QUIMICA CEPSA QUIMICA PALOS DE LA FRONTERA IPPC

QUIMICA CEPSA QUIMICA PALOS DE LA FRONTERA IPPC DEVELOPMENT Palos de la Frontera Jul 12 th, 2012 Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: KEY DATES YEAR PUBLICATION/ACTION 1996/09 Council Directive 96/61/EC of 24 th September 1996 concerning integrated pollution prevention and control ("IPPC Directive") 2002/07 Transposition to Spanish legislation: Law 16/2002 (IPPC) 2003/02 Publication of Reference Document on Best Available Techniques in the Large Volume Organic Chemical Industry (LVOC BREF) 2004/01 Presented documentation to Andalusia Environment Government 2005/04 Obtained “Integrated Environmental Authorization (AAI)” 2007/10/30 Final date for “Integrated Environmental Authorization (AAI) Pagina 1 de 3” CEPSA Química

Quality, Safety and Environment Certifications QUALITY ISO 9001 1992 ENVIRONMENT ISO 14001 1999 ENVIRONMENT EMAS 2010 RISKS PREVENTION OHSAS 18001 2004 SUSTAINABILITY RESPONSIBLE CARE 1993 SUSTAINABILITY DOÑANA 21 2007 At start of IPPC legislation CEPSA Química had established operational procedures to control and minimize pollution Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT What’s needed to obtain IPPC permit? : BREF Documents relevant to petrochemical industry: QUIMICA “Large Volume Organic Chemical Industry”, 2003/02. “Cooling Systems”, 2001/12. “Common Waste Water and Waste Gas Treatment and Management Systems in the Chemical Sector”, 2003/02. “Emission from storage of bulk or dangerous materials”, 2003/07. “Monitoring Systems”, 2003/07. “Large Combustion Plants”, 2003/03 Did not exist specific BREF of phenol production (today: first draft in study). Methylamine: BREF LVOC summary of system established in CEPSA Química: BAT. PHENOL/ACETONE: Process via cumene oxidation formed by alkylation: BAT Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Air Pollution Emissions Fuel: Priority utilization of natural gas. Minimization of Fuel-oil (Voluntary objective) QUIMICA 2004: Only one furnace used FO and NG simultaneously: B-401. New plant that started at 2007: furnace designed only for natural gas. 2008: stopped use of FO. 2009: New furnace B-401 N to substitute old B-401. New furnaces: Low NOx burners. B-401 NOx emissions below limits. High reduction in SOx and Nox emissios Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Air Pollution Emissions Continuous emissions Monitoring system for furnaces > 50 Mw: (B-401/ B-401 N) and cogeneration plant. QUIMICA Adaptation of platform and ladder in furnace B-401’s stack for air emission measurements. Design of stacks to optimize dispersion of pollutant. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Air Pollution Emissions Minimization of Volatile Organic Compound emissions (VOC’s) (Voluntary objective) QUIMICA Optimization of activated charcoal chambers system to reduce VOC in air from oxidation reactors. New vents absorber of Methylamine plant. Reduction of atmospheric vents from trucks and drums loading. Change of open samplings systems to closed-loops. Pump Seals: Substitution of water systems to gas closed circuits. Establishment of a Leak Detection and repair (LDAR) program. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Air Pollution Emissions CEPSA Química has a Cogeneration plant that has an independent IPPC Permit. QUIMICA Reduction of limit to NOx: 500 to 75 mg/Nm 3. Change to a gas generator with Dry Low Emissions technology. Investment 8 MM €. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Waste Water Emissions Process water waste is sent to a primary treatment and then goes to the treatment plant where the contaminants are eliminated through a biological cleaning process: Emission point #1 QUIMICA IPPC permit established authorized waste water limits and how they must be controlled. CQ have made Investments to optimize effluent plant in order to improve the quality of the waste water even better than limits: Design and implementation of new system of waste water treatment from new plant that started operation at 2007. Optimization of control elements to lower contamination of waste water. New filter system for sludge excess Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Waste Water Emissions The rainfall water has an independent circuit: Emission point #2 IPPC permit established that water could only be sent at this emission point when it's QUIMICA raining and must be free of contaminants. CEPSA Química had made Investments to take residual water out of rainfall circuit. Implementation of Continuous Flow equipment that allows us to control that rainfall circuit only operates when it’s raining. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of Wastes IPPC permit established authorized Hazardous waste and regulations about its management. QUIMICA CQ has established techniques and operational controls to minimize wastes. New temporary warehouses has been built to gather the residues. Selective gathering of residues has been improved. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Control of soil and groundwater CQ has established techniques and operational controls to avoid this contamination. QUIMICA Special attention to storage: leak proofing of storage tanks, built over pedestal with leaks detectors, bunds, …. . Protection of land of Operational areas by use of waterproof concrete. Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements Other requirements stipulated in the permit Internal and external measurements, control and report of air emissions, waste water, wastes…(many of these are indicated on environmental legislation). QUIMICA Audits of compliance of requirements from IPPC permit by administration (each 2 years, measurements including). Establish obligation of Communication: environmental incidents/accidents, changes in process, productive stops…. Realization of annual report of “European Regulation on Pollutant Release and Transfer Registers (E-PRTR)”. Pagina 1 de 3 CEPSA Química

Environment-related operational costs and investments (MM €) YEAR 2005 2006 2007 2008 2009 2010 2011 INVESTMENTS 0, 184 0, 776 0, 501 0, 544 5, 281 1, 438 10, 024 OPERATIONAL COSTS 4, 963 6, 350 7, 867 8, 640 4, 942 5, 572 6, 274 Not including technical changes operational and security that have relation with environment. Not including Cogeneration Plant. Pagina 1 de 3 CEPSA Química

Consumption of water, calorific energy, electricity Pagina 1 de 3 CEPSA Química

IPPC DEVELOPMENT: requirements And now? Validity period of permit is 8 years (will expire in 2013): The documentation for renewal was presented in May, 2012 QUIMICA Requirements of new BREF and new legislation will be included (for example Industrial Emissions Directive) Will establish new BAT and emission levels associated (BAT-AELs): new investments. Will include references to raw materials and energy consumption. Pagina 1 de 3 CEPSA Química

THANKS QUIMICA Pagina 1 de 3 CEPSA Química