upon completion you will be required to individually

* upon completion you will be required to individually complete and submit a test as proof of training WHMIS 1988/2015 Workplace Hazardous Materials Information System

WHMIS Workplace Hazardous Materials Information System Canada wide system designed to provide employers and workers with information about hazardous materials used in the workplace

What is GHS? GHS is global system that defines and classifies the hazards of chemical products and communicates health and safety information on labels and Safety Data Sheets (SDS’s)

WHMIS 1988 + GHS = WHMIS 2015

WHMIS 1988 + GHS = WHMIS 2015 Federal: WHMIS 2015 is in place • Not governed by Controlled Products Regulation (now it is the new Hazardous Products Regulation) • WHMIS 1988 is not off the books – we still need to cover it until it is phased out WHMIS 2015 will be fully implemented by Dec 2018

Why the changes? Implementing GHS into Canada will help harmonize Canada’s chemical hazard communication system with those of other countries providing more consistent hazard information.

Excluded Products • Explosives • Cosmetics • Food and Drugs • Pesticides • Radioactive Material • Hazardous Waste * Although these items are excluded from the WHMIS requirements we still need to know if they are safe and how to protect ourselves • Consumer Products • Wood/Wood Products • Tobacco/Tobacco Products

WHMIS/GHS 2015 What’s New? • New hazard pictograms • New hazard classes • New labels and their required elements such as signal words • New meaning of all signal words and hazard statements • New SDS format and how to locate information needed to work safely

VIDEO – WHMIS 2015 Introduction

WHMIS/GHS RESPONSIBILITIES Suppliers/Manufacturers: • Identify and classify controlled products • Prepare supplier labels and MSDS/SDS • Review and update MSDS/SDS • Provide most current MSDS upon delivery

WHMIS/GHS RESPONSIBILITIES Employer/Supervisor (Principal): · create/apply workplace labels · obtain most current MSDS/SDS · assess products produced in the house · worker education and training · provide information in medical emergencies · establish a WHMIS program

WHMIS/GHS RESPONSIBILITIES Worker: • to use or wear the equipment, protective clothing as required by the employer • to report hazards and cases of non-compliance to their supervisor (i. e. missing or damaged labels) • participate in training • understand use information provided (labels and MSDS/SDS)

WHMIS & GHS Hazardous information is provided in 3 ways: 1. Labels 2. MSDS/SDS 3. Worker training

WHMIS 1998 LABELS WHMIS 1988

WHMIS/GHS 2015 WHMIS 2015 – Potential GHS Label

7 Components of a Supplier Label: WHMIS 1998 1. 2. 3. 4. 5. WHMIS/GHS 2015 Product identifier Supplier identifier (name only) Hazard symbols (1 or more 1. circular) 3. 2. and telephone number) effect which may result from exposure) 4. Precautionary measures 5. 7. First aid instructions Reference to MSDS Hazard pictograms (symbol within a Diamond) Risk phrases (description of the Hazard statements (supplier must use standard wording) (describes safe handling use & storage) 6. Product identifier Supplier identifier (name, address Precautionary statements (response, prevention, storage and disposal) 6. 7. Signal word (danger or warning) No reference to MSDS/SDS

Workplace Labels A workplace label is required when: • a hazardous product is produced (made) at the workplace and used in that workplace, • a hazardous product is decanted (e. g. , transferred or poured) into another container, or • a supplier label becomes lost or illegible (unreadable)

Workplace Labels SAMPLE WORKPLACE LABEL Methanol 3 REQUIRED PIECES OF INFORMATION 1. Product Identifier 2. Hazard Information 3. Reference to MSDS Flammable – Do not use near flame or spark Avoid inhaling vapours See the MSDS before using product g into in t n a c e d n e h w s e on *You create these spray bottles etc…

There are two situations when a workplace label is not necessary When a hazardous product is… #1. poured into a container and it is going to be used immediately, or #2. "under the control of the person who decanted it". For example, when the person who poured the product into another container will be the only person who will use it, and the product will be used during one shift, a full workplace label may not be required. However, the container must still be identified with the product identifier (name). If the product is not used right away or if more than one person will be in control of the product, a full workplace label is required.

