Metamorphism of CalcareousUltramafic Rocks Metamorphism of CalcareousUltramafic Rocks Slides: 24 Download presentation Metamorphism of Calcareous/Ultramafic Rocks Metamorphism of Calcareous/Ultramafic Rocks – the System Ca. O-Mg. O-Si. O 2 -CO 2 -H 2 O Calcareous Rocks Ultramafic Rocks Metamorphic zones in siliceous dolomites of the Lepontine Alps Mineral Assemblages in Siliceous Dolomites All reactions isobarically univariant! The Effect of H 2 O on Decarbonation Reactions – T-XCO 2 Diagrams Mixed-Volatile (H 2 O-CO 2)Equilibria 3 XCO 2 at TMax n. CO 2/(n. CO 2+n. H 2 O) T-XCO 2 Phase Equilibria in the System Ca. O-Mg. O-Si. O 2 -CO 2 -H 2 O Chemical Potential and T-XCO 2 Diagrams m H 2 O Yields correct orientation of topology m. CO 2 Internal Buffering of Fluid Composition (XCO 2) Internal Versus External Buffering of XCO 2 External Buffering Internal buffering The Assemblage Dol-Qtz and the Talc Field Note that the assemblage dol-qtz will produce, talc, tremolite or diopside depending on XCO 2 Intersecting Isograds – the Role of XCO 2 Intersecting Isograds – the Role of XCO 2 Effect of XCO 2 on Isograd Distribution in Mixed Pelitic and Calcareous Assemblages CO 2 Infiltration and the Amphibolite – Granulite Transition Isograds in Limestone around Mount Royal Note the implications of internal buffering of XCO 2 Metamorphism of Ultramafic Rocks Progressive Metamorphism of Ultramafic Rocks T-XCO 2 Relationships for Metamorphosed Ultramafic Rocks P-T relationships During Progressive Metamorphism of Ultramafic Rocks Ultramafic Rocks, CO 2 Sequestration and Global Cooling A CO 2 Sequestration Model • Create a hydrous slurry of ultramafic rock • Pump CO 2 through the slurry at elevated temperature Results of a CO 2 sequestration Experiment Temperature: 195 o. C Duration: 5 hrs 25 min Serpentinite Magnesite 30 mm A Potential Thermoelectric Power Station of the Future