History of Chemistry Early models of the atom

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History of Chemistry Early models of the atom • Democritus- early Greek philosopher •

History of Chemistry Early models of the atom • Democritus- early Greek philosopher • matter made up of tiny indivisible particles called atoms •

Dalton- “ 1 st modern atomic theory” 5 Parts to theory 1) All elements

Dalton- “ 1 st modern atomic theory” 5 Parts to theory 1) All elements made of tiny particles called atoms. 2) Atoms of same element are identical; 3)different atom = different element 4) Atoms bind together in simple whole number ratios. H 2 O 2: 1 correct H 1. 25 O 1. 25: 1 incorrect (2: 1 ratio) 2 H + O H 2 O H 2 O 2 (2: 2 ratio) 2 H + 2 O 5)Chemical reactions join or rearrange atoms But atoms can not change into another element

Structure of Atom: J. J. Thomson- Plum Pudding Model Or chocolate chip cookie Electron-

Structure of Atom: J. J. Thomson- Plum Pudding Model Or chocolate chip cookie Electron- J. J. Thomson used cathode ray tube to discover electrons, e- have a negative charge

Structure of Atom: Proton- positively charged subatomic particle Goldstein- P+ mass 1840 times larger

Structure of Atom: Proton- positively charged subatomic particle Goldstein- P+ mass 1840 times larger than e- mass Neutron- neutral charged subatomic particle - Discovered by Chadwick - Mass of proton = mass of neutron

Rutherford- discovered atoms have a nucleus that e- orbit Rutherford Performed Gold Foil Experiment

Rutherford- discovered atoms have a nucleus that e- orbit Rutherford Performed Gold Foil Experiment - Shot alpha particles (+ charge) from radioactive lead through gold foil - He expected it to go through b/c heavy mass and fast - But Some bounced back - Concluded it had a dense center called it nucleus - Nucleus is most dense has protons & neutrons - Almost all atoms mass located in nucleus

Mendeleev • Created the first periodic table • Observed when elements are arranged in

Mendeleev • Created the first periodic table • Observed when elements are arranged in order of increasing atomic mass then chemical and physical properties appear at regular intervals Based on atomic mass Based on atomic number

 • The Periodic Table Mendeleev- Arranged by increasing atomic mass, left blank spaces,

• The Periodic Table Mendeleev- Arranged by increasing atomic mass, left blank spaces, able to predict properties of missing elements b/c properties repeated • Moseley- arranged in order of increasing atomic number, the one we use today Periodic Law- elements in increasing atomic number will have a periodic repetition of physical & chemical properties

Atoms Atomic Number- # protons in nucleus Atoms are electrically neutral so #p =

Atoms Atomic Number- # protons in nucleus Atoms are electrically neutral so #p = #e Protons = electrons

Atoms Mass Number = #p + #n = mass # number of protons +

Atoms Mass Number = #p + #n = mass # number of protons + number of neutrons = mass number If given Mass # and proton # you can figure out #of neutrons Mass # - #p = #n

Atoms • Shorthand: Mass # Symbol # Protons 1 4 H 1 He 2

Atoms • Shorthand: Mass # Symbol # Protons 1 4 H 1 He 2 figure out for Carbon

Atoms 12 C 6

Atoms 12 C 6

Atoms • Isotope- same # p, different # n; so different mass 1 2

Atoms • Isotope- same # p, different # n; so different mass 1 2 H 1 3 H 1

 • Problems: – Fill in the chart: Element Mass # Be 9 Atomic

• Problems: – Fill in the chart: Element Mass # Be 9 Atomic # # Protons Electrons Neutrons 4 20 Na 23 10 11 15 16

 • Problems: – Fill in the chart: Element Mass # Atomic # #

• Problems: – Fill in the chart: Element Mass # Atomic # # Protons Electrons Neutrons Be 9 4 4 4 5 Ne 20 10 10 Na 23 11 11 11 12 P 31 15 15 15 16

 • Warm up Problems: – Fill in the chart: Element Mass # Mg

• Warm up Problems: – Fill in the chart: Element Mass # Mg 24 Atomic # # Protons Electrons Neutrons 12 32 K 39 16 19 32 41

 • Warm up Answer: – Fill in the chart: Element Mass # Atomic

• Warm up Answer: – Fill in the chart: Element Mass # Atomic # # Protons Electrons Neutrons Mg 24 12 12 S 32 16 16 K 39 19 19 19 20 Ge 73 32 32 32 41