HAZARD CLASSIFICATION/SYMBOLS: Hazard Classes WHMIS 1988 6 Classes: 1. Class A-Compressed Gas 2. Class B- flammable and Combustible Material 3. Class C-Oxidizing Material 4. Class D Poisonous and Infectious Material 5. Class E-Corrosive Material 6. Class F- Dangerously Reactive Material 11/2/2020 WHMIS/GHS 2015 Physical hazards – 16 classes Health hazards – 10 classes Environmental hazards – 2 classes

WHMIS/GHS 2015 Hazard Classes Pictograms Summary Physical Hazards Health Hazards Environmental Hazard (Optional – not required by WHMIS in Canada)

GHS - Physical Hazard Classes 1. Explosives 9. Self Reactive Substances and Mixtures 2. Flammable Gases 10. Pyrophoric Liquids (ignite spontaneously) 3. Flammable Aerosols 11. Pyrophoric Solids 4. Flammable Liquids 12. Self-Heating Substances and Mixtures 5. Flammable Solids 13. Organic Peroxides 6. Oxidizing Gases 14. Corrosive to Metals 7. Oxidizing Liquids 15. Gases Under Pressure 8. Oxidizing Solids 16. Self Reactive substances

GHS – Health Hazard Classes 1. Acute toxicity 2. Skin corrosion/irritation 3. Serious eye damage/eye irritation 4. Respiratory sensitization/skin sensation 5. Germ cell mutagenicity 6. Carcinogenicity 7. Reproductive Toxicity 8. Specific target organ toxicity – single exposure 9. Specific target organ toxicity – repeated exposure 10. Aspiration hazard

GHS - Environmental Hazard Class (optional) 1. Hazardous to Aquatic Environment 2. Hazardous to Ozone Layer

How Chemicals Enter the Body - Route of Entry

Common Terms you may encounter on Labels or MSDS/SDS: Acute - Sudden or brief. Acute exposure is a short tem exposure that lasts min/hrs/days. Acute effects occur quickly and can harm the body after one single exposure. Chronic – Long term or prolonged. Chronic exposure is a long term exposure that lasts for months or years.

Carcinogen - A substance which can cause cancer. Mutagen - A substance which can cause changes in the DNA of cells (mutations). Teratogen – A substance which can cause birth defects.

LD 50/LC 50 – Lethal dose or lethal concentration of a material that causes death in 50% of the test animals. Exposure Limits – Time and concentration/ dose that a normal healthy adult can be exposed to before suffering adverse health effects.

Combustible - Able to burn. Flash Point - The lowest temperature at which a liquid or solid gives off enough vapour to form a flammable air -vapour mixture near its surface. The lower the flash point, the greater the fire hazard.

CLASS A: Compressed Gas PHYSICAL HAZARD: Compressed Gas RISKS: • Could explode due to pressure • Could explode if heated or dropped • Possible hazard from both the force of explosion and the release of contents PRECAUTIONS: EXAMPLE: ENSURE CONTANER IS ALWAYS SECURED Oxyacetylene gas • Store in appropriate designated areas CO 2 • Do not drop or allow to fall Oxygen

PHYSICAL HAZARD RISKS: • Poses an explosion hazard • Self-reactive- heating may cause fire or explosion • Organic Peroxide PRECAUTIONS: • Ensure container is away from any heat sources

CLASS B: PHYSICAL HAZARD: Flammable and Combustible Material RISKS: • Potential fire hazard • May ignite spontaneously PRECAUTIONS: STORE IN PROPERLY DESIGNATED AREAS WORK IN WELL VENTILATED AREAS • Avoid heating EXAMPLE: • Avoid sources of sparks/flames Acetone Turpentine Kerosene Butane Varnish Spray Paint

CLASS C: Oxidizing Material PHYSICAL HAZARD: Oxidizing RISKS: Materials which can cause other materials to burn or support combustion • Can cause skin or eye burns EXAMPLE: • Increase fire and explosion hazard Sodium Hypochlorite • May cause combustibles to explode or Potassium Permanganate react violently PRECAUTIONS: STORE IN AREAS AWAY FROM COMBUSTIBLES WEAR BODY, HAND, FACE AND EYE PROTECTION • Store in proper containers which will not rust or oxidize

