How Much Do You Really Know www pdaonline
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How Much Do You Really Know? www. pda-online. org
Polyurea Advantages • • Fast Set. Can Be Walked on in Seconds No VOC's and Little to No Odor Some Systems are USDA and NSF Approved Weather Tolerant: Cures at 25ºF to 300ºF and in High Humidity Excellent Resistance to Thermal Shock Place in Service Immediately Flexible: Bridges Cracks Waterproof, Seamless and Resilient www. pda-online. org • • Unlimited Mil Thickness in One Application Spray, Hand Mix and Caulk Grade Materials Excellent Bond Strengths to Properly Prepared Substrates Resistant to Many Solvents, Caustics and Mild Acids Low Permeability Can be Top-Coated for Added Features Texture Can be Added for Slip Resistance
Polyurea Definition • A polyurea coating / elastomer is that derived from the reaction product of an isocyanate component and a resin blend component. The isocyanate can be aromatic or aliphatic in nature. It can be monomer, polymer, or any variant reaction of isocyanates, quasi-prepolymer or a prepolymer. The prepolymer, or quasi-prepolymer, can be made of an amine-terminated polymer resin, or a hydroxyl-terminated polymer resin. • The resin blend must be made up of amine-terminated polymer resins, and/or amine-terminated chain extenders. The amine-terminated polymer resins will not have any intentional hydroxyl moieties. Any hydroxyls are the result of incomplete conversion to the amine-terminated polymer resins. The resin blend may also contain additives, or non-primary components. These additives may contain hydroxyls, such as pre-dispersed pigments in a polyol carrier. Normally, the resin blend will not contain a catalyst(s). www. pda-online. org
Polyurea History • 1981 – Developed for Automotive RIM • 1986 – Polyurea Spray Systems Developed • 1987 – Polyurea Spray Technology Introduced to Industry • 1988 – First Commercial Use www. pda-online. org
Who Benefits from the PDA? • The Polyurea Development Association (PDA) is a trade association comprised of raw material suppliers, system formulators, equipment manufacturers, distributors, sales reps, contractors, consultants, academia, and end-users. – Formed in 2000 • Mission Statement – “To promote market awareness, understanding and acceptance of Polyurea technology through the development of education programs, product standards, safety and environmental and use recommendations” www. pda-online. org
Association Objectives • Develop product certification and use standards • Act as a “clearing house” for dissemination of Polyurea questions and information • Develop educational, safety and training programs • Develop marketing programs to promote Polyurea applications and benefits • Host Annual Polyurea Conference and Exhibit www. pda-online. org
Systems Available • Aromatic Based Spray Formulations • Aliphatic Color Stable Based Spray Formulations • Slow Cure Joint Sealants • Brush Grade Systems for Repair www. pda-online. org
Performance Disclaimer • All Polyurea systems are not equal – Physical Properties and Performance Ratings are affected by formulation and application parameters • Consult your Polyurea supplier for exact physical properties and performance ratings for each individual system NOTICE: All statements, information and data given herein are believed to be accurate and reliable but are presented without guarantee, warranty or responsibility of any kind expressed or implied. Statements or suggestions concerning physical properties and/or possible use of Polyurea and are made without representation or warranty that any such use is free of patent infringement, and are not recommendations to infringe any patent. The user should not assume that all safety measures are indicated or that other measures may not be required. www. pda-online. org
