ESH RSL Factory Summit 08 ESH ENVIRONMENT SAFETY

ESH / RSL Factory Summit 08 ESH ENVIRONMENT SAFETY HEALTH RSL Sittichoke Huckuntod, Health and Safety Manager Environment, Health and Safety LS&CO RESTRICTED SUBSTANCE LIST

ESH / RSL Factory Summit 08 Chemical Management

ESH / RSL Factory Summit 08 830 Spot Lifter • MSDS - Contains Perchloroethylene – Scientific name - Tetrachloroethylene – Suspected Carcinogen – Reacts with oxidizers – Decomposes to Phosgene & HCL in fire • Phosgene? ? ? – Recommended PPE: SCBA, PPSa. F

ESH / RSL Factory Summit 08 Topics to Cover Chemical Identification and Hazards – Chemical Identification – How chemicals enter the body – Health Effects Factory Requirements – Know hazards of the chemical – Label Chemicals – Provide PPE – Storing Chemicals – Segregating Chemical – Disposing of Used Chemicals

ESH / RSL Factory Summit 08 Chemical Information Material Safety Data Sheets • Lists chemicals in the product • Physical and health hazards • How to protect workers from the hazards

ESH / RSL Factory Summit 08 Chemical Identification Types of chemical hazards • Physical hazards • Transportation Classification label • Health hazards • Route of Entry into the body • Health effect • NFPA/HMIG Hazard Labels

ESH / RSL Factory Summit 08 Chemical Identification – Physical Hazards TRANSPORT CLASSIFICATION Color Physical Hazard Red Flammable Orange Explosive Yellow Oxidizer Blue Water reactive Green Non-toxic Non-Flammable

ESH / RSL Factory Summit 08 Chemical Identification – Physical Hazard TRANSPORT CLASSIFICATION Class Name 2 Gases 3 Flammable Liquids 4 4. 1 Flammable Solids 4. 2 Self-reactive substances 4. 3 Substances dangerous when wet 5 5. 1 Oxidizing Substances 5. 2 Organic Oxidizers Symbol

ESH / RSL Factory Summit 08 Chemical Identification – Physical Hazard TRANSPORT CLASSIFICATION Class Name 6 Poisonous Substances 8 Corrosive Substances 9 Miscellaneous Symbol

ESH / RSL Factory Summit 08 Chemical Identification - Health Inhalation breathing Ingestion swallowing Absorbtion Skin contact

ESH / RSL Factory Summit 08 Chemical Identification - Health Carcinogens - cancer-causing compounds. Teratogens - compounds that can harm the developing fetus, causing birth defects or death. Mutagens - cause genetic mutations or changes, can cause birth defects or lead to cancer in the exposed person. Sensitizers - cause a reaction, base on an individual worker’s susceptibility.

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Know hazards of your chemicals • • • MSDSs are available for inspection MSDS are written in language spoken by workers Workers are trained, and understand the hazards associated with the chemicals they are working with

ESH / RSL Factory Summit 08 Know hazards of your chemicals Resources • Chemical Supplier • Chemical Manufacturer • Websites – – http: //www. osha. gov/web/dep/chemicaldata/#target http: //www. cdc. gov/niosh/npg/search. html

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Labels Factory Requirements • All chemical containers are labeled, including secondary containers. • Applies to solids, liquids, and gases • Chemical class is identified • NFPA hazard class or similar label

ESH / RSL Factory Summit 08 Chemical Identification Common Labels Blue – Health Red – Fire (Flammability) Yellow/Orange – Reactivity (Instability) White – Special Hazards 4 – Extreme Hazard 3 – Severe Hazard 2 – Moderate Hazard 1 – Minor Hazard 0 – Least Severe Hazard 4 2 1 0 3

ESH / RSL Factory Summit 08 Labels • Secondary container labels

ESH / RSL Factory Summit 08 Labels • Labels with Chemical Classification

ESH / RSL Factory Summit 08 Labels • NFPA labels

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Personal Protective Equipment (PPE)

