Nano FASE INSPIRED cooperation Christa Schimpel 1 INSPIRED

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Nano. FASE - INSPIRED cooperation Christa Schimpel 1 (INSPIRED) Claus Svendsen 2 (Nano. FASE)

Nano. FASE - INSPIRED cooperation Christa Schimpel 1 (INSPIRED) Claus Svendsen 2 (Nano. FASE) 1 2 Bio. Nano. Net Forschungsgesellschaft mb. H, Austria Natural Environment Research Centre (NERC), UK Workshop on SAFETY ASPECTS IN PILOT LINES an EPPN-NSC i 2 L joint session 7 th November 2018| Grenoble| France

Outline (1) Introduction & Project Presentations of INSPIRED and Nano. FASE - Overview of

Outline (1) Introduction & Project Presentations of INSPIRED and Nano. FASE - Overview of both Safety Assessment Approaches incl. Gap Analysis and Challenges (2) Connecting INSPIRED & Nano. FASE – Identification of harmonisation potential of the different tools (connecting the tools/strategies with each other) to benefit from synergies – Introducing the planned case study

INSPIRED – Overall Concept The core of the R&D activities of the INSPIRED project

INSPIRED – Overall Concept The core of the R&D activities of the INSPIRED project are • Nanomaterial - Industrial Scale Production – the development of independent synthesis routes for the nanocopper, Ag. NW and graphene (lab scale and then industrial scale quantities for end users) • High Volume Printing Production Processes – development and optimisation of the high throughput printing systems (inkjet for nano-copper, screen and gravure for Ag. NW and the one step interconnect process pioneered by M-Solv) • Exemplar End Use Applications – demonstration of the functional nanomaterials within three exemplar end use systems (relevant industrial environments)

INSPIRED – Overall Concept INSPIRED aims to scale-up the whole value chain to ensure

INSPIRED – Overall Concept INSPIRED aims to scale-up the whole value chain to ensure the availability of nano-based functionalised inks in industrial scale quantities to produce novel printed electronic components for a wide variety of end-user product. Nanosafety assessment is involved in ALL process steps

INSPIRED - Nanosafety Approach Schimpel, Christa, et al. "A methodology on how to create

INSPIRED - Nanosafety Approach Schimpel, Christa, et al. "A methodology on how to create a real-life relevant risk profile for a given nanomaterial. " Journal of Chemical Health and Safety (2017).

Nano. FASE – Overall Concept

Nano. FASE – Overall Concept

Nano. FASE – The product value chain

Nano. FASE – The product value chain

Nano. FASE – Our Industry partners INDUSTRIAL PARTNERS HEMPEL Antifouling Paints PROMETHEAN PARTICLES NPs

Nano. FASE – Our Industry partners INDUSTRIAL PARTNERS HEMPEL Antifouling Paints PROMETHEAN PARTICLES NPs synthesis Cu 2 O, Cu, Zn. O (Cu. O, Ce. O 2) TUL Soil and water remediation INOTEX Textiles Ag, Ti. O 2 AMEPOX Conductive inks Ag FCCCO Roads coating Ti. O 2 APPNANO Additives for anaerobic digesters Fe 3 O 4 Fe 0

Nano. FASE – Silver inks for Electronics Pristine NMs Ag dispersed in organic solvent

Nano. FASE – Silver inks for Electronics Pristine NMs Ag dispersed in organic solvent NEP Conductive inks. Printed / flexible electronics. Relevant (env. ) End-of-life: Recycling, e-waste or Landfilling if not properly managed. compartments Other NFs Ag (PVP), Ag (parafin)

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS

PATHWAY ANALYSIS D BEYOND: ion missions. at or pl ex e ac TO INFINITY

PATHWAY ANALYSIS D BEYOND: ion missions. at or pl ex e ac TO INFINITY AN sp el op pr smart sail concept to “ ce ee Fl for Ink Jet systems n er de lv ol si G h it he w “T k in d an er EPOX nano size silv ings on the sail. at co lic al Nano. FASE partner AM et m of n io at circuits and applic use in printed control

Nano. FASE – Cu. O Antifouling paint Pristine NMs Cu and Cu 2 O

Nano. FASE – Cu. O Antifouling paint Pristine NMs Cu and Cu 2 O in both nano and macro size (Cu 2 O macro is the current commercial NF). Industrial producers. Also sub-micron Zn. O. NEP Antifouling paint for application on boats (fresh and saline water). Trialling 4 Different New formulations. Relevant (env. ) Sea / fresh water. Release during use (Cu 2+ release) compartments End-of-life: e. g. paint dust WWTP, empty cans landfill or incinerated Other NFs Cu, Cu. O (uncoated) and Cu-PVP have been distributed.

Nano. FASE – Cu. O Antifouling paint ENVIRONMENT Sea water

Nano. FASE – Cu. O Antifouling paint ENVIRONMENT Sea water

Nano. FASE – Working with industry

Nano. FASE – Working with industry

Nano. FASE – Working with industry WHAT NEEDS SHARING TO MAKE IT WORK? The

Nano. FASE – Working with industry WHAT NEEDS SHARING TO MAKE IT WORK? The immediate details about the product itself we would like to know are: A picture of the nano material and product itself if possible The dimensions and constituents of the nano material The processes NM is included in the final product (i. e. coating techniques …) Samples of the product itself and the NMs used in the formulation • characterization of the start materials and “as in product” material • comparison with the characterization of the released materials during the use and end-of-life processes. • Any characterization and information that can be share will save time. • So the start is nearly always the “Memorandum of Understanding”, always difficult. • •

Connecting Nano. FASE and INSPIRED Legal Checkpoint Idea Market Nano-Inks Innovator Safety Expert Safety

Connecting Nano. FASE and INSPIRED Legal Checkpoint Idea Market Nano-Inks Innovator Safety Expert Safety Regulatory Expert Benefiting from synergies between the 2 projects, a safer product/process will be enabled; risks that could probably impact on downstream users in the lifecycle are eliminated/minimised/controlled during design/manufacturing stages.

THANK YOU for your attention! Christa Schimpel Bio. Nano. Net Forschungsgesellschaft mb. H, Austria

THANK YOU for your attention! Christa Schimpel Bio. Nano. Net Forschungsgesellschaft mb. H, Austria Contact: christa. schimpel@bionanonet. at Tel. : +43 (0)699 155 266 06 Web: www. bionanonet. at Claus Svendsen NERC-Centre for Ecology and Hydrology, UK Contact: csv@ceh. ac. uk Tel. : +44 (0)1491 692672 Web: www. nanofase. eu