3 Main Groups of Elements on PT (Periodic Table) Metals Non-Metals Metalloids

3 Main Groups of Elements on PT (Periodic Table) Metals Non-Metals Metalloids

3 Main Groups of Elements on PT (Periodic Table) Metalso Left side of PT

3 Main Groups of Elements on PT (Periodic Table) Metalso Left side of PT o 80% elements o Conduct electricity o Luster o Ductile o Malleable o Mostly solids w/ some exceptions o 1 A Alkali metals o 2 A Alkaline Earth Metals o Group B- Transition & Inner Transition Metals

· Nonmetalso o Right side of PT Don’t conduct electricity Aren’t ductile or malleable

· Nonmetalso o Right side of PT Don’t conduct electricity Aren’t ductile or malleable Can be solids, liquids or gases No luster 7 A- Halogens 0 - Noble gases Metalloidso Border Stair Step o Properties of metals & nonmetals o Used in solar cells & computer chips

THE PERIODIC TABLE • The rows across the elements in the periodic table are

THE PERIODIC TABLE • The rows across the elements in the periodic table are called periods 1 -7 • The columns down are called groups. • groups numbered 1 to 18 or 1 A-8 A

GROUPS or Families • Group 1(1 A) are found on the far left side

GROUPS or Families • Group 1(1 A) are found on the far left side and are called the alkali metals • Group 2(2 A) are found on the far left side and are called the alkaline metals • Group 7 A(17) are found at the right hand side and are called the halogens. • Group 8 A(18) are called the noble gases

GROUP 7 - halogens are all non- metals they are: -Fluorine, Chlorine, Bromine, Iodine

GROUP 7 - halogens are all non- metals they are: -Fluorine, Chlorine, Bromine, Iodine

 • They have low melting points (this means that the change from a

• They have low melting points (this means that the change from a solid to a liquid at a low temperature) • They do not conduct electricity • They go around as pairs of atoms. • We call them diatomic molecules • We write them like this • Fluorine - F 2 • Chlorine - Cl 2 • Bromine - Br 2 • Iodine - I 2

What are they like? • • Fluorine is a very pale yellow gas Chlorine

What are they like? • • Fluorine is a very pale yellow gas Chlorine is a green gas Bromine is a dark red brown liquid Iodine is a black shiny solid

THE REACTIONS OF THE HALOGENS • The halogens like to take most • The

THE REACTIONS OF THE HALOGENS • The halogens like to take most • The halogens like to take part in chemical reactions reactive part in chemical reactions • The react with metals to make salts • • The most reactive halogen is fluorine and the least reactive is iodine. • They get less reactive as you go down the group Least reactive

Uses of the halogens • Iodine is used as an antiseptic • Chlorine is

Uses of the halogens • Iodine is used as an antiseptic • Chlorine is used in swimming pools to kill bacteria • Fluorine is used in tooth paste • Bromine is used photographic film

How much does an atom weigh? • Amu- (atomic mass unit) = 1/12 C-12

How much does an atom weigh? • Amu- (atomic mass unit) = 1/12 C-12 atom • How many protons in C? • How many neutrons in C? • Atomic Mass of C?

 • Amu- (atomic mass unit) = 1/12 C-12 atom • How many protons

• Amu- (atomic mass unit) = 1/12 C-12 atom • How many protons in C = 6 • How many neutrons in C = 6 • Atomic Mass of C =12 • Therefore 1/12 th of a C atom is = • to 1 proton • Or = to 1 neutron

 Relative Atomic Mass 1 p = 1 amu 1 n = 1 amu

Relative Atomic Mass 1 p = 1 amu 1 n = 1 amu 1 e- = 0 amu Therefore one carbon atom weighs 12 amu’s © Addison-Wesley Publishing Company, Inc.

Isotopes- same # protons different # neutrons 6 3 7 3 Li 0. 00000

Isotopes- same # protons different # neutrons 6 3 7 3 Li 0. 00000 amu Li

6 3 7 3 Li lithium - 6 0. 00000 amu lithium - 7

6 3 7 3 Li lithium - 6 0. 00000 amu lithium - 7 Li

Li-6 = 6. 0 amu

Li-6 = 6. 0 amu

Li-7 = 7. 0 amu

Li-7 = 7. 0 amu

Isotopes Carbon-12 vs. Carbon-14 © Addison-Wesley Publishing Company, Inc.

Isotopes Carbon-12 vs. Carbon-14 © Addison-Wesley Publishing Company, Inc.

