Petroleum Additives Global Technology Leader Global Technology Leader
![Petroleum Additives Global Technology Leader Petroleum Additives Global Technology Leader](https://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-1.jpg)
Petroleum Additives Global Technology Leader
![Global Technology Leader Synthetic Base Fluids and Petroleum Additives Base Fluids Poly Alpha Olefins Global Technology Leader Synthetic Base Fluids and Petroleum Additives Base Fluids Poly Alpha Olefins](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-2.jpg)
Global Technology Leader Synthetic Base Fluids and Petroleum Additives Base Fluids Poly Alpha Olefins Esters Phosphate Esters Aminic Antioxidants Additives Detergents Antiwear/EP Additives Corrosion Inhibitors Industrial Fluids Finished Fluids Refrigeration Fluids Fire-resistant Hydraulic Fluids Aerospace and Defense Fluids High-performance Greases Chemtura Confidential 2
![Innovating Through the Value Chain Key Industries Served Portfolio Synthetic Base Stocks Lubricant Additives Innovating Through the Value Chain Key Industries Served Portfolio Synthetic Base Stocks Lubricant Additives](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-3.jpg)
Innovating Through the Value Chain Key Industries Served Portfolio Synthetic Base Stocks Lubricant Additives Synthetic Finished Fluids Chemtura Confidential Industries Refrigeration/Power/Automotive Aviation General Industrial Automotive General Industrial Marine/Power/Other General Industrial Refrigeration Aviation 3
![Petroleum Additives Footprint Global Manufacturing, R&D & Sales Manufacturing Plants by Region North America Petroleum Additives Footprint Global Manufacturing, R&D & Sales Manufacturing Plants by Region North America](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-4.jpg)
Petroleum Additives Footprint Global Manufacturing, R&D & Sales Manufacturing Plants by Region North America Mapleton, IL East Hanover, NJ Fords, NJ Perth Amboy, NJ Gastonia, NC Elmira, Canada West Hill, Canada EMEA Latina, Italy Bergkamen, Germany Accrington, UK Trafford Park, UK Ankerweg, The Netherlands Asia/Pacific Nantong, China Kaohsiung, Taiwan Hyeongok, South Korea Nanjing*, China Global R&D Naugatuck CT, USA Applications Center Trafford Park UK Applications Center Nanjing China Applications Center West Hill CAN Latin America Rio Claro, Brazil Altamira, Mexico Reynosa, Mexico *Plant to be closed West Hill, Canada – R&D for Detergents Trafford Park, UK – R&D for Poly Alpha Olefins, Industrial Finished Fluids Chemtura Confidential 4
![Global R&D Center Naugatuck, USA Comprehensive Technology Testing Facilities • Tribology Testing • Titrations Global R&D Center Naugatuck, USA Comprehensive Technology Testing Facilities • Tribology Testing • Titrations](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-5.jpg)
Global R&D Center Naugatuck, USA Comprehensive Technology Testing Facilities • Tribology Testing • Titrations • Viscometrics • Deposits • Oxidation • Additive / Oil Compatibility Full Analytical Services • Spectroscopy & Chromatography Chemtura Confidential Outside ASTM Certified Lab Testing: • NOACK Volatility ASTM D 5800 • TEOST 33 C - ASTM D 6335 • Cu-Pb-Sn Corrosion ASTM D 6594 • Elastomer Testing ASTM D 7216, PV 3344 • Elastomer Testing PV 3344 5
![Naugatuck, USA Comprehensive Technology Testing Other Internal Analytical & Outside Testing Spectroscopy • NMR Naugatuck, USA Comprehensive Technology Testing Other Internal Analytical & Outside Testing Spectroscopy • NMR](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-6.jpg)
