Nuclear Radiation Natural Radioactivity Nuclear Equations Producing Radioactive

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Nuclear Radiation Natural Radioactivity Nuclear Equations Producing Radioactive Isotopes Half-Life Nuclear Fission and Fusion

Nuclear Radiation Natural Radioactivity Nuclear Equations Producing Radioactive Isotopes Half-Life Nuclear Fission and Fusion 1

Subatomic Particles • Protons- plus charge In the nucleus • Neutrons- neutral • Electrons

Subatomic Particles • Protons- plus charge In the nucleus • Neutrons- neutral • Electrons - negative charge Outside the nucleus 2

Nuclear Symbols Mass number (p+ + no) Element symbol Atomic number (number of p+)

Nuclear Symbols Mass number (p+ + no) Element symbol Atomic number (number of p+) 3

RADIOACTIVITY • Nuclei of unstable isotopes called radioisotopes gain stability by undergoing changes •

RADIOACTIVITY • Nuclei of unstable isotopes called radioisotopes gain stability by undergoing changes • These changes are always accompanied by large amounts of energy • Discovery of radioactivity dealt a blow to Dalton’s theory that atoms are 4 indivisible

Radiation • Radiation comes from the nucleus of an atom. • Unstable nucleus emits

Radiation • Radiation comes from the nucleus of an atom. • Unstable nucleus emits a particle or energy alpha beta gamma 5

Alpha Particle Same as a helium nucleus (He) 4 2 He or Two protons

Alpha Particle Same as a helium nucleus (He) 4 2 He or Two protons Two neutrons 6

Beta Particle An electron emitted from the nucleus 0 e or 1 A neutron

Beta Particle An electron emitted from the nucleus 0 e or 1 A neutron in the nucleus breaks down 1 1 0 n H + e 0 1 -1 7

Gamma Radiation • Pure radiation • Like an X-ray but comes from the nucleus

Gamma Radiation • Pure radiation • Like an X-ray but comes from the nucleus 8

Radiation Protection • Shielding alpha – paper, clothing beta – lab coat, gloves gamma-

Radiation Protection • Shielding alpha – paper, clothing beta – lab coat, gloves gamma- lead, thick concrete • Limit time exposed • Keep distance from source 9

Radiation Protection 10

Radiation Protection 10

Balancing Nuclear Equations In the reactants and products Atomic numbers must balance and Mass

Balancing Nuclear Equations In the reactants and products Atomic numbers must balance and Mass numbers must balance 11

Alpha decay 12

Alpha decay 12

Beta decay 234 Th 90 ® 234 Pa 91 + 0 e 1 beta

Beta decay 234 Th 90 ® 234 Pa 91 + 0 e 1 beta particle 13

Gamma radiation No change in atomic or mass number 11 B 5 5 +

Gamma radiation No change in atomic or mass number 11 B 5 5 + 0 0 boron atom in a high-energy state 14

Types of Radioactive Decay vgamma ray production ( ): • v 0 vpositron production

Types of Radioactive Decay vgamma ray production ( ): • v 0 vpositron production 1 e : • velectron capture: (inner-orbital electron is captured by the nucleus) 15

Types of Radiation 16

Types of Radiation 16

Learning Check NR 1 Write the nuclear equation for the beta emitter Co-60. 17

Learning Check NR 1 Write the nuclear equation for the beta emitter Co-60. 17

Solution NR 1 Write the nuclear equation for the Beta emitter Co-60. 60 Co

Solution NR 1 Write the nuclear equation for the Beta emitter Co-60. 60 Co 60 Ni 27 28 + 0 e -1 18

Half-Life of a Radioisotope The time for the radiation level to fall (decay) to

Half-Life of a Radioisotope The time for the radiation level to fall (decay) to one-half its initial value decay curve initial 1 half-life 8 mg 4 mg 2 2 mg 3 1 mg 19

Examples of Half-Life Isotope C-15 Ra-224 Ra-223 I-125 C-14 U-235 Half life 2. 4

Examples of Half-Life Isotope C-15 Ra-224 Ra-223 I-125 C-14 U-235 Half life 2. 4 sec 3. 6 days 12 days 60 days 5700 years 710 000 years 20

Learning Check NR 3 The half life of I-123 is 13 hr. How much

Learning Check NR 3 The half life of I-123 is 13 hr. How much of a 64 mg sample of I-123 is left after 26 hours? 21

Solution NR 3 t 1/2 = 13 hrs 26 hours = 2 x t

Solution NR 3 t 1/2 = 13 hrs 26 hours = 2 x t 1/2 Amount initial = 64 mg Amount remaining = 64 mg x ½ = 16 mg 22

Nuclear Fission large nuclei break up 235 U 92 + 1 n 0 139

Nuclear Fission large nuclei break up 235 U 92 + 1 n 0 139 Ba 56 + 94 Kr 36 + 3 1 n + Energy 0 23

Fission 24

Fission 24

Nuclear Fusion small nuclei combine 2 H 1 + 3 H 4 He 1

Nuclear Fusion small nuclei combine 2 H 1 + 3 H 4 He 1 2 + 1 n + Energy 0 Occurs in the sun and other stars 25

Learning Check NR 4 Indicate if each of the following are (1) Fission (2)

Learning Check NR 4 Indicate if each of the following are (1) Fission (2) fusion A. B. C. D. Nucleus splits Large amounts of energy released Small nuclei form larger nuclei Hydrogen nuclei react Energy 26

Solution NR 4 Indicate if each of the following are (1) Fission (2) fusion

Solution NR 4 Indicate if each of the following are (1) Fission (2) fusion A. B. C. D. 1 1+2 2 2 Nucleus splits Large amounts of energy released Small nuclei form larger nuclei Hydrogen nuclei react 27

Energy and Mass Nuclear changes occur with small but measurable losses of mass. The

Energy and Mass Nuclear changes occur with small but measurable losses of mass. The lost mass is called the mass defect, and is converted to energy according to Einstein’s equation: DE = Dmc 2 Dm = mass defect DE = change in energy c = speed of light Because c 2 is so large, even small amounts of mass are converted to enormous amount of energy. 28