 Isotopes • Chlorine-37 – atomic #: 17 – mass #: 37 – #

Isotopes • Chlorine-37 – atomic #: 17 – mass #: 37 – # of protons: 17 – # of electrons: 17 – # of neutrons: 20

Mass # • mass # = protons + neutrons • always a whole number

Mass # • mass # = protons + neutrons • always a whole number • NOT on Periodic Table! • Nuclear symbol: Mass # Atomic #

Average Atomic Mass • weighted average of all isotopes • on the Periodic Table

Average Atomic Mass • weighted average of all isotopes • on the Periodic Table • round to 2 decimal places

 • Average atomic mass- is mass on PT -Based on natural abundance of

• Average atomic mass- is mass on PT -Based on natural abundance of isotopes 1. Change % to decimal 2. Multiply decimal by the mass 3. Add the numbers together

 • Average atomic mass- is mass on PT -Based on natural abundance of

• Average atomic mass- is mass on PT -Based on natural abundance of isotopes 1)Change % to decimal 2)Multiply decimal by the mass 3)Add the numbers together Element X has two isotopes. The isotope with a mass of 10. 012 amu has a relative abundance of 19. 91%. The isotope with a mass of 11. 009 amu has a relative abundance of 80. 09%. Calculate the atomic mass of this element.

 • Average atomic mass- is mass on PT -Based on natural abundance of

• Average atomic mass- is mass on PT -Based on natural abundance of isotopes 1)Change % to decimal. 1991 and. 8009 2)Multiply decimal by the mass 3)Add the numbers together Element X has two isotopes. The isotope with a mass of 10. 012 amu has a relative abundance of 19. 91%. The isotope with a mass of 11. 009 amu has a relative abundance of 80. 09%. Calculate the atomic mass of this element.

 • Average atomic mass- is mass on PT -Based on natural abundance of

• Average atomic mass- is mass on PT -Based on natural abundance of isotopes 1)Change % to decimal. 1991 and. 8009 2)Multiply decimal by the mass. 1991 x 10. 012 = 1. 993. 8009 x 11. 009=8. 817 3)Add the numbers together Element X has two isotopes. The isotope with a mass of 10. 012 amu has a relative abundance of 19. 91%. The isotope with a mass of 11. 009 amu has a relative abundance of 80. 09%. Calculate the atomic mass of this element.

 • Average atomic mass- is mass on PT -Based on natural abundance of

• Average atomic mass- is mass on PT -Based on natural abundance of isotopes 1)Change % to decimal. 1991 and. 8009 2)Multiply decimal by the mass. 1991 x 10. 012 = 1. 993. 8009 x 11. 009=8. 817 3)Add the numbers together 10. 810 amu Element X has two isotopes. The isotope with a mass of 10. 012 amu has a relative abundance of 19. 91%. The isotope with a mass of 11. 009 amu has a relative abundance of 80. 09%. Calculate the atomic mass of this element.

Average atomic mass [Worksheet] • Based on abundance of isotopes 1)Change % to decimal

Average atomic mass [Worksheet] • Based on abundance of isotopes 1)Change % to decimal 2)Multiply decimal by the mass 3)Add the numbers together 50. 54% of naturally occurring isotopes of bromine have an atomic mass of 78. 92 amu. While the other 49. 46% of isotopes of bromine have an atomic mass of 80. 92 amu. Calculate the average atomic mass of bromine.

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054 and. 4946 2)Multiply decimal by the mass 3)Add the numbers together 50. 54% of naturally occurring isotopes of bromine have an atomic mass of 78. 92 amu. While the other 49. 46% of isotopes of bromine have an atomic mass of 80. 92 amu. Calculate the average atomic mass of bromine.

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054 and. 4946 2)Multiply decimal by the mass. 5054 x 78. 92= 39. 89 . 4946 x 80. 92= 40. 02 3)Add the numbers together 50. 54% of naturally occurring isotopes of bromine have an atomic mass of 78. 92 amu. While the other 49. 46% of isotopes of bromine have an atomic mass of 80. 92 amu. Calculate the average atomic mass of bromine.

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054

Average atomic mass • Based on abundance of isotopes 1)Change % to decimal. 5054 and. 4946 2)Multiply decimal by the mass. 5054 x 78. 92= 39. 89 . 4946 x 80. 92= 40. 02 3)Add the numbers together 39. 89 + 40. 02 = 79. 91 50. 54% of naturally occurring isotopes of bromine have an atomic mass of 78. 92 amu. While the other 49. 46% of isotopes of bromine have an atomic mass of 80. 92 amu. Calculate the average atomic mass of bromine.

Average Atomic Mass • Calculate avg. atomic mass of oxygen if abundance is 99.

