CHEMSHEETS REACTIONS OF HALOGENOALKANES www chemsheets co uk
- Slides: 15
CHEMSHEETS REACTIONS OF HALOGENOALKANES © www. chemsheets. co. uk AS 1140 2 -Feb-2016
Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. bromoethane + aqueous Na. OH Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -chloropropane + aqueous Na. OH Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 1 -bromopropane + aqueous Na. OH Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -iodo-3 -methylbutane + aqueous Na. OH Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -chloropropane + ethanolic KCN Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 1 -bromobutane + ethanolic KCN Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -chloropropane + excess hot conc NH 3 Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -bromo-3 -methylbutane + excess hot conc NH 3 Nucleophilic substitution © www. chemsheets. co. uk AS 1140 2 -Feb-2016
• Hot, ethaanolic KOH (not warm, aq Na. OH) • Lose X and H from adjacent C (if there is one) • Forms alkene(s) • Can get different alkenes depending which adjacent C the H comes from • OH- acts as base (not nucleophile) Elimination © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -chloropropane + hot ethanolic KOH Elimination © www. chemsheets. co. uk AS 1140 2 -Feb-2016
e. g. 2 -bromobutane + hot ethanolic KOH Elimination © www. chemsheets. co. uk AS 1140 2 -Feb-2016
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