Structural formulas of cyclic molecules Cyclohexane v Expanded
- Slides: 54
Structural formulas of cyclic molecules -- Cyclohexane v. Expanded formula 2021/9/6
Structural formulas of cyclic molecules -- Cyclohexane v. Condensed formula 2021/9/6
Structural formulas of cyclic molecules -- Cyclohexane v. Polygon formula 2021/9/6
Examples of Cyclic Molecules 2021/9/6
More examples 2021/9/6
取代单环烷烃的命名 Nomenclature of the Substituted Monocycloalkanes v 取代基只有一个不需标出位号 v If there is only one substituent, do not use the “ 1”. v 取代基不只一个标出所有取代基位号 v If there is more than one substituent, you must use all numbers, including “ 1”! v 从取代基位号小的方向给环编号 v Number around the ring in a direction to get from the first substituent to the second substituent by the shorter path. v 在取代程度相同时按字母顺序编号 v 多取代碳编号优先 2021/9/6
1, 1 -Dimethylcyclohexane 2021/9/6
4 -Ethyl-1, 1 -dimethylcyclohexane 2021/9/6
Two Ways of Naming This 1 -Isopropyl-2 -methylcyclohexane 1 -Methyl-2 -(1 -methyl)cyclohexane 2021/9/6
长链作母体,3 -Cyclobutyl-3 methylpentane 2021/9/6
环烷基 Cycloalkyl Groups 2021/9/6
2021/9/6
Cyclobutane (puckered form) 蝴 蝶 式 2021/9/6
Cyclopentane 信 封 式 2021/9/6
Estimate of Angle Strain 2021/9/6
Cyclohexane 椅 式 构 象 球 棒 模 型 2021/9/6
Cyclohexane (top view) no contact 斯 陶 特 模 型 2021/9/6
Cyclohexane (boat form) bowsprit-flagpole interaction 2021/9/6 船 式 构 象 球 棒 模 型
Cyclohexane (top view -- steric strain) 船 式 斯 陶 特 模 型 2021/9/6 Notice!
Chair-chair Inversion in Cyclohexane 半椅式 船式 扭船式 椅式 2021/9/6 转 环 作 用 中 的 能 量 变 化
凡与垂 直轴成 。 109 28’ 的C-H 键 2021/9/6 Cyclohexane (equatorial bonds)
Cyclohexane (showing both axial and equatorial bonds 直立键 平伏键 2021/9/6
Chair-chair Inversion in Methylcyclohexane 甲 基 环 己 烷 2021/9/6
tert-Butylcyclohexane (equatorial) 叔 丁 基 环 己 烷 2021/9/6
tert-Butylcyclohexane (space-filling model) 叔 丁 基 环 己 烷 2021/9/6
tert-Butylcyclohexane (axial group) 1, 3 - a 二 键 相 互 作 用 叔 丁 基 环 己 烷 2021/9/6 HUGE steric strain
Form the Complete IUPAC Name: 反-1 -(1, 1 -二甲基乙基)-4氯环己烷 trans-1 -tert-Butyl-4 -chlorocyclohexane 2021/9/6
二、Diels-Alder Reaction 内型(endo) 2021/9/6
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