The BornOppenheimer Separation The BornOppenheimer Separation Molecules electronic
The Born-Oppenheimer Separation
The Born-Oppenheimer Separation Molecules electronic transitions E > 10000 cm-1
The Born-Oppenheimer Separation Molecules electronic transitions E > 10000 cm-1 Vibrational transitions E = 100 -10000 cm-1
The Born-Oppenheimer Separation Molecules electronic transitions E > 10000 cm-1 Vibrational transitions E = 100 -10000 cm-1 Rotational transitions E = 0. 1 – 100 cm-1
The Born-Oppenheimer Separation H = E H = Hel + Hvib + Hrot+ …
The Born-Oppenheimer Separation H = E H = Hel + Hvib + Hrot+ … = el vib rot …
The Born-Oppenheimer Separation H = E H = Hel + Hvib + Hrot+ … = el vib rot … = i i
The Born-Oppenheimer Separation H = E H = Hel + Hvib + Hrot+ … = el vib rot … E = Eel + Evib + Erot +… = i i
The Born-Oppenheimer Separation H = E H = Hel + Hvib + Hrot+ … = el vib rot … E = Eel + Evib + Erot +… = i i E= i Ei Harry Kroto 2004
E(r) H+H v”=3 2 1 0 r
Excited electronic states - often many H + H* v’=3 2 1 E(r) 0 H+H v”=3 2 1 0 r
Nuclear Energies H+H E(r) Chemical Energies Rotational levels 0 r
Continuum wavefunction of a dissociating state E(r) H+H Rotational levels 0 r
H+H E(r) Rotational levels 0 r
C* + N E(r) v’= 0 C+N v”=3 2 1 0 r
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