National 5 Chemistry Unit 2 Natures Chemistry Section
- Slides: 80
National 5 Chemistry Unit 2 – Nature’s Chemistry Section 6 – Homologous Series
Section 6 – Homologous Series Pupils should be able to… • State that hydrocarbons are compounds of hydrogen and carbon • Define a homologous series • State that alkanes are a homologous series of saturated hydrocarbons • Define saturated hydrocarbons as having single carbon-carbon bonds • Represent the alkanes by a general formula • Describe the pattern of physical properties of a homologous series such as melting and boiling points. • State common uses of alkanes, chemical and physical properties • Explain this pattern of physical properties in relation to the increasing strength of intermolecular forces as molecular size increases
What are Hydrocarbons? • A hydrocarbon is a molecule which contains only the elements Carbon and Hydrogen. • Hydrocarbons are obtained from the Fractional Distillation of crude oil. We use them for fuels in cars (octane) and in cookers (methane).
How do we Group all these Hydrocarbons Together?
What is a Homologous Series? Homologous Series • A group of chemically similar compounds which can be represented by a general formula. • Physical properties change gradually as you go down the series There are three groups that we are going to look at 1. Alkanes 2. Alkenes 3. Cycloalkanes
Alkanes Methane Monsters Ethane Eat Propane Pupils Butane But Pentane Prefer Hexane Hairy Heptane Haggis Octane Occasionally
Alkane Structure 3 D Full Structural Formula 2 D Full Structural Formula
Alkanes • Each member can be represented in three different ways: Methane Propane • Full Structural Formula • Shortened Structural Formula • Molecular Formula
Alkane Information • The Alkanes are a family of hydrocarbons and all share the same chemical properties: • Single Carbon to carbon bonds (- C – C -) • They are insoluble in water • Burn in oxygen to produce carbon dioxide and water • All end in -‘ane’ • Saturated hydrocarbons • All share a General Formula
Trends of the Alkanes Alkane (Carbon Atoms) Molecular Formula Methane (1) CH 4 Ethane (2) C 2 H 6 Propane (3) Shortened Structural Formula CH 4 CH 3 C 3 H 8 CH 3 CH 2 CH 3 Full Structural Formula Boiling Point -164 - 89 - 42
Trends of the Alkanes Alkane (Carbon Atoms) Molecular Formula Shortened Structural Formula Butane C 4 H 10 CH 3 CH 2 CH 3 -1 Pentane (5) C 5 H 12 CH 3 CH 2 CH 3 36 Hexane (6) C 6 H 14 CH 3 CH 2 CH 3 69 (4) Full Structural Formula Boiling Point
Trends of the Alkanes Alkane (Carbon Atoms) Molecular Formula Shortened Structural Formula Heptane (7) C 7 H 16 Octane (8) C 8 H 18 CH 3 CH 2 CH 2 CH 2 CH 2 CH 3 Full Structural Formula Boiling Point 8 126 9
Alkane Trend Summary Name Formula Melting Point (°C) Boiling Point (°C) Physical State Methane CH 4 -182 -164 Gas Ethane C 2 H 6 -183 -89 Gas Propane C 3 H 8 -190 -42 Gas Butane C 4 H 10 -138 -1 Gas Pentane C 5 H 12 -130 36 Liquid Hexane C 6 H 14 -95 69 Liquid
Alkanes General Formula The no. of Hydrogen atoms = 2 times the number of Carbon atoms plus 2 General Formula for alkanes is Cn. H 2 n+2
Alkanes – Physical Properties • M. p/B. p – gradual increase from methane to octane • Viscosity - increases as you move down the group • Colour – darker in colour as you move down the group • Density – less dense than water
Intermolecular Forces between Molecules • Larger molecules have more places for intermolecular forces. • More intermolecular forces requires more energy to overcome these forces thus the larger the molecule the higher the melting and boiling point.
