Properties of Solutions CA Standards Students know the

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Properties of Solutions

Properties of Solutions

CA Standards Students know the definitions of solute and solvent. Students know how to

CA Standards Students know the definitions of solute and solvent. Students know how to describe the dissolving process at the molecular level by using the concept of random molecular motion. Students know temperature, pressure, and surface area affect the dissolving process.

Classification of Matter Solutions are homogeneous mixtures

Classification of Matter Solutions are homogeneous mixtures

Solute A solute is the dissolved substance in a solution. Salt in salt water

Solute A solute is the dissolved substance in a solution. Salt in salt water Sugar in soda drinks Carbon dioxide in soda drinks Solvent A solvent is the dissolving medium in a solution. Water in salt water Water in soda

“Like Dissolves Like” Nonpolar solutes dissolve best in nonpolar solvents Fats Steroids Benzene Hexane

“Like Dissolves Like” Nonpolar solutes dissolve best in nonpolar solvents Fats Steroids Benzene Hexane Waxes Toluene Polar and ionic solutes dissolve best in polar solvents Inorganic Salts Sugars Water Small alcohols Acetic acid

Water’s Solvent Interactions The oxygen (slightly negative) end of the water molecule is attracted

Water’s Solvent Interactions The oxygen (slightly negative) end of the water molecule is attracted to the positive ion of a salt.

Water’s Solvent Interactions The hydrogen (slightly positive) end of the water molecule is attracted

Water’s Solvent Interactions The hydrogen (slightly positive) end of the water molecule is attracted to the negative ion of a salt.

Solubility Trends § The solubility of MOST solids increases with temperature. § The rate

Solubility Trends § The solubility of MOST solids increases with temperature. § The rate at which solids dissolve increases with increasing surface area of the solid. § The solubility of gases decreases with increases in temperature. § The solubility of gases increases with the pressure above the solution.

Therefore… Solids tend to dissolve best when: o Heated o Stirred o Ground into

Therefore… Solids tend to dissolve best when: o Heated o Stirred o Ground into small particles Gases tend to dissolve best when: o The solution is cold o Pressure is high

Solubility Chart

Solubility Chart

Definition of Electrolytes and Nonelectrolytes An electrolyte is: A substance whose aqueous solution conducts

Definition of Electrolytes and Nonelectrolytes An electrolyte is: A substance whose aqueous solution conducts an electric current. A nonelectrolyte is: A substance whose aqueous solution does not conduct an electric current.

Electrolytes vs. Nonelectrolytes The ammeter measures the flow of electrons (current) through the circuit.

Electrolytes vs. Nonelectrolytes The ammeter measures the flow of electrons (current) through the circuit. If the ammeter measures a current, and the bulb glows, then the solution conducts. If the ammeter fails to measure a current, and the bulb does not glow, the solution is non-conducting.

Try to classify the following substances as electrolytes or nonelectrolytes… 1. Pure water 2.

Try to classify the following substances as electrolytes or nonelectrolytes… 1. Pure water 2. Tap water 3. Sugar solution 4. Sodium chloride solution 5. Hydrochloric acid solution 6. Lactic acid solution 7. Ethyl alcohol solution 8. Pure sodium chloride

Answers to Electrolytes ELECTROLYTES: NONELECTROLYTES: Tap water (weak) Pure water Na. Cl solution Sugar

Answers to Electrolytes ELECTROLYTES: NONELECTROLYTES: Tap water (weak) Pure water Na. Cl solution Sugar solution HCl solution Ethanol solution Lactate solution (weak) Pure Na. Cl

Colligative Properties Colligative properties are those that depend on the concentration of particles in

Colligative Properties Colligative properties are those that depend on the concentration of particles in a solution, not upon the identity of those particles. q Boiling Point Elevation q Freezing Point Depression q Osmotic Pressure

Freezing Point Depression Each mole of solute particles lowers the freezing point of 1

Freezing Point Depression Each mole of solute particles lowers the freezing point of 1 kilogram of water by 1. 86 degrees Celsius. Boiling Point Elevation Each mole of nonvolatile solute particles raises the boiling point of 1 kilogram of water by 0. 51 degrees Celsius.