Nonideal solutionHm 0 Enthalpy of mixingHm Hm Xa

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기본 개념 • Nonideal solution(ΔHm≠ 0)에서 Enthalpy of mixing(ΔHm) 은 ΔHm=Ω Xa Xb Ω

기본 개념 • Nonideal solution(ΔHm≠ 0)에서 Enthalpy of mixing(ΔHm) 은 ΔHm=Ω Xa Xb Ω = (ΔHm/Xa. Xb ) = L 0 + L 1 Xb + L 2 Xb 2 + … • Activity coefficient (γb=ab/xb)는 RT lnγb= RT ln(ab/xb)= L 0 + 2 L 1 Xb + 3 L 2 Xb 2 + …

기본 개념 • Chemical potential μBβ = Δ˚GB α→β + RT ln. XBβ +(∂

기본 개념 • Chemical potential μBβ = Δ˚GB α→β + RT ln. XBβ +(∂ Ω β / ∂ XBβ )XAβ 2 XBβ + Ω βXAβ 2 • 평형 조건 μPsfcc =μPsbcc , μTkfcc =μTkbcc μPsbcc =μPs. L , μTkbcc =μTk. L μPsfcc =μPs. L , μTkfcc =μTk. L

결과 plot

결과 plot

1 Subregular Solution Enthalpy of MixingHm Activityai CompositionXi1 Subregular Solution Enthalpy of MixingHm Activityai CompositionXi
ENTHALPY CHANGES ENTHALPY CHANGES CONTENTS Thermodynamics Enthalpy changesENTHALPY CHANGES ENTHALPY CHANGES CONTENTS Thermodynamics Enthalpy changes
BOND ENTHALPY Bond Enthalpy The enthalpy associated withBOND ENTHALPY Bond Enthalpy The enthalpy associated with
Enthalpy Enthalpy Enthalpy His the total amount ofEnthalpy Enthalpy Enthalpy His the total amount of
Enthalpy ENTHALPY CHANGES ENTHALPY H the energy contentEnthalpy ENTHALPY CHANGES ENTHALPY H the energy content
Lecture 3 Nonideal Transistor Theory 4 Nonideal TransistorLecture 3 Nonideal Transistor Theory 4 Nonideal Transistor
Lecture 4 Nonideal Transistor Theory Outline q NonidealLecture 4 Nonideal Transistor Theory Outline q Nonideal
Lecture 4 Nonideal Transistor Theory Outline q NonidealLecture 4 Nonideal Transistor Theory Outline q Nonideal