Writing Lewis Structures for Molecular (Covalent) Compounds 1. sketch arrangement of atoms (determine central atom) 2. determine number of valence e 3. place two e- in each bond 4. complete octets on non-central atoms 5. place any remaining e- on central atom 6. IF central atom has less than an octet, form multiple bonds
Drawing Lewis Structures
Draw the Lewis structure for the NO 21 - ion. First, determine the atomic arrangement. O N O
Next, determine the total number of valence electrons. 5 electrons from the N 6 electrons from each O for 12 more electrons 1 additional electron because it is a monoanion 18 total valence electrons
Use the electrons to make electron-pair bonds between the central and outer atoms. O N O 18 - 4 = 14 electrons remain
Complete the octet of each outer atom. . . N . . O. . 14 - 12 = 2 electrons remaining
If there any remaining electrons, put them on the central atom. . . N . . O. . All of the valence electrons have now been used.
If, and only if, the central atom has fewer than eight electrons, complete its octet by using nonbonding electron pairs from outer atoms to make multiple bonds. . . N . . O. .
In the final Lewis structure, each atom should have a complete octet of electrons. If it is an ion, indicate the charge outside of brackets. . . N . . O. . O . . 1 -