C-O bonds, increase C-H bonds – Reducing agents: Li. Al. H 4, Na. BH 4, H 2/Pt Li. Al. H 4 propanal 1 -propanol CH 3−CH 2−OH CH 3−CH 2−CHO Na. BH 4 2 -methyl-3 -pentanone 2 -methyl-3 -pentanol
![Reduction of AldehydesKetones Li Al H 4 3 oxopentanal 1 3 pentanediol Na BH Reduction of Aldehydes/Ketones Li. Al. H 4 3 -oxopentanal 1, 3 -pentanediol Na. BH](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-28.jpg)
Reduction of Aldehydes/Ketones Li. Al. H 4 3 -oxopentanal 1, 3 -pentanediol Na. BH 4 cyclohexanol cyclohexanone H 2/Pt pentanedial 1, 5 -pentanediol
![Carboxylic Acid Nomenclature Parent chain longest containing carboxyl group COOH Name of Carboxylic Acid Nomenclature • Parent chain: longest containing carboxyl group (COOH) • Name of](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-29.jpg)
Carboxylic Acid Nomenclature • Parent chain: longest containing carboxyl group (COOH) • Name of parent: replace “–e” with “–oic acid” • Numbering starts at carboxyl carbon – Priority: Carboxylic acid > aldehydes > ketones > alcohols “hydroxy” “oxo” substituents 3 -oxobutanoic acid (diabetes) propanedioic acid (apples) trans-3 -methyl-2 -hexenoic acid (human armpits)
![aspirin Tylenol Can irritate your stomach Gentle on the stomach A carboxylic acid Just aspirin Tylenol Can irritate your stomach Gentle on the stomach A carboxylic acid Just](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-30.jpg)
aspirin Tylenol Can irritate your stomach Gentle on the stomach A carboxylic acid Just an alcohol
![Carboxylic Acid Reactions Reduction to 1 alcohols Only Li Al H 4 Carboxylic Acid Reactions • Reduction to 1° alcohols – Only Li. Al. H 4](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-31.jpg)
Carboxylic Acid Reactions • Reduction to 1° alcohols – Only Li. Al. H 4 reduces carboxylic acids (not Na. BH 4 or H 2/Pt) butanoic acid Li. Al. H 4 1 -butanol Na. BH 4 or H 2/Pt NO RXN Reactant remains unchanged
![What are the products 3 oxo4 pentenoic acid H 2Pt Na BH 4 Li What are the products? 3 -oxo-4 -pentenoic acid H 2/Pt Na. BH 4 Li.](https://slidetodoc.com/presentation_image_h/8a2cde61921493b1bf9577fe062c506b/image-32.jpg)
What are the products? 3 -oxo-4 -pentenoic acid H 2/Pt Na. BH 4 Li. Al. H 4 3 -hydroxypentanoic acid 3 -hydroxy-4 -pentenoic acid 4 -pentene-1, 3 -diol
Alcohol and hbr
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Imf
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Intermolecular forces
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Intermolecular and intramolecular forces
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