CLASS D 1: Toxic – Immediate and Severe HEALTH HAZARD: Toxic - Acute Toxic RISKS: • May be fatal if ingested or inhaled • May be absorbed through the skin • Small volumes have a toxic effect EXAMPLE: PRECAUTIONS: Chemicals used in Photography AVOID BREATING DUST OR VAPOURS AND AVOID CONTACT WITH SKIN OR EYES • Use personal protective equipment • Store in designated areas Sulfuric Acid

CLASS D 2: Other Toxic Effects RISKS: • May cause death or permanent injury • May cause cancer, birth defects or sterility • May be sensitizer causing allergies EXAMPLE: PRECAUTIONS: Window Cleaner WEAR APPROPRIATE PERSONAL PROTECTION WORK IN A WELL VENTILATED AREA Drain Cleaner Asbestos Sweeping Compound • Store in appropriate designated areas • Avoid direct contact • Use personal protective equipment, work in ventilated areas and store in designated areas

HEALTH HAZARD RISKS: • Carcinogenicity • Respiratory Sensitization • Reproductive Toxicity • Specific Target Organ Toxicity • Germ Cell Mutagenicity • Aspiration Hazard PRECAUTIONS: • Wear appropriate personal protective equipment

Exclamation Mark RISKS: • Irritant (skin or eyes) • Skin Sensitization • Acute Toxicity (harmful) • Specific Target Organ Toxicity • Hazardous to the Ozone Layer PRECAUTIONS: • Ensure appropriate personal protective equipment

CLASS D 3 Biohazardous and Infectious RISKS: • Biological materials which can cause disease or have the same effects of disease • Includes viruses, yeasts, moulds, bacteria and parasites which affect humans PRECAUTIONS: SPECIAL TRAINING REQUIRED TO WORK WITH THESE MATERIALS • Avoid direct contact • Always use universal precautions or other handling techniques

CLASS E: Corrosive Material PHYSICA HAZARD: Corrosive RISKS: • Eye and skin irritation on exposure • Severe burns/tissue damage on longer exposure - may cause blindness if eyes contacted – lung damage if inhaled PRECAUTIONS: EXAMPLE: WEAR BODY, FACE AND EYE PROTECTION • • Ensure protective equipment is appropriate Work in well ventilated area Avoid all direct body contact Use appropriate storage containers Degreaser Floor Stripper Chlorine Sulfuric Acid

CLASS F: Dangerously Reactive Material EXAMPLE: (not recom. for school use) Vinyl Chloride Ethylene Oxide Aluminium Chloride RISKS: • Unstable • May react with water to release a toxic or flammable gas • May explode if exposed to shock or heat PRECAUTIONS: HANDLE WITH CARE AVOIDING VIBRATION, SHOCKS AND SUDDEN TEMP. CHANGES • • • Store in appropriate containers away from heat Ensure storage containers are sealed Store in cool, flame-proof area

ENVIRONMENTAL HAZARD RISKS: • Toxic to the environment and aquatic life if contents should enter the environment PRECAUTIONS: • Ensure container is secured/closed • Ensure proper disposal, do not pour into sink or allow to spill near sewers/drains • Store in appropriate designated areas

What is an MSDS/SDS? A Material Safety Data Sheet (MSDS) or SDS is a document that: - contains information on the potential hazards (health, fire, reactivity and environmental) and how to work safely with the chemical product - contains information on the use, storage, handling and emergency procedures all related to the hazards of the material - contains much more information about the material than the label - prepared by the supplier or manufacturer of the material Under WHMIS 2015, SDS will be phased in and replace MSDS by 2018

HAZARD COMMUNICATION: MSDS/SDS WHMIS 1988 WHMIS/GHS 2015 (Material Safety Data Sheets) Current within 3 years (Safety Data Sheets) SDS MSDS vs Most current available from supplier The most current MSDS/SDS must be accessible to all staff, electronic format is acceptable as long as it can be accessed in an emergency

HAZARD COMMUNICATION – In the Workplace MSDS 1. 2. 3. 4. 5. 6. 7. 8. 9. Product Identification & Use Hazardous Ingredients Physical Data Fire & Explosion Hazard Data Reactivity Data Toxicological Properties/Health Hazard Data Preventative Measures First Aid Measures Preparation Date of MSDS 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. Identification Hazard Identification Composition Information on Ingredients First Aid Measures Fire Fighting Measures Accidental Release Measures Handling and Storage Exposure Controls/Personal Protection Physical and Chemical Properties Stability and Reactivity Toxicological Information Ecological Information Disposal Considerations Transport Information Regulatory Information Other Information