Uses of Alkanes Name of Alkane Use Methane Fuel for cooking and heating Butane Used in barbecues and camping stoves Octane One of the compounds in petrol https: //www. bbc. co. uk/bitesize/guides/zw 4 tw 6 f/revision/1
Section 6 – Homologous Series Pupils should be able to… • State that alkenes are a homologous series of unsaturated hydrocarbons • State that alkenes contain the C = C double bond • State common uses of alkenes, chemical and physical properties • Represent the alkenes by a general formula • Write molecular as full and shortened formula
Alkenes X Ethene Propene Butene Pentene Hexene Heptene Octene Monsters Eat Pupils But Prefer Hairy Haggis Occasionally
Alkene Structure • 3 D Full Structural 2 D Full Structural Formula
Alkenes • Each member can be represented in three different ways: Ethene Propene • Full Structural Formula • Shortened Structural Formula • Molecular Formula
Alkenes • The Alkenes are a family of hydrocarbons and all share the same chemical properties: • Double Carbon to carbon bonds (-C=C-) • All end in -‘ene’ • Unsaturated hydrocarbons • All share a General Formula
Trends of Alkenes Alkene (Carbon Atoms) Molecular Formula Shortened Structural Formula Full Structural Formula Boiling Point Ethene (2) C 2 H 4 CH 2=CH 2 -104 Propene (3) C 3 H 6 CH 2 =CHCH 3 -48 Butene (4) C 4 H 8 CH 2=CHCH 2 CH 3 -6
Trends of Alkenes Alkene (Carbon Atoms) Molecular Formula Shortened Structural Formula Full Structural Formula Boiling Point Pentene (5) C 5 H 10 CH 2=CHCH 2 CH 3 30 Hexene (6) C 6 H 12 CH 2=CHCH 2 CH 3 63
Trends of Alkenes Alkene (Carbon Atoms) Molecular Heptene C 7 H 14 CH 2=CHCH 2 CH 3 C 8 H 16 CH 2=CHCH 2 CH 2 CH 3 (7) Octene (8) Formula Shortened Structural Formula Full Structural Formula Boiling Point 93 123
Alkene Trend Summary Name Formula Melting Point (°C) Boiling Point (°C) Ethene C 2 H 4 -169 -104 Propene C 3 H 6 -185 -48 Butene C 4 H 8 -185 -6 Pentene C 5 H 10 -138 30 Hexene C 6 H 12 -140 63
Alkene General Formula The no. of Hydrogen atoms = 2 x the number of Carbon atoms General Formula for alkenes is Cn. H 2 n
Properties of Alkenes • Physical Properties • The alkenes increase in size down the group • Their melting and boiling points increase down the group • Chemical Properties • All burn completely to produce carbon dioxide and water • Undergo addition reactions
Uses of Alkenes • Making polymers (plastics) • Industrial production of ethanol • Fuels • Solvents https: //www. bbc. co. uk/bitesize/guides/zw 4 tw 6 f/revision/3
Section 6 – Homologous Series Pupils should be able to… • State that cycloalkanes are a homologous series of saturated cyclic hydrocarbons • State common uses of cycloalkanes, chemical and physical properties • Represent the cycloalkanes by a general formula
Cycloalkanes Information • Cycloalkanes are a homologous series of cyclic hydrocarbon Uses Cyclohexane for making nylon Solvents for compounds that don’t dissolve in water Used in motor oil, kerosine, diesel and other heavy oils
Cycloalkanes X X Cyclopropane Cyclobutane Cyclopentane Cyclohexane Cycloheptane Cyclooctane Monsters Eat Pupils But Prefer Hairy Haggis Occasionally
Cycloalkane Structure • 3 D Full Structural 2 D Full Structural Formula
Cycloalkanes • Each member can be represented in three different ways: Cyclopropane • Full Structural Formula • Shortened Structural Formula • Molecular Formula
Cycloalkanes Information • The Cycloalkanes are a family of hydrocarbons and all share the same chemical properties: • Single Carbon to carbon bonds (-C–C-) • All end in -‘ane’ • Saturated hydrocarbons • All share a General Formula • Instead of forming straight chain molecules they form circular or cyclical molecules. • Burn to produce carbon dioxide and water • Cycloalkanes are isomers of alkenes
Physical Properties • They increase in size • The m. p/b. p increases as the size increases
Trends in Cycloalkanes Cycloalkane (Carbon Atoms) Molecular Formula Shortened Structural Formula C 3 H 6 CH 2 CH 2 Cyclobutane (4) C 4 H 8 CH 2 CH 2 Cyclopentane C 5 H 10 Cyclopropane (3) (5) CH 2 CH 2 Full Structural Formula
Trends in Cycloalkanes Cycloalkane (Carbon Atoms) Cyclohexane (6) Molecular Shortened Structural Full Structural Formula C 6 H 12 Cycloheptane (7) C 7 H 14 Cyclooctane C 8 H 16 (8) CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2
Cycloalkane Trend Summary Name Formula Melting Point (°C) Boiling Point (°C) Cyclopropene C 3 H 6 -126. 6 -33 Cyclobutane C 4 H 8 -90 13 Cyclopentane C 5 H 10 -94 49 6. 5 81 Cyclohexane C 6 H 12
Cycloalkanes – General Formula The number of Hydrogen atoms = 2 times the number of Carbon atoms General Formula for cycloalkanes is Cn. H 2 n https: //www. bbc. co. uk/bitesize/guides/zw 4 tw 6 f/revision/4
Section 6 – Homologous Series Pupils should be able to… • Describe how to distinguish an unsaturated and saturated compound using bromine solution • State that alkenes can undergo addition reactons: • With hydrogen forming alkanes, known as hydrogenation • With halogens forming dihaloalkanes • With water forming alcohols known as hydration
How can we tell these Hydrocarbons apart? We need to be able to experimentally tell whether a hydrocarbon is an alkane, an alkene or even a cycloalkane so how might we do this? What chemical property do they have that is different that we may be able to exploit? Answer: the reactive C=C bond which we can break. We use the Bromine Test.
