MOF overview MOF recent review issue http newsroom

MOF overview

MOF recent review issue http: //newsroom. ucla. edu/portal/ucla/srpview. aspx? id=105680 http: //pubs. acs. org/toc/chreay/112/2

Nets derived from the net of the primitive cubic lattice (pcu). Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets Michael O’Keeffe *†‡ and Omar M. Yaghi *‡§ Chem. Rev. , 2012, 112 (2), pp 675– 702 DOI: 10. 1021/cr 200205 j

SBUs Figure 5. (a) The Re 6 Se 8(CN)6 unit. (b) The same abstracted as an octahedral SBU. Chem. Rev. , 2012, 112 (2), pp 675– 702

Linkers Chem. Rev. , 2012, 112 (2), pp 675– 702

Science 18 January 2002: Vol. 295 no. 5554 pp. 469 -472 DOI: 10. 1126/science. 1067208

Intergrown nets Figure 4: Catenation of rings in nets intergrown with their dual structures. The nets are shown augmented with triangles at the threecoordinated vertices and octahedra at the six-coordinated vertices. a, A pair of identical rings in the self-dual pyr net of MOF-150 (ref. 11). b, A six-membered ring of the qom net (red) of MOF-177 catenated with a ring of the dual net (blue). A pair of three-coordinated vertices are directly linked, as are pairs of sixcoordinated vertices. Nature 427, 523 -527 (5 February 2004) | doi: 10. 1038/nature 02311; Received 9 September 2003; Accepted 16 December 2003

Microstructures http: //www. mf. mpg. de/de/abteilungen/schuetz/ Figure 14. (a) Top- and (b) cross-sectional view the ZIF-8 membrane synthesized by secondary growth technique. Reproduced with permission from ref 278 Chem. Rev. , 2012, 112 (2), pp 933– 969

Properties Nature Communications 3(604), 2012; DOI: 10. 1038/ncomms 1618 Crystal structure of zinc-adeninate MOF. ZN 2+, dark blue tetrahedra; C, gray spheres; O, red spheres; N, blue spheres; H, omitted for clarity. I …exhibits a high surface area (4, 300 m 2 g− 1), one of the lowest crystal densities (0. 302 g cm− 3) and the largest metal-organic framework pore volume reported to date (4. 3 cm 3 g− 1).

CO 2 adsorption Figure 12. A portion of the crystallographic structure of Ni 2(dobdc) following dosing with CO 2. Green, gray, and red spheres represent Ni, C, and O atoms, respectively; H atoms are omitted for clarity. (193) http: //www. sigmaaldrich. com/technicaldocuments/articles/materials-science/metal-organicframeworks/ni-mof-74. html

Separations Table 10. Components of the Shifted Products of Steam Methane Reformation(417) component approximate percentage (vol %) H 2 70– 80 CO 2 15– 25 CO 1– 3 CH 4 3– 6 Chem. Rev. , 2012, 112 (2), pp 724– 781

Ferroelectric MOFs Figure 9. Structures of [(NH 4)Li(C 4 H 4 O 6)]·H 2 O in the paraelectric phase (293 K): (a) unit cell along the c axis and (b) layer structure in the ab plane. Green dotted lines represent hydrogen bonds. Chem. Rev. , 2012, 112 (2), pp 1163– 1195 Temperature dependence of dielectric constant of (a) [(NH 4)Li(C 4 H 4 O 6)]·H 2 O