Introduction to Chemical Engineering Thermodynamics Chapter 6 Thermodynamic

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Introduction to Chemical Engineering Thermodynamics Chapter 6 Thermodynamic properties of fluids Smith 1

Introduction to Chemical Engineering Thermodynamics Chapter 6 Thermodynamic properties of fluids Smith 1

Chapter 6. 2 Thermodynamic properties of fluids n 流體熱力性質的計算 n n n T, P,

Chapter 6. 2 Thermodynamic properties of fluids n 流體熱力性質的計算 n n n T, P, V ΔU, Δ H ΔS ΔG, ΔA HR , S R , G R n n n Chemical potential, μi Fugacity , fi 數據資料型態 n n n 圖 – 圖形座標 表 – 表格變數 方程式

Chapter 6. 3 Thermodynamic properties of fluids n 熱力變數(性質)與定義 n 衍生之熱力變數(性質) n 能量 n

Chapter 6. 3 Thermodynamic properties of fluids n 熱力變數(性質)與定義 n 衍生之熱力變數(性質) n 能量 n n 自由能 n n n Enthalpy Gibbs free energy Helmholtz free energy 能量交換所定義 n n Work Heat

Chapter 6. 5 Thermodynamic properties of fluids n Maxwell 方程式 n 較有用的兩個Maxwell 方 程式

Chapter 6. 5 Thermodynamic properties of fluids n Maxwell 方程式 n 較有用的兩個Maxwell 方 程式

Chapter 6. 7 Thermodynamic properties of fluids n 輕功 n 天羅地網式 淩波微步 神行百變 n

Chapter 6. 7 Thermodynamic properties of fluids n 輕功 n 天羅地網式 淩波微步 神行百變 n … n n n 計算式 葵花寶典 易筋經

Chapter 6. 8 Thermodynamic properties of fluids n 內能的推導計算 n 兩種推導方式

Chapter 6. 8 Thermodynamic properties of fluids n 內能的推導計算 n 兩種推導方式

Chapter 6. 10 Thermodynamic properties of fluids n 獨立變數是體積與溫度時 n 考慮由內能函數代替焓作 前置推導

Chapter 6. 10 Thermodynamic properties of fluids n 獨立變數是體積與溫度時 n 考慮由內能函數代替焓作 前置推導

Chapter 6. 11 Thermodynamic properties of fluids n 熱力性質改變計算式

Chapter 6. 11 Thermodynamic properties of fluids n 熱力性質改變計算式

Chapter 6. 16 剩餘Gibbs自由能計算範例 Thermodynamic properties of fluids n n n 選定一個定溫條件 由蒸氣表查取比容 換算成莫耳體積

Chapter 6. 16 剩餘Gibbs自由能計算範例 Thermodynamic properties of fluids n n n 選定一個定溫條件 由蒸氣表查取比容 換算成莫耳體積 計算壓縮因子 計算縱座標值 t = 300 C ；T = 573. 15 K P / [k. Pa] 1 10 264500. 26440. /[cm^3/g] 20 13210.

Chapter 6. 19 Thermodynamic properties of fluids n n 焓的計算式 n 熵的計算式 利用副程式的計算 n

Chapter 6. 19 Thermodynamic properties of fluids n n 焓的計算式 n 熵的計算式 利用副程式的計算 n 如第四章與第五章

Chapter 6. 26 Thermodynamic properties of fluids n 兩相平衡系統總性質的計 算式

Chapter 6. 26 Thermodynamic properties of fluids n 兩相平衡系統總性質的計 算式

Chapter 6. 31 Thermodynamic properties of fluids n 第二維里係數通式化式 n 電腦程式的應用

Chapter 6. 31 Thermodynamic properties of fluids n 第二維里係數通式化式 n 電腦程式的應用

Chapter 6. 34 Thermodynamic properties of fluids n 在氣體混合物的應用 n n 基於理想氣體混合之假設 擬臨界參數

Chapter 6. 34 Thermodynamic properties of fluids n 在氣體混合物的應用 n n 基於理想氣體混合之假設 擬臨界參數

Chapter 6. 35 Thermodynamic properties of fluids 劇情如何發展？ 敬請期待！

Chapter 6. 35 Thermodynamic properties of fluids 劇情如何發展？ 敬請期待！

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