MULTIPLE REACTIONS Lecturer Zulfakar Mokhtar Introduction 1 Types
- Slides: 58
MULTIPLE REACTIONS Lecturer: Zulfakar Mokhtar
� Introduction 1. Types of Reactions 2. Selectivity & Yield � Maximizing the Desired Product 1. Parallel Reactions - for one reactant - for two reactants 2. Series Reactions � Algorithm for solving Reaction Eng. Problems
TYPE OF REACTIONS � Parallel � Series reactions � Complex reactions (parallel and series reactions) � Independent reactions
� Identify the type of reactions 1. The oxidation of ethylene to ethylene oxide: 2. The reaction of ethylene oxide (EO) with ammonia to form monoethanolamine, diethanolamine and triethanolamine:
3. Formation of butadiene from ethanol: 4. The cracking of crude oil to form gasoline:
DESIRED & UNDESIRED REACTION
SELECTIVITY & YIELDS Selectivity : the ratio of (reaction rate @ molar flowrate) of desired product to the (reaction rate @ molar flowrate) of undesired product Instantaneous selectivity Overall selectivity Yield : the ratio of (reaction rate @ molar flowrate) of desired product formed to the (reaction rate/ @ molar flowrate) the reactant either fed or consumed Instantaneous yield Overall yield Batch flow
PARALLEL REACTIONS � Selectivity for single reactant system Thus, Consider some of reactor operating scenarios to maximize the selectivity ( SD/U (max) )
Need high CA to favor D production ( to increase selectivity) CA ~ SD/U CA will always start at high value CA in a perfectly mixed CSTR is always at its lowest value
Need low CA to favor D production ( to increase selectivity) CA ~ SD/U CA in a perfectly mixed CSTR is always at its lowest value
So, CA cannot be used as operating parameters to maximize the selectivity Thus the solution is: Thus, to achieve high selectivity: E = Activation Energy reca l l * higher energy requires higher temperature
� Selectivity for two reactant system For high SD/U, maintain both CA and CB as high as possible - refer Figure 6. 3(c) - refer Figure 6. 3(b)
For high SD/U, maintain high CA and low CB - refer Figure 6. 3(d) -refer Figure 6. 3(f) - - refer Figure 6. 3(h)
For high SD/U, maintain both CA and CB as low as possible - refer Figure 6. 3(a) - Tubular reactor with large recylce ratio - refer Figure 6. 3(i)
For high SD/U, maintain low CA and high CB - refer Figure 6. 3(e) - refer Figure 6. 3(g) - refer Figure 6. 3(h)
ALGORITHM FOR MULTIPLE REACTIONS
ALGORITHM FOR COMPLEX REACTIONS
Continue….
Continue….
Net Rate of Formation of A:
In multiple reactions:
Example
Example
Example
The net rate of formation of NO is:
The net rate of formation of N 2 is:
The net rate of formation of O 2 is:
SERIES REACTIONS Maximizing the desired product : Increase the selectivity of Desired (D) in series reactions
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