IB PHYSICS Topic 3 Thermodynamics Study of conversion

IB PHYSICS Topic 3: Thermodynamics: Study of conversion of heat to other forms of energy (mechanical, light, sound, chemical, electromagnetic, nuclear, and atomic). Ex. Mechanical to Heat: 4. 186 J = 1 cal. 1 st Law: Energy is conserved. ΔU = Q - W > 0 2 nd Law: Disorder (change in entropy, ΔU) tends to increase. Entropy is unavailable energy (waste heat). Thermodynamics is based on Kinetic Theory: 1. All matter is composed of tiny particles (atoms and molecules). 1 10/7/2020 2. These particles are in constant motion.

Thermal Physics Applications: fabrication of materials chemical reactions biological processes 2 phase transitions 10/7/2020

The Four States of Matter 1. Gases - easy to compress, particles far apart, expand to fill any container, and repel each other. 2. Liquids - no definite shape, hard to compress, particles close together, and attract each other. 3. Solids - definite shape, much harder to compress, closer spacing than liquids. 4. Plasma – electrically charged particles in chaotic motion. 3 10/7/2020

THE GAS LAWS 1. Boyle’s Law: states that the product of pressure and volume is constant. PV = k or P 1 V 1 = P 2 V 2 2. Charles’ Law – states that volume and temperature are directly proportional. V 1 / T 1 = V 2 / T 2 3. Combined Law – a combination of Boyle’s and Charles’ Laws. P 1 V 1 / T 1 = P 2 V 2 / T 2 4. Ideal Gas Law – relates volume, temperature, pressure, and number of particles (n). PV = n. RT where R = 8. 315 J/mol∙K , Universal Gas Constant. 4 10/7/2020

3 temperature scales: Fahrenheit TF, Celsius TC, Kelvin TK. Metric unit for temperature is the Kelvin. a. TK = TC + 273 , ex. (10 o. C = 283 K) b. TC = TK – 273 , ex. (10 K = -263 o. C) c. TC = 5/9(TF – 32) , ex. (32 o. F = 0 o. C) d. TF = 9/5 TC + 32 , ex. (100 o. C = 212 o. F) Thermal Energy – total of all the kinetic and potential energy of all the particles in a substance. Proportional to temperature. 5 10/7/2020

1. Solids: L = • L • T = coefficient of linear expansion L L 2. Liquids: V = • V • T = coefficient of volume expansion V 6 V 10/7/2020

First Law Equation: ΔU = (Uf -Ui) = Q-W Types of Thermal Processes) A thermal process is considered quasi-static when it occurs slowly enough that a uniform pressure and temperature exist throughout the system at all times. Process Occurs at or with • Isobaric - constant pressure. • Isochoric - constant volume. • Isothermal - constant temperature. • Adiabatic - takes place without the transfer of heat.

Heat Engine (schematic)

Heat Transfer Mechanisms Heat is the Thermal Energy transferred from an object to its surroundings due to a difference in temperature. There are now four ways of moving heat: • Convection (moving heat with a material) • Conduction (moving heat through a material) • Radiation (moving heat away from a source) • Evaporation (using latent, hidden, heat) Temperature determines the direction of heat transfer. Heat ALWAYS moves from a hot to a cold object. 9 10/7/2020

How to calculate changes in thermal energy Q = m • c • T Q = change in thermal energy, J m = mass of substance, kg c = specific heat capacity of substance (ex. Water, 4186 J/kg °C) T = change in temperature, C 10 10/7/2020

Law of Heat Exchange, Q = 0 QG + QL = 0 QG = -QL QL = heat lost by substance at high temperature QG = heat gained by substance at low temperature T = change in temperature (Tf – Ti) So now we have, when mixing 2 substances m 1 • c 1 • (Tf – Ti) = -[m 2 • c 2 • (Tf – Ti)] m 1 • c 1 • (Tf – Ti) = m 2 • c 2 • (Ti – Tf) 11 10/7/2020

Specific heat - amount of heat needed to raise the temperature of 1 kg of substance by 1°C or 1 K). 1) Cwater = 4186 J / kg o. C 2) Csand = 664 J / kg o. C Why the beach (sand) heats up quickly during the day and cools quickly at night, but water takes longer to do both. 12 10/7/2020