Naugatuck, USA Comprehensive Technology Testing Other Internal Analytical & Outside Testing Spectroscopy • NMR - Nuclear Magnetic Resonance (Proton and C 13) • FT-IR - Fourier Transform Infrared (Standard and Infrared Microscopy) • UV-Vis - UV-Visual Spectroscopy • X-Ray- X-Ray Fluorescence Elemental Analysis Mass Spectroscopy & Hyphenated Techniques • MS/MS - Tandem Mass Spectrometry Mas Spectrometry • HPLC-MS - High Performance Liquid Chromatography - Mass Spectrometry • GC-MS - Gas Chromatography – Mass Spectrometry Mass Spectroscopy & Hyphenated Techniques • GC - Gas Chromatography • GPC - Gel-Permeation Chromatography for Molecular weight determinations) • HPLC - High Performance Liquid Chromatography • Column, - Open Column – Extraction Chromatography Outside ASTM Certified Lab Testing: • ICP - Elemental Analysis - ASTM D 5185 Chemtura Confidential 6
![Lubricants Technology Development Center of Excellence, Trafford Park, UK • New purpose built ISO Lubricants Technology Development Center of Excellence, Trafford Park, UK • New purpose built ISO](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-7.jpg)
Lubricants Technology Development Center of Excellence, Trafford Park, UK • New purpose built ISO 9001 certified laboratory opened in 2014 • Providing technical service to our EMEA and Global businesses • Lubricant and Chemical industries • Lubricant oil formulation and blending • Lubricant analysis and bench testing • Additive Component R&D • Organic chemistry • Organo-phosphorous chemistry • Lubricant bench testing • Technology Network for additional Specialist Testing • In house using QC test labs and at other Chemtura facilities including Naugatuck, USA • Carefully selected third party UK and European facilities delierving, Physio-Chemical analysis, Flammability, Bench Testing and Rig Testing Chemtura Confidential 7
![Trafford Park, United Kingdom Facilities Comprehensive Technology Testing Test capabilities include the following test Trafford Park, United Kingdom Facilities Comprehensive Technology Testing Test capabilities include the following test](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-8.jpg)
Trafford Park, United Kingdom Facilities Comprehensive Technology Testing Test capabilities include the following test methods Test Method Kinematic viscosity ASTM D 445/ISO 3104 TAN and TBN ASTM D 664/ISO 6619 and ASTM D 4739 Water Content ISO 760 Foam ASTM D 892/ISO 6247 Water Separation ASTM D 1401/ISO 6614 Air and CO 2 Entrainment ASTM D 3427/ISO 9120 Flash point ASTM D 92 Volume resistivity ASTM D 1169/IEC 60247 Fourier Transform Infra-red Spectroscopy (FTIR) Thermo-Gravimetric Analysis (TGA) Pressurised Differential Scanning Calorimetry ASTM D 6186 (PDSC) • Added in 2015 - TA Instruments Q 20 Pressurised Differential Scanning Calorimeter (PDSC) • For testing the oxidative stability of lubricant formulations • In 2016 - we will be adding lubricity testing capability • 4 ball wear and EP Chemtura Confidential 8
![Antioxidents NAUGALUBE ® Antioxidents NAUGALUBE ®](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-9.jpg)
Antioxidents NAUGALUBE ®
![NAUGALUBE® Antioxidants for Lubricants NAUGALUBE® Aminic based Antioxidants Extensively used by formulators: -: Automotive, NAUGALUBE® Antioxidants for Lubricants NAUGALUBE® Aminic based Antioxidants Extensively used by formulators: -: Automotive,](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-10.jpg)
NAUGALUBE® Antioxidants for Lubricants NAUGALUBE® Aminic based Antioxidants Extensively used by formulators: -: Automotive, Industrial Aviation Marine Provide excellent inhibition in a vast array of mineral and synthetic based lubricants (oils & grease) NAUGALUBE® is manufactured at 4 Global locations – giving you security of supply Available in liquid, powder or flake form Chemtura Confidential 10
