Sigma to sigma H HI Ry calc V6
- Slides: 15
Sigma to sigma H+ HI+ Ry, calc.
V=6? H+ HI+ Ry, calc. V? or R? J=5, 6? V=5? Q line
Sigma to pi H+ Unfitted HI+ Ry, calc.
Sigma to delta H+ HI+ Ry, calc. Unfitted
6 H+ 5 4 3 2 1 HI+ 1 V calc. Unfitted
? ? ? 6 7 H+ 5 4 3 2 HI+ 1 V calc. Unfitted 7 6
7 8 H+ 6 5 4 3 HI+ 3 V calc. Near
V=8? H+ HI+ Ry, calc. V? or R? J=7, 8? V=7? Q line
J=8 J=7 J=6 H+ HI+ calc. Ry + V Calc. calc. V calc. Ry J=5, 8 J=7 J=6
8 9 7 6 5 4 H+ HI+ 3 ? ? Calc. Near V
H+ HI+ calc. Ry Calc. J=9 calc. V J=4 J=8
Unfitted
J´= 10 J´= 8 J´= 7 J´= 6 J´= 5 • If this is the case, largest mixing is for the J´s no. 6 and 7 Therefore largest shifts as well as intensity alterations will be seen for the corresponding J´lines (J´= 6, 7) J´= 5 J´= 4 J´= 2 J´= 0 Ry(1 S(0+); v´) Region worth focusing on V(1 S(0+); v´= m+ 18 ) • Less analogous effects will bee seen for the J´s no. 5 and 8. • Since this corresonds to an intermediate strong interaction, effect on the positions of lower J´ lines may also bee seen as shifts -to higher energies for the ion-pair state and to lower energies for the Ry-state.
NB: in addition to simulation calculations by pgopher you should record: 1) Reduced term value plots: (E(J´)-E 0(J´)) vs. J´ 2) Relative intensities of peaks vs. J´: I(J´) vs. J´ (deduce relative intensities from line fits) 3) linewidths (LW) vs J´: LW(J´) vs. J´ (deduce LW´s from line fits) - analogous to many of our previous perturbation analysis: see for example, https: //notendur. hi. is/agust/rannsoknir/papers/jcp 142 -244312 -15. pdf https: //notendur. hi. is/~agust/rannsoknir/papers/pccp 17 -32517 -15. pdf https: //notendur. hi. is/~agust/rannsoknir/papers/jcp 140 -244304 -14. pdf https: //notendur. hi. is/~agust/rannsoknir/papers/jmsp 290 -5 -13. pdf https: //notendur. hi. is/agust/rannsoknir/papers/HBr/jcp 136 -214315 -12. pdf
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