Beware of Phase Changes. Watch out for Latent (hidden) Heat. Latent Heat (H) – The amount of heat per kilogram that must be added or removed to change the phase of a particular substance Q = m·Hf Hf = Latent Heat of Fusion (freezing or melting) Q = m·Hv Hv = Latent Heat of Vaporization (evaporating or condensing)

We can calculate the amount of heat that passes through a conductor…… A L Q = (k·A·ΔT·t)/L k = thermal conductivity

The radiant energy emitted by an object…… Q = energy emitted Depends on: A = surface area of object t = time e = emissivity (depends on surface and type of radiation), 0<e<1 Temp T Q = e T 4 A t, Stefan-Boltzmann Law, with = 5. 67 x 10 -8 J/sm 2 K 4 , Stefan-Boltzmann Constant

Recall: This applies to radiant energy also: e T 4 A Environment at temp T 0 Object at temp T Net Power Emitted 4 – T 4) = e A (T 0 by Object

• Laws of Thermodynamics - First Law Equivalence of different forms of energy ΔU = Q - W - Second Law Only fraction of thermal energy can be used to do mechanical work Eff = 1 – (Tcold / Thot) - Zeroth Law Temperature is ONLY measure of thermodynamic equilibrium 17 10/7/2020

Heat Engine (schematic) For the Heat engine, Change in energy = heat added minus work done ΔU = Q – W For the Colder region, Entropy = heat added divided by the temperature ΔS = Q/T 18 10/7/2020

Work Done By a Gas: W = P·ΔV , Work = Pressure x change in Volume. Movable piston GAS 2 kg 3 3 m 3 1 m Fixed base and walls.

Carnot Efficiency “To find the Efficiency of a Heat Engine, take its temperature. ” Sadi Carnot (1796 -1832) Paris. In his paper, “Reflections on the Motive Power of Heat”, we find the Carnot efficiency: Efficiency = (Thot - Tcold) / Thot = 1 – (Tcold / Thot). Temperatures in Kelvin. Thot = internal temperature of the engine, and Tcold is temperature of exhaust gases. Typical efficiency today is about 30%. 20 10/7/2020

HISTORY OF HEAT ENGINES: 1. Hero’s Engine: 100 BC, Greek inventor, Hero of Alexandria. Mechanical interaction of heat and water. 21 10/7/2020

2. Thomas Savery (1650 -1715) English military engineer and inventor who in 1698, patented the first crude steam engine, based on a pressure cooker invented in 1679. 22 10/7/2020

3. Thomas Newcomen (1663 -1729) British blacksmith, invented the atmospheric steam engine. Improvement over Savery's design. 23 10/7/2020

• In the 1800’s, US, Fulton and Watt perfected the steam engine. Eff increased from 2% to 20% • Reasons: 1. Larger engines, 2. Higher pressure and temperature, 3. Special metals • Steam engine replaced by steam turbine and gasoline engine. • 2 types of heat engines: 1. Internal combustion, 2. External combustion. 24 10/7/2020

Number of moles n in a sample equals the number of particles N (atoms or molecules) in the sample divided by the number of particles per mole NA. Or n = N/NA NA = 6. 022 x 1023 particles per mole (Avogadro’s Number) Amedeo Avogadro (17761856), Turin, Italy. Number of moles also equals mass m of the sample (in grams) divided by the mass per mole (in grams per mole ). n = m/(mass per mole). Mass of a particle (in grams) can also be obtained by dividing mass per mole (in g/mol) by Avogadro's number. mparticle = mass per mole/NA.

Temperature is a quantity proportional to the average kinetic energy of the particles. KEavg = ½ mv 2 rms where vrms is the root-mean-square speed of the particles, derived statistically by Boltzmann. The internal energy U of n moles of a monatomic ideal gas is U = 3/2 n. RT. Ludwig Boltzmann (1844 -1906), Austria, Developed the branch of Physics known as Statistical Mechanics.

Fick’s Law, named after Adolf Eugen Fick (1829 -1901), Germany. The mass of a solute that diffuses in time through a channel of known length, L, and cross-sectional area, A, is given by m = (D·A·ΔC)t/L. ΔC is the solute concentration difference between the ends of the channel D is the diffusion constant.