Where to find the HCDSB MSDS/SDS: Follow this link: www. 3 eonline. com or https: //www. 3 eonline. com/Eee. Online. Portal/Desktop. Default. aspx? tabid=90 or check with your supervisor

If prompted for login use ID: haltoncatholicdistrict PW: burlington

HCDSB MSDS/SDS Management • If you find a chemical that doesn’t have a MSDS inform Health and Safety Officer before they are used • Temporary chemicals used during a renovation or health outbreak should come with MSDS/SDS to be kept on site • Do not bring unapproved chemicals into the workplace

HCDSB Chemical Storage • Chemicals must be stored based on their reactivity, refer to MSDS/SDS and Science Safety Manual • Science chemicals must be securely stored in the science prep room, not in the classroom • When not in use, store chemicals away from children – keep chemical storage areas locked • All chemicals must be labeled

Flammable Chemicals STORING CHEMICALS • In approved containers (if under 5 gal. ) or, in a metal cabinet • Report all flammable liquid spill/leaks to the supervisor • Decant flammable chemicals in the fume hood • See HCDSB Science Safety Manual for additional information

HCDSB Chemical Handling • Decant chemicals using proper dispensing system in approved areas • Follow specific chemical handling instructions • Order small quantities, enough • Use the appropriate chemical for the task • Do not mix chemicals unless instructed to do so (ie. as part of a science experiment) • Never use flammable chemicals to clean your hands • Use caution when cleaning areas where unknown chemicals have been used (science sinks/benches) • Wear appropriate Personal Protective Equipment (PPE)

OHSA - Sec. 28(1) A worker shall PPE (b) wear the equipment, protective devices or clothing that the worker’s employer requires Personal Protective Equipment Types of Personal Protective Equipment (PPE): Gloves (different types) Goggles/face shields Apron/clothing Shoes/boots Respirators (different types) *refer to the MSDS/SDS

HCDSB Hazardous Waste Disposal • Dispose of waste in a safe environmentally sound way • All chemicals should be disposed of according to the MSDS sheets – See HCDSB Science/Tech Safety Manuals for additional information • Contact your Facilities Manager or Health and Safety Officer for direction • Hazardous waste disposal scheduled every December, March and June in all Secondary Schools • Only those with valid TDG Certification should sign the Transportation Manifest on pickup

HCDSB Emergency Procedures Types of emergencies: • • First Aid/injury Fire Explosion Chemical Spill Ensure you are familiar with the specific emergency procedures at your school/location and for the specific chemicals you are using before you use them.

Report all accidents, injuries and spills to your Supervisor. An Accident/Incident investigation may be required and can provide valuable information for prevention.

FIRST AID Know who the first aid providers are in your school and how to reach them in case of emergency Know where the emergency eyewash station is and how to use it in an emergency (eyewash bottles have only enough water to get you to a eyewash station)

Emergency Procedures Know the Basic First Aid BASIC - FIRST AID Refer to MSDS/SDS For Chemicals in the eye (burn/absorption): Flush with water for 15 minutes Chemicals on the skin (burn/absorption): Brush off dry chemicals/Flush with water for 15 minutes

Emergency Procedures Know the Basic First Aid Refer to MSDS/SDS Ingestion of chemicals: Consult poison control http: //www. ontariopoisoncentre. ca/ Inhalation of chemicals: Get fresh air and monitor casualty Injection of chemicals: Seek medical attention

Can you answer the following questions? ü What are the hazards of the products I am using? ü How do I protect myself from those hazards? ü What do I do in case of an emergency? ü Where can I get additional information?

Additional Resources: http: //whmis. org/ - Canada’s National WHMIS Portal http: //www. ccohs. ca/products/posters/WHMIS 2015/ WHMIS/GHS Posters

Next Step: Please click on the link below to complete your WHMIS/GHS Test. 2016 WHMIS Test/Acknowledgement link https: //survey. hcdsb. org/2016 WHMIS. aspx? u=92 a 9 aa 3 d-c 0004 e 17 -9 d 42 -c 2 dcd 926 caa 7&force. New=true&test=true

Questions? Kimberly George Health and Safety Officer georgek@hcdsb. org 905 -632 -6300 Ext. 174