![NAUGALUBE® Product Range Physical Properties ANTIOXIDANT AMINE TYPE PHYSI CAL FOR M KINEMATIC VISCOSITY NAUGALUBE® Product Range Physical Properties ANTIOXIDANT AMINE TYPE PHYSI CAL FOR M KINEMATIC VISCOSITY](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-11.jpg)
NAUGALUBE® Product Range Physical Properties ANTIOXIDANT AMINE TYPE PHYSI CAL FOR M KINEMATIC VISCOSITY (mm 2/s) 40˚C 100˚C Flash Point COC (˚C) Specific Gravity 25/25˚C (g/l) TBN (mg. KOH/g) Nitrogen Content %wt. NAUGALUBE® 438 octylated diphenylamine Solid, waxy - - 275 0. 99 130 3. 6 NAUGALUBE® 438 L nonylated diphenylamine Liquid 580 17 220 0. 95 140 3. 5 NAUGALUBE® 750 octylated, butylated diphenylamine Liquid 320 10 216 0. 98 180 4. 6 NAUGALUBE® PANA Phenyl-αnaphthylamine Solid - - 214 1. 33 240 6. 4 NAUGALUBE® APAN Alkylated phenyl-αnaphthylamine Liquid -2 3 260 1. 02 150 3. 8 NAUGALUBE® AMS 4, 4’-bis (α, α-di-methylbenzyl) DPA Solid - - 270 1. 14 138 3. 4 Chemtura Confidential 11
![Detergents LOBASE HYBASE Detergents LOBASE HYBASE](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-12.jpg)
Detergents LOBASE HYBASE
![Anti-wear Additives NAUGALUBE® 810/812 DURAD® Anti-wear Additives NAUGALUBE® 810/812 DURAD®](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-13.jpg)
Anti-wear Additives NAUGALUBE® 810/812 DURAD®
![NAUGALUBE® 810/812 Alkyl Citrate Esters - For Automotive Applications Naugalube® 810 and Naugalube 812® NAUGALUBE® 810/812 Alkyl Citrate Esters - For Automotive Applications Naugalube® 810 and Naugalube 812®](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-14.jpg)
NAUGALUBE® 810/812 Alkyl Citrate Esters - For Automotive Applications Naugalube® 810 and Naugalube 812® are organic anti-wear additives specially developed for use in automotive engine oils to prolong engine life. Free from metals, sulfur and phosphorus these additives assist in sustaining the integrity of an engine’s catalytic converter. Naugalube® 812 molecular structure gives it an advantage for applications where operating temperatures may exceed 120 °C. Key benefits • • • Metal, Phosphorus & Sulfur free Synergistic with ZDDP No friction increase Anti-wear retention Liquid additive Chemtura Confidential 14
![DURAD® Anti-wear Additives The DURAD® product range is a series of phosphate ester fluids DURAD® Anti-wear Additives The DURAD® product range is a series of phosphate ester fluids](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-15.jpg)
DURAD® Anti-wear Additives The DURAD® product range is a series of phosphate ester fluids which can either be used as fire resistant functional fluids or as anti wear additives They are most commonly used in metal working and other industrial lubricant applications Very effective in reducing friction and wear in applications where high loads cause boundary lubrication conditions Chemtura Confidential 15
![DURAD® Anti-wear Additives DURAD® Ester Type Alkyl Phosphate Ester Tricresyl phosphate (TCP) Ester Iso-propylphenyl DURAD® Anti-wear Additives DURAD® Ester Type Alkyl Phosphate Ester Tricresyl phosphate (TCP) Ester Iso-propylphenyl](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-16.jpg)
DURAD® Anti-wear Additives DURAD® Ester Type Alkyl Phosphate Ester Tricresyl phosphate (TCP) Ester Iso-propylphenyl phosphate (IPPP) Ester Tert-butylphenyl phosphate (TBPP) Ester Trixylyl (TXP) Ester Chemtura Confidential Product Kinematic Viscosity @40 C (mm 2/s) DURAD® 40 DURAD® 48 3 6. 7 DURAD® 60 DURAD® 125 7. 9 27 DURAD® 125 Aviation DURAD® 125 L DURAD® 110 DURAD® 150 DURAD® 220 DURAD® 300 DURAD® 310 M DURAD® 110 B 21 -26 24 28 38 66 57 -66 26 DURAD® 150 B DURAD® 220 B DURAD® 620 B DURAD® 220 X 34 46 125 46 DURAD® 250 X 55 16
![Corrosion Inhibitors CALCINATES™ Corrosion Inhibitors CALCINATES™](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-17.jpg)
