1 sodium hydroxide NIHON SHIYAKU REAGENT 95 2

二、實驗方法 實驗材料與藥品: 1. 氫氧化鈉(sodium hydroxide) NIHON SHIYAKU REAGENT 95% 2. 鹽酸(Hydrochloric acid) NIHON SHIYAKU REAGENT 37% 3. 二氧化鈦(Ti. O 2 P 25) Degussa 4. 釕金屬錯化合物染料(uthenium 535 -bis. TBA, Ru. L 2(NCS)2 : 2 TBA, C 58 H 86 O 8 S 2 Ru, N-719) 5. 碘(Iodine, I 2) 6. 碘化鋰(Lithium Iodide, Li. I) 7. 聚乙二醇(Polyethylene glycol 20000) Fluka 8. 甲氧基丙腈(Methoxypropanenitrtle, MPN)

2. 2 儀器設備: 實驗用設備: 1. 微波消化器 Microwave digestion system (State D/Milestone) 2. 高溫煅燒爐 NEY 3 -500 3. 超音波震盪洗淨機 LEO，1502 H 4. 烘箱 明昱企業有限公司 5. 旋轉塗佈機 CHEMAT 檢測用設備: 1. 場發射電子顯微鏡 (Field Emission Scanning Electron Microscope, FE-SEM) JEOL 7001型 2. 太陽光模擬器 (Solar simulator) 3. X光線繞射分析儀 (X-Ray Diffraction, XRD) Rigakw D/MAX 2500 V 4. 紫外光-可見光吸收光譜儀 (UV-Visible Absorption Spectrometer) Jasco V 550

微波水熱式樣酸洗至不同p. H值對I-V曲 線效率的影響 η, % TRT Voc, V Jsc, m. A/cm 2 p. H 1 0. 791 0. 5725 0. 7153 0. 3239 p. H 4 0. 637 0. 5000 0. 5329 0. 1668 p. H 7 0. 478 0. 1042 0. 2990 0. 0149 p. H 10 0. 436 0. 0816 0. 2540 0. 0090 F. F.

酸洗至p. H=1. 0之微波水熱式樣對不同 煅燒溫度I-V曲線效率的影響 煅燒溫 度 Voc, V Jsc, m. A/cm 2 F. F. η, % 350℃ 0. 69 0. 9312 0. 4832 0. 3105 450℃ 0. 791 0. 5725 0. 7153 0. 3239 550℃ 0. 667 0. 6237 0. 550 0. 2290

微波水熱式樣煅燒不同溫度對I-V曲線 效率的影響 煅燒溫度 Voc, V Jsc, m. A/cm 2 F. F. η, % 350℃ 0. 789 0. 36625 0. 690 0. 2000 400℃ 0. 782 0. 5350 0. 7088 0. 2965 450℃ 0. 791 0. 5725 0. 7153 0. 3239 500℃ 0. 819 0. 4625 0. 7798 0. 2954

TRT摻混P 25粉末不同比例(a)TRT: P 25=4: 0 (b)3: 1 (c)2: 2 (d)1: 3 (e)1: 9 (f)0: 4對I-V曲線效率的影響 TNR : P 25 Voc, V Jsc, m. A/cm 2 F. F. η, % 4 : 0 0. 791 0. 5725 0. 7153 0. 3239 3 : 1 0. 813 1. 8875 0. 7291 1. 1189 2 : 2 0. 775 3. 9125 0. 6777 2. 0550 1 : 3 0. 816 3. 1750 0. 8968 2. 3236 0 : 4 0. 807 4. 0625 0. 8120 2. 6623 1 : 9 0. 780 4. 3375 0. 8343 2. 8227

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