Testing for Saturation Collect: goggles, three test tubes, bromine solution, test tube rack, an alkane, alkene and cycloalkane for testing. Method: add 2 cm 3 alkane to a test tube then add in a few drops of bromine water, shake and observe what happens Repeat with the alkene and the cycloalkane then record your results in a table.
Hydrocarbon Result Saturated/ Unsaturated Alkane Alkene Cycloalkane Conclusion: very Alkanes decolourise red/brown bromine solution _______ slowly therefore alkanes are saturated hydrocarbons. _______ Alkenes decolourise red/brown bromine solution quickly therefore alkenes are unsaturated ____ hydrocarbons
Testing for Unsaturation Alkane + Bromine Cycloalkane + Bromine Alkene + Bromine
Why?
Addition Reaction Dihaloalkane Pentene Bromine Colourless Red/Orange 1, 2 -dibromopentane Colourless This is called an Addition Reaction
Addition Reaction Hydrogenation Pentene Hydrogen Pentane
Addition Reaction Hydration Pentene Water Pentanol
Saturation Summary • We can use Bromine solution to test for unsaturation in an addition reaction • Alkanes are saturated hydrocarbons. Alkanes decolourise red/brown bromine solution very slowly • Alkenes are unsaturated hydrocarbons. Alkenes decolourise red/brown bromine solution quickly
The Problem…. • Three liquid hydrocarbons have the same general formula…. . or do they? • Design an experiment to determine which homologous series each hydrocarbon belongs to. • Draw the structure of the saturated molecule with 6 carbons • Draw the structure of the unsaturated molecule, with 6 carbons
Section 6 – Homologous Series Pupils should be able to… • Systematically name straight and branched chain alkanes and alkenes • Draw structural formula from the systematic names of straight chain and branched alkanes and alkenes • Systematically name non-branched cycloalkanes
Naming Alkanes 1. Find the longest chain which will form the last part of the name. 2. Number the main chain so that it gives the lower number over positions to the side groups. 3. Side branch names end in “yl” and depend on the number of carbon atoms in them; 1 = methyl 2 = ethyl 3 = propyl etc 4. Alphabetically order is used if different side branches appear in the same structure e. g. ethyl before methyl 5. Hyphens are used before or after numbers that come next to letters within a name e. g. (2 -ethyl-3 -methyl…. . ) 6. Commas are used between numbers if there is more than one of the same side branch (e. g. 2, 3, 3 – trimethyl…. )
Name each of these Straight Chain Alkanes It has a chain of three carbon atoms and only single carbon to carbon bonds so this makes it propane It has a chain of 8 carbon atoms and only single carbon to carbon bonds so this makes it Octane
Naming Straight Chain Alkenes 1. Find the longest chain which contains the double bond, this will form the last part of the name. 2. Number the main chain so that it gives the lowest number for the double bond over positions to the side groups. 3. Side branch names end in “yl” and depend on the number of carbon atoms in them; 1 = methyl 2 = ethyl 3 = propyl etc 4. Alphabetically order is used if different side branches appear in the same structure e. g. ethyl before methyl 5. Hyphens are used before or after numbers that come next to letters within a name e. g. (2 -ethyl-3 -methyl…. . ) 6. Commas are used between numbers if there is more than one of the same side branch (e. g. 2, 3, 3 – trimethyl…. )
Name each of these Straight Chain Alkanes It has a chain of three carbon atoms and only single carbon to carbon bonds so this makes it propane It has a chain of 8 carbon atoms and only single carbon to carbon bonds so this makes it Octane
Name each of these Straight Chain Alkenes Pent-1 -ene It has a chain of 5 carbon atoms and 1 double bond which makes it pentene Pent-2 -ene It has a chain of 5 carbon atoms and 1 double bond which also makes ithis pentene Because these molecules have different structures we must give them different names
How to Name this Branched Alkane C 5 C 4 C 3 C 2 C 1 C 2 -methylpentane l l l Longest chain = 5 – pentane Number the Carbon chain so that the branch is on the lowest carbon position – 2 Name the branch chain – methyl