Corrosion Inhibitors CALCINATES™
![CALCINATE™ for Industrial, Grease and Metalworking Applications Wide range of products used for both CALCINATE™ for Industrial, Grease and Metalworking Applications Wide range of products used for both](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-18.jpg)
CALCINATE™ for Industrial, Grease and Metalworking Applications Wide range of products used for both corrosion inhibition and EP/AW performance Extensively used in Industrial, Metalworking and Grease applications Typically amorphous Calcium Carbonate used for applications where clarity is critical whilst the crystalline form is used when additional EP & AW performance is required Overbased products can offer effective EP and AW performance Chemtura Confidential Where enhanced corrosion inhibition is required Barium Sulphonates can be used 18
![CALCINATE™ Overbased Calcium Sulphonate Corrosion Inhibitors, Anti-wear & EP Additives Manufactured in the Netherlands CALCINATE™ Overbased Calcium Sulphonate Corrosion Inhibitors, Anti-wear & EP Additives Manufactured in the Netherlands](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-19.jpg)
CALCINATE™ Overbased Calcium Sulphonate Corrosion Inhibitors, Anti-wear & EP Additives Manufactured in the Netherlands PROPERTY CALCINATE NC C-300 CS CALCINATE C-300 R OTS OR CALCINATE C-400 CLR CALCINATE C-400 W PHYSICAL PROPERTIES Calcium Carbonate Form - Crystalline Sml Size Average Micelle size (nm) - 40 -80 10 -30 100 -200 TBN (mg. KOH/g) 30 285 305 405 385 Calcium (%wt. ) 2. 7 10. 5 12 12 15. 2 14. 5 Calcium Sulfonate (%wt. ) 44. 5 18. 5 28. 0 18. 5 17. 6 Calcium Carbonate (%wt. ) - 25 27 27 36 36 34 Viscosity @ 100°C (mm²/s) 55 100 75 75 - - - - 40, 000 Oil Content (%) 53 47 45 45 46 46 49 ASTM Colour (dilute) 5 5 5 5 Free Alkalinity <1 20 21 30 10 <1 20 Viscosity @ 25°C (c. Ps) Chemtura Confidential amorphous Crystalline Med Size 19
![Barium Sulphonates Enhanced Corrosion Inhibitors Surchem & Barinate Surchem 404 Barinate B-70 Calcium (%wt. Barium Sulphonates Enhanced Corrosion Inhibitors Surchem & Barinate Surchem 404 Barinate B-70 Calcium (%wt.](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-20.jpg)
Barium Sulphonates Enhanced Corrosion Inhibitors Surchem & Barinate Surchem 404 Barinate B-70 Calcium (%wt. ) 6. 6 14. 0 TBN (mg KOH/g) 4. 0 68. 0 Viscosity at 100°C (mm 2/s) 110 40 1. 000 1. 160 - Pass 1 b 1 b 1 b Pass Specific Gravity @ 15°C (kg/l) Water Demulsibility Copper Strip Corrosion Rust Chemtura Confidential Surchem 404 D 20
![High Viscosity PAO’s SYNTON® High Viscosity PAO’s SYNTON®](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-21.jpg)
High Viscosity PAO’s SYNTON®
![SYNTON® High Viscosity PAO Synthetic Base Fluids Chemtura Confidential SYNTON® 40 & 100 are SYNTON® High Viscosity PAO Synthetic Base Fluids Chemtura Confidential SYNTON® 40 & 100 are](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-22.jpg)
SYNTON® High Viscosity PAO Synthetic Base Fluids Chemtura Confidential SYNTON® 40 & 100 are high viscosity PAOs Have a high viscosity Index providing good low and high temperature performance Offer outstanding oxidation and thermal stability for extended oil drain intervals Used by formulators in top tier synthetic oils and greases wind turbines, industrial geared systems, automatic transmissions and other fully synthetic high viscosity driveline lubricants More consistent film thickness is provided from their inherent shear stability Proven industry standard with extensive formulary application experience 22
![SYNTON® Typical Physical Results SYNTON® PAO 40 TEST Kinematic Viscosity @40 o. C (mm SYNTON® Typical Physical Results SYNTON® PAO 40 TEST Kinematic Viscosity @40 o. C (mm](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-23.jpg)