Performance Comparison Performance Type Physical strength Elongation Impact resistance Abrasion resistance Adhesion to concrete Cure shrinkage Permeability UV Resistance Creep Temperature limit Polyurea Low-High Low-High Low Mid-High Low-High Polyurethane Low-Mid High Mid-High Low-Mid Low Mid-High Low-High Mid Polyester High Low Mid-High Mid High Low Mid-High Low-Mid Epoxy High Low Mid-High Low Low Low-Mid Mid-High Vinyl Ester High Low Mid-High Mid High Low Mid Low-Mid Mid-High Acrylic Mid-High Low-Mid High Low-Mid Polysulfide Low-Mid High Mid-High Mid Low-Mid Low Mid-High Low-Mid Chemical Resistance Mineral acids Organic acids Alkalis Chlorinated solvents Oxygenated solvents Hydrocarbon solvents Salts Water Low-Mid Mid-High Low-Mid Low-Mid Low-Mid Mid-High Low-High Mid-High Mid-High Mid High Low-High Mid-High Mid-High Mid High Low-Mid Low-High Mid-High Low-Mid Low-Mid Mid-High Low-High www. pda-online. org
Typical Physical Properties Tensile Strength, psi Shore Hardness Elongation, % Tear Strength, pli 100% Modulus, psi Burst Strength, psi Flex/Crack Bridging -26°C / -15°F www. pda-online. org up to 4000 A 30 to D 65 up to 1000 250 to 600 500 to 2000 250 to 500 > 1/8 inch
Adhesion Substrate Concrete, dry Concrete, primed Steel, 2 -mil blast profile Aluminum, cleaned Wood SF = Substrate Failure www. pda-online. org Elcometer Adhesion, psi 400, SF > 2000 250, SF
Salt Spray Corrosion Studies System Reactivity, (sec) 2. 5 3. 5 Blistering Bare steel Urethane primer Epoxy primer Corrosion from scribe, mm Bare steel Urethane primer Epoxy primer Elcometer adhesion, psi Urethane primer Epoxy primer 1000 hours ASTM B-117 Salt Fog Exposure www. pda-online. org none F, #2 4. 0 7. 0 >10 9. 5 >10 8. 0 Bare steel >2000 500 1200 800 1100 >2000
Plural-Component Equipment • Proportioning Machine – Spray – Pour – Injection • 1: 1 Ratio Metering Pumps – Hydraulic Driven – Air Driven – Other than 1: 1 ratios can be achieved • Caulking / Joint Fill Dispensers www. pda-online. org
Polyurea Uses • Abrasion Protection • Corrosion Resistant Coating • Containment – Primary – Secondary • • Decorative Application Molding Joint / Crack Fill Structural Bonding & Reinforcement www. pda-online. org
Applications www. pda-online. org
Waste Water Treatment Linings www. pda-online. org
Tank Coatings & Linings www. pda-online. org
Pipe / Pipeline Coatings & Linings www. pda-online. org
Manhole & Sewer Linings www. pda-online. org
Flooring and Parking Decks www. pda-online. org
Bridge Coating www. pda-online. org
Truck Bedliners www. pda-online. org
Railcar Lining & Track Containment www. pda-online. org
Water Parks & Playgrounds www. pda-online. org
Landscape & Water Containment www. pda-online. org
Fuel Storage & Containment www. pda-online. org
Aquarium Lining www. pda-online. org
Architectural Design www. pda-online. org
Theme Park & Decorative Design www. pda-online. org
Roof Coating www. pda-online. org
Marine www. pda-online. org
Automotive Fascia OEM Molded Parts www. pda-online. org
Line Striping www. pda-online. org
Joint Fill / Caulk www. pda-online. org
Companies That Know… • • • AT&T Agricultural Canada Alcoa Bayer Pharmaceutical Chevron/Mobile Coca Cola Diamond Shamrock Du. Pont Frito Lay Ford Motor General Motors Johnson & Johnson www. pda-online. org • • • Kohler Company Miller Brewing Co NASA Pepsi Cola Quaker Oats Tandy Corporation Texaco U. S. Dept of Energy US Navy Union Pacific Railroad Wilsonart Plastics
Conclusion • Plural Component Technology - no solvents, no VOC’s • • Excellent substrate adhesion Sound case history base Characterized by NACE / SSPC Polyurea Development Association www. pda-online. org
Polyurea Development Association Contact Information: Polyurea Development Association 14 West Third Street, Suite 200 Kansas City, MO 64105 Phone: (816) 221 -0777 Fax: (816) 472 -7765 www. pda-online. org
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