Branched Alkanes Straight-chain hydrocarbon – all C atoms linked in a single continuous chain Find and name the longest chain: Systematic Naming heptane Find and name each chain branch: H H C H H 1 2 C C H 3 C 4 ethyl H H H 5 6 H H C H H methyl 7 C C C H H C H Branched-chain hydrocarbon – one or more side chains of C atoms emerge from main chain Number from end nearest chain branch: Assign a number to each chain branch: 5 -ethyl-2, 2 -dimethylheptane
H Examples H H C H H H H C C H H H C H 2, 3 -dimethylpentane H H H H C H H H H H C C C H H H C H 2 -methylhexane H C C H C H H H 3 -ethyl-2, 4 -dimethylhexane Formulae from Names H H C H 5 -ethyl-2 -methylheptane H H H C H H H C C C C H H H 4, 4 -dimethyloctane H C C C H H H H C C H H
Naming Branched Alkenes Isomers are compounds with the same molecular formula but different structural formulae Systematic Naming H H 4 3 2 H H C C H H 1 Find the longest chain containing the C=C and but give its prefix: Number from the end nearest C=C: Insert lowest number for C=C between prefix and the ending ‘ene’: but-1 -ene Number and name any branches as for alkanes: Isomers of but-1 -ene H H H C C H H H but-2 -ene H C H C C H H 2 -methylpropene
Section 6 – Homologous Series Pupils should be able to… • State the definition of an isomer • Understand that an isomer may belong to different homologous series • Describe how isomers may have different physical properties • Be given the structural formula for a compound, be able to draw an isomer • Use a molecular formula to draw isomers
Isomers of Alkanes Isomers have the same molecular formula but different structural formulas A molecular formula shows how many atoms of each element is present in the molecule A structural formula shows how the atoms are arranged in the molecule
Butane C 4 H 10 A molecular formula shows how many atoms of each element is present in the molecule Butane 2 -methylpropane A structural formula shows how the atoms are arranged in the molecule
Isomers of Butane 2 -methylpropane are • Butane Bothand Molecules contain isomers of each other as they have 4 carbon atomsformula but the same molecular different structural formulas • Both Molecules contain 10 hydrogen atoms 2 -methylpropane
Isomers of Alkanes • Isomers are molecules that have the same molecular formula but different structural formulas Number of possible isomers for the alkanes Number of Carbons Possible Isomers 1 -3 1 4 2 5 3
Isomers of Alkenes e. g. Butene C 4 H 8 A molecular formula shows how many atoms of each element is present in the molecule A structural formula shows how the atoms are arranged in the molecule
Isomers of Butene • All three molecules have 4 carbon atoms and 8 hydrogen atoms 1 -Butene 2 -Butene • They all have the same molecular formula but different structural formula • Firstly we number the longest chain of carbon atoms including the double bond • Number the carbon atoms so that the double bond has the lowest number in the chain 2 -methyl-1 -propene https: //www. bbc. co. uk/bitesize/guides/zw 4 tw 6 f/revision/5
Question 1 Identify: a) Octane A b) Propane E c) Ethane B
Question 2 Explain what is meant by: a) A saturated hydrocarbon b) An unsaturated hydrocarbon
Question 3 Consider this list of hydrocarbons Butane, Ethene, Octane, Methane, Butene Name the hydrocarbons which are a) Saturated b) Unsaturated
Question 4 State the molecular formula for each of the following straight chain hydrocarbons a) Octane b) Hexene c) The saturated hydrocarbon with 12 carbon atoms per molecule d) The unsaturated hydrocarbon with 10 carbon atoms per molecule
Question 5 Name each of the following molecules: a) c) d) b)
Question 6 • Which bond is present in molecules of heptene but not those in of heptane?
Question 7 • Two bottles contain a different hydrocarbon, one is saturated and the other is unsaturated. Explain how to find out which is which.
Question 8 C 2 H 4 + H 2 X What is the molecular formula and name of substance X?
Question 9 a) Explain the meaning of the following terms: i) Isomer ii) Homologous series b) Give an example of a reaction that butene and cyclobutane would undergo
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