SYNTON® Typical Physical Results SYNTON® PAO 40 TEST Kinematic Viscosity @40 o. C (mm 2/s) Kinematic Viscosity @100 o. C (mm 2/s) Pour Point (o. C) Flash Point (o. C) Specific Gravity 20/20 o. C (kg/l) Color (APHA) Bromine (ppm) Viscosity Index SYNTON® PAO 100 TEST Kinematic Viscosity @40 o. C (mm 2/s) Kinematic Viscosity @100 o. C (mm 2/s) Pour Point (o. C) Flash Point (o. C) Specific Gravity 20/20 o. C (kg/l) Color (APHA) Bromine (ppm) Viscosity Index Chemtura Confidential MINIMUM TYPICAL MAXIMUM TEST METHOD 380 39 266 0. 84 - 399 40 -36 288 0. 847 24 <20 152 430 41 -30 0. 850 50 50 - D 445 D 97 D 92 D 1209 XRF - MINIMUM TYPICAL MAXIMUM TEST METHOD 1200 98 280 0. 845 - 1250 100 -24 301 0. 847 24 <20 168 1350 102 -18 0. 855 50 70 - D 445 D 97 D 92 D 1209 XRF - 23
![SYNTON® Fast Facts and Key Benefits Heavy PAOs marketed under the SYNTON® brand Proven SYNTON® Fast Facts and Key Benefits Heavy PAOs marketed under the SYNTON® brand Proven](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-24.jpg)
SYNTON® Fast Facts and Key Benefits Heavy PAOs marketed under the SYNTON® brand Proven industry standard with extensive formulary application experience They are derived from 1 -Decene using Ziegler Natta Catalyst technology FDA 21 C FR 178. 3570 178. 3620 compliant Manufactured at 2 global locations - Elmira, Canada and Ankeweg, Netherlands Low volatility for lower oil consumption They provide excellent shear stability Chemtura Confidential High VI providing improved wear protection and better fuel efficiency Outstanding oxidation & thermal stability for extended oil drains 24
![Synthetic Esters HATCOL® Synthetic Esters HATCOL®](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-25.jpg)
Synthetic Esters HATCOL®
![HATCOL® Synthetic Esters They are used in a broad range of lubricant formulations including HATCOL® Synthetic Esters They are used in a broad range of lubricant formulations including](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-26.jpg)
HATCOL® Synthetic Esters They are used in a broad range of lubricant formulations including crankcase oils, air compressor oils, oven chain oils, gas turbine oils, transformer oils, refrigerator oils and grease HATCOL Synthetic Esters are extensively used in synthetic formulations to enhance high and low temperature performance, improve additive solubility, and increase lubricity The HATCOL range includes Monoester, Diester, Triester and Polyol Ester chemistry Chemtura Confidential 26
![HATCOL® Synthetic Esters (Sample of Portfolio) Monoesters Diesters Product Viscosity @ 40°C, c. St HATCOL® Synthetic Esters (Sample of Portfolio) Monoesters Diesters Product Viscosity @ 40°C, c. St](http://slidetodoc.com/presentation_image_h/79931ffdb5d5cb1c1f83ade12868c124/image-27.jpg)
HATCOL® Synthetic Esters (Sample of Portfolio) Monoesters Diesters Product Viscosity @ 40°C, c. St HATCOL 2976 2. 7 Chemistry Product Viscosity @ 40°C, c. St HATCOL 2906 HATCOL 3110 HATCOL 2901 Neopentyl glycol (NPG) esters Product Viscosity @ 40°C, c. St HATCOL 2957 7. 5 Chemistry Trimellitate Esters Product Viscosity @ 40°C, c. St 9. 1 HATCOL 2920 87 12 HATCOL 2941 213 14 HATCOL 2932 132 28 HATCOL 2940 310 Chemistry Trimethylolpropane (TMP) esters Pentaerythritol (PE) esters Product Viscosity @ 40°C, c. St HATCOL 2915 12 HATCOL 2377 HATCOL 2925 17 HATCOL 2938 19 HATCOL 2954 HATCOL 2352 HATCOL 3169 HATCOL 5068 Chemistry Product Viscosity @ 40°C, c. St Chemistry 20 24 29 33 64 Dipentaerythritol (Di. PE) esters Product HATCOL 2926 HATCOL 2999 HATCOL 2372 HATCOL 5150 HATCOL 3165 Chemtura Confidential Viscosity @ 40°C, c. St Chemistry 53 81 125 178 390 27
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