ESH / RSL Factory Summit 08 Personal Protective Equipment Factory Requirements • PPE provided to workers prevents chemicals from entering body (inhalation, absorption, ingestion) – Based on MSDS – Respirator cartridges match the hazard • Workers trained on how to properly use and wear PPE • PPE is in good condition

ESH / RSL Factory Summit 08 Respirators Full Face cartridge Respirator Powered Air Purifying Respirator Half- Face Cartridge Respirator N 95 Filter (Dust Mask)

ESH / RSL Factory Summit 08 Respirators and Cartridges Multi-Gas Organic Vapor and Chlorine Gas Organic Vapor and Acid Gas Organic Vapor

ESH / RSL Factory Summit 08 PPE • Absorption through the skin/eyes – Gloves – Safety Glasses/goggles – Long Sleeves – Aprons – Closed Toe Shoes

ESH / RSL Factory Summit 08 PPE

ESH / RSL Factory Summit 08 Minimizing Exposure Ingestion • Eating, Drinking, or Smoking is not allowed in Chemical Handling or Storage Areas • Sink is provided so workers can regularly Wash Hands • Gloves

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Chemical Segregation Factory Requirement • All chemicals and chemical waste must be segregated into categories to prevent incompatible mixtures and dangerous chemical reactions

ESH / RSL Factory Summit 08 Chemical Segregation Compatibility Chart Terminology – KEEP APART – Keep at minimum 3 m apart – SEGREGATE – Keep in separate compartments of the same store separated by at least a firewall or in separate building – ISOLATE – Keep in separate building or isolate within a cabinet designed for this purpose

ESH / RSL Factory Summit 08 Chemical Segregation Segregating solvents from the following chemicals? Chemical Keep Apart Segregate Isolate Sodium Hypochlorite Acetic Acid Propane

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Chemical Storage Factory Requirements • All chemicals and chemical waste must be properly stored to prevent accidental chemical release to the environment • Aisles and Forklift Routes are Clearly Marked to prevent chemical containers from being hit or tipped over.

ESH / RSL Factory Summit 08 Drum Storage STACKED less than 4 high Closure device up CHOCKED to prevent rolling

ESH / RSL Factory Summit 08 Secondary Containment • • Chemicals must have Secondary Containment to prevent an accidental release or spill kits with materials for containment and absorption Secondary containment must be 110% of the largest volume container For a Single Tank 200 liters 110% or 220 liters

ESH / RSL Factory Summit 08 Secondary Containment For Multiple Tanks in Single Containment 100 liters 200 liters 110% (200) or 220 liters

ESH / RSL Factory Summit 08 Chemical Spills Factory Requirements • Chemical spills are cleaned only by trained personnel. § Person assigned to do the clean-up is trained to assess the size of the spill, physical hazards of the material, the health hazards of the spilled material, and how to use the spill containment kit

ESH / RSL Factory Summit 08 Chemical Spills Factory Requirements: • Proper PPE is provided for clean up • Materials used to clean up the spill are properly disposed

ESH / RSL Factory Summit 08 Good or Bad Secondary Containment?

ESH / RSL Factory Summit 08 Chemical Storage • Storage Area Must Have Safety shower/eye wash

ESH / RSL Factory Summit 08 Signs • Storage Area Must Have Signs informing workers of required PPE

ESH / RSL Factory Summit 08 Fire Extinguisher • Storage Area Must Have a working fire hose or Fire Extinguisher in the chemical storage area

ESH / RSL Factory Summit 08 Chemical Waste Storage • Chemical waste must be labeled • Chemical waste containers must be inspected weekly for signs of leaks, corrosion, or deterioration.

ESH / RSL Factory Summit 08 Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

ESH / RSL Factory Summit 08 Waste Disposal • Factories must use licensed and approved waste transporters • Waste must be disposed at a licensed & permitted disposal facility.

ESH / RSL Factory Summit 08 Not in compliance!!!

ESH / RSL Factory Summit 08 Summary Chemical Identification and Hazards – Chemical Identification – How chemicals enter the body – Health Effects Factory Requirements – Know hazards of the chemical – Label Chemicals – Provide PPE – Storing Chemicals – Segregating Chemical – Disposing of Used Chemicals

ESH / RSL Factory Summit 08 Questions?