Zeroth Law of Thermodynamics: “Two systems are in thermal equilibrium if there is no net heat flow between them when they are brought into thermal contact. ” First Law of Thermodynamics: “The total increase in thermal energy of a system is equal to the sum of the heat added to it and the work done on it. ” ΔU = (Uf -Ui) = Q-W The second law also states that natural processes always go in a direction that increases the entropy, S, unavailable energy, or disorder, of a system. ΔS = Q – W. A thermal process is considered quasi-static when it occurs slowly enough that a uniform pressure and temperature exist throughout the system at all times.

The work done in any kind of quasistatic process is given by the area under the pressure versus volume graph. W = n. RT·ln(Vf /Vi). 1. An isobaric process is one that occurs at constant pressure. W = P·ΔV = P(Vf -Vi). 2. An isochoric process is done at constant volume and no work is done. W=0 3. An isothermal process is done at constant temperature. W=0 4. An adiabatic process takes place without the transfer of heat. W = 3/2 n. R(Ti -Tf)

For an Adiabatic Process, ideal gas obeys: 1. Ideal Gas Law, PV = NRT γ γ 2. Pi. Vi = Pf. Vf , where γ = cp/cv, ratio of specific heat capacities at constant pressure and constant volume. The molar specific heat capacity of a substance determines how much heat is added or removed when the temperature of n moles of the substance changes. This is given by the equation Q = C·n·ΔT. For a monatomic ideal gas, the molar specific heat capacities at constant pressure and constant volume are, respectively, CP = 5/2 R and CV = 3/2 R, where R = 8. 31 J/(mol·K) the Ideal Gas Constant. For any ideal gas, the difference between CP and CV is R, or CP - CV = R.

A heat engine continuously converts thermal energy to mechanical energy and does work. The efficiency, e, of a heat engine is expressed by the equation e = (Work done)/(Input heat) = W/QH. Conservation of energy requires that QH = W + QC. Combining the equations we get, e = 1 – (QC / QH ). From Carnot, we have QC/QH = TC/TH. This gives an equation for the maximum efficiency that an engine can have operating between two fixed temperatures. e Carnot = 1 - TC/TH.

A heat pump, air conditioner, or refrigerator uses mechanical energy to transfer heat from an area of lower to higher temperature. These are governed by the Law of Conservation of Energy with QH = W + QC. The coefficient of performance of a refrigerator or air conditioner is given by the equation Coefficient of performance = QC / W. For the heat pump which also moves heat from a cold area, we have a similar relationship, Coefficient of performance = QH / W.

Famous Early Automobile Makers 1. Nicolaus August Otto invented the gas motor engine in 1876. 2. In 1885, Gottlieb Daimler invented a gas engine that allowed for a revolution in car design. 3. Karl Benz was the German mechanical engineer who designed and in 1885 built the world's first practical automobile to be powered by an internal-combustion engine. Named it Mercedes, after his daughter. 33 10/7/2020

Principle of an Internal Combustion Engine 34 10/7/2020

4 Cycles: 1. Induction 2. Compression 3. Power 4. Exhaust 35 The Internal Combustion Engine 10/7/2020

That Thing Got A Hemi? Sweeeeeeet. 36 10/7/2020

1900’s: Jet engines were developed. Rely on Newton’s 3 rd Law (action/reaction) to produce motion. 1. Ram. Jet - simple, no moving parts, must be moving to operate, propelled by a rocket. Supersonic? Scramjet.

2. Turbo-Jet Turbine (fan blades) force air into combustion chamber. Thrust produced by escaping hot gases. Auxiliary power must start engine. Ex. Today’s jet engines. 38 10/7/2020

3. Rocket – reaction force (thrust) produces motion. Carries fuel and oxygen needed for combustion. Travels beyond atmosphere. Specific Impulse of the fuel, S. I. = (Thrust / Weight) x Time 39 SPECIFIC IMPULSE 10/7/2020

4. DIESEL ENGINE –developed by Rudolf Diesel (1858 -1913), Germany. Fuel is compressed to ignition temperature. Low power to weight ratio. Cheaper fuel (at one time). 40 10/7/2020

5. Gas turbine – continuously drawn-in air. Fan blades. Fuel burns with steady flame. Gases pass through exhaust nozzle at high speed. Runs its own turbine. Used in aircraft. 41 10/7/2020

Fossil-fuel electric plant: thermodynamics 42 10/7/2020

43 NUCLEAR REACTOR 10/7/2020

Efficiencies of Power Plants Power plants these days (almost all of which are heatengines) typically get no better than 33% overall efficiency. 44 The End. 10/7/2020