The physical properties of alkane The physical properties
- Slides: 36
The physical properties of alkane
The physical properties of alkanes • Boiling points:
Boiling points of alkanes
Boiling point of alkanes
Boiling point of alkanes • Alkanes are held together by Van der Waals forces • Van der Waals forces: - The weakest of all intermolecular attractions - Are induced-dipoleinduce-dipole interaction
Boiling point of alkanes • van der Waals forces depends on area of contacts between the molecules • Greater area of the contacts stronger van der Waals forces • Stronger van der Waals greater amount energy needed to break it higher boiling point
B. p of branched and unbranched alkanes • Branched alkanes have lower b. p than unbranched alkane
B. p of branched and unbranched alkanes • Branched alkane has lower area of contact compare to unbranched alkane • Branched alkane has more compact, spherical shape • Imagine: pentane is cigar and neopentane is tennis ball
Melting points • Melting point (mp) of a compound is • Is influenced by packing (how well the individual molecules in a solid fit together in crystal lattice) • Greater packing Greater amount of energy needed to break the lattice and melt the compound
Melting points • Alkane with odd number have lower m. p than alkane with even number • Alkane with odd number packed less tightly compared to even numbered alkane
Solubility of alkane • Alkane are not soluble in water/ polar solvent • Alkane are soluble in organic solvent
Solubility of alkane • Solubility rule based on polarity of molecules: - Example: polar compound dissolve in polar solvent -Solvation: Interaction between the solvent and molecule/ ion dissolved in that solvent
Solubility of alkane
Solubility of alkane • Alkane is non-polar compound • No net charge – polar solvent not attracted to them
Solubility of alkane • When a molecular substance dissolves in water, you have to: • break the intermolecular forces within the substance. In the case of the alkanes, these are Van der Waals forces. • break the intermolecular forces in the water so that the substance can fit between the water molecules. In water the main intermolecular attractions are hydrogen bonds.
Solubility of alkane • Breaking any intermolecular forces cause energy • Making a new intermolecular forces release energy • Possible interaction between alkane and water is only van der Waals forces
Solubility of alkane • Amount of energy release if alkane make a new van der Waals bond between alkane and water is small • The small amount of energy released will not be enough to break the hydrogen bonds of water • Therefore alkane are not dissolved in water
Solubility of alkane • Breaking any intermolecular forces cause energy • Making a new intermolecular forces release energy • Possible interaction between alkane and water is only van der Waals forces
Exercise • Arrange the alkane in each set in order of decreasing boiling point (a) Butane, decane, hexane (b) 2 -methylheptane, octane, 2, 2, 4 trimethylpentane
Exercise • Explain why has a lower boiling point than CH 3 CH 2 CH 3.
Conformations of Alkanes: Rotation about Carbon–Carbon Bonds • Conformations: different spatial arrangements of the atoms that result from rotation about a single bond. • Conformational isomers/conformers- molecules with different conformations.
Conformations of Alkanes: Rotation about Carbon–Carbon Bonds • Ethane -The conformers produced by rotation about carbon-carbon bond of ethane: staggered conformer eclipsed conformer.
Conformations of Alkanes: Rotation about Carbon–Carbon Bonds
Conformations of Alkanes: Rotation about Carbon–Carbon Bonds
Conformations of Alkanes: Rotation about Carbon–Carbon Bonds • Staggered conformer is more stable than eclipsed conformer
Different Conformations of Ethane Noticed that staggered conformers are at energy minima, whereas eclipsed conformers are at energy maxima.
Different Conformations of Ethane • Why staggered conformers are stable than eclipsed conformers? - In an eclipsed conformers, there is a bond repulsion of hydrogens existing in close proximity to other hydrogens on the same intersecting plane - Consequently, the energy is higher by 2. 9 kcal/mol when the degree of rotation is 0.
Conformations of butane • Butane has 3 C-C single bonds • Rotation can occur about each of them.
Conformations of butane • The Newman projections below show the staggered and eclipsed conformers that result from rotation about the C 1 -C 2 bond: • The staggered conformers resulting from rotation about the C 1 -C 2 bond in butane- have the same energy
Conformations of butane • The staggered conformers resulting from rotation about the C 2 -C 3 bond- do not have the same energy. • The staggered and eclipsed conformers from rotation about the C 2 -C 3 bond in butane are:
• Of the staggered conformers: -D is more stable than B and F -Because the 2 methyl groups are far apart from each other. -D is called anti-conformer -B and F is called gauche conformer
Conformations of butane • Anti and gauche conformers do not have the same energy Steric strain • Steric strain: strain experienced by a molecule when atoms or groups are close enough to one another for their electron clouds to repel each other. Thus possesses additional energy. • Steric strain in molecules increase as the size of the group increase
Conformations of butane • Why A has the highest potential energy compare to other conformers?
Exercise • Draw all the staggered and eclipsed conformers that result from the rotation about the C-2 and C-3 bond of pentane • Draw a potential energy diagram for a rotation of C-2 and C-3 bond of pentane through 360, starting with the least conformers
- Butyl isomers
- Alkane common name
- Alkane functional group
- Alkane organic chemistry
- Tollens reagent
- General molecular formula of alkene
- Methane ethane propane butane pentane
- R-x functional group
- Stability of chair and boat conformation
- Homologe reihe der alkane
- Nomenclature
- Alkane viscosity
- Benzolring
- Alkane complete combustion
- Vereinfachte strukturformel alkane
- 2 3 dimethylpentane
- Is alkane an organic compound
- Name
- The polar group
- Alkyne to alkene
- Hydrocarbons class 11
- Meth eth prop
- Chemistry cracking
- Methan ethan propan
- Chemical property definition
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