Average Atomic Mass • Calculate avg. atomic mass of oxygen if abundance is 99. 76% 16 O, 0. 04% 17 O, and 0. 20% 18 O. . 9976 x 16 = 15. 96. 0004 x 17 = 0. 00068 16. 002 x 18 = 0. 036 amu 16. 00

Average Atomic Mass • EX: Find chlorine’s average atomic mass if approximately 8 of

Average Atomic Mass • EX: Find chlorine’s average atomic mass if approximately 8 of every 10 atoms are chlorine 35 and 2 are chlorine-37. • 8/10 =. 80 • 2/10 =. 20 • . 80 x 35 = 28. 0 • . 2 x 37 = 7. 4 35. 40 amu

 • Warm up Answer: – Fill in the chart: Element Mass # Atomic

• Warm up Answer: – Fill in the chart: Element Mass # Atomic # # Protons Electrons Neutrons Mg 24 12 12 S 32 16 16 K 39 19 19 19 20 Ge 73 32 32 32 41

Dmitri Mendeleev (1869) In 1869 Mendeleev and Lothar Meyer (Germany) published nearly identical classification

Dmitri Mendeleev (1869) In 1869 Mendeleev and Lothar Meyer (Germany) published nearly identical classification schemes for elements known to date. The periodic table is base on the similarity of properties and reactivities exhibited by certain elements. Later, Henri Moseley ( England, 1887 -1915) established that each elements has a unique atomic number, which is how the current periodic table is organized. http: //www. chem. msu. su/eng/misc/mendeleev/welcome. html

The Periodic Table • A map of the building block of matter. http: //www.

The Periodic Table • A map of the building block of matter. http: //www. chemsoc. org/viselements/pages/periodic_table. html

Periodic Table: Metallic arrangement • Layout of the Periodic Table: Metals vs. nonmetals Metals

Periodic Table: Metallic arrangement • Layout of the Periodic Table: Metals vs. nonmetals Metals Nonmetals

 • Family: Are arranged vertically down the periodic table (columns or group, 1

• Family: Are arranged vertically down the periodic table (columns or group, 1 - 18 or I-VIII A) • These elements have the same number electrons in the outer most shells, the valence shell. Alkali Family: 1 e- in the valence shell Halogen Family: 7 e- in the valence shell

 • Notable families of the Periodic Table Halogen Noble Gas Chalcogens Alkaline (earth)

• Notable families of the Periodic Table Halogen Noble Gas Chalcogens Alkaline (earth) Transition Metals

He H Li Na Mg K Ca Fe Cu Zn Ag C N O

He H Li Na Mg K Ca Fe Cu Zn Ag C N O F Al Si P S Cl Br I

 e- configuration from the periodic table H 1 s 1 He 1 s

e- configuration from the periodic table H 1 s 1 He 1 s 2 Li Be 2 s 1 2 s 2 Na Mg 3 s 1 3 s 2 K 4 s 1 Sc 3 d 1 Rb 5 s 1 Ca 4 s 2 Sr 5 s 2 Y 4 d 1 V Ti Cr Mn Fe Co 3 d 2 3 d 3 4 s 13 d 5 3 d 6 3 d 7 Zr Nb Mo Tc Ru Rh 4 d 2 4 d 3 5 s 14 d 5 4 d 6 4 d 7 Cs 6 s 1 Ba 6 s 2 La 5 d 1 Hf Ta W Re Os 5 d 2 5 d 3 6 s 15 d 5 5 d 6 Fr 7 s 1 Ra 7 s 2 Ac Rf 6 d 1 6 d 2 Db Sg Bh 6 d 3 7 s 16 d 5 Ni 3 d 8 Ni 4 d 8 Ir Ni 7 5 d 5 d 8 Hs Mt 6 d 6 6 d 7 Cu 4 s 13 d 10 Ag 5 s 14 d 10 Au 6 s 15 d 10 B 2 p 1 • C B N O 1 2 3 • 2 p 2 p 4 F 2 p 5 Ne 2 p 6 Al 3 p 1 Si 3 p 2 S P 3 3 p 3 p 4 Cl 3 p 5 Ar 3 p 6 Zn Ga Ge 3 d 10 4 p 1 4 p 2 Cd In Sn 10 4 d 5 p 1 5 p 2 As Se 4 p 3 4 p 4 Be 4 p 5 Sb Te 5 p 3 5 p 4 I 5 p 5 Kr 4 p 6 Xe 5 p 6 Hg Tl Pb 5 d 10 6 p 1 6 p 2 Bi Po At 6 p 3 6 p 4 6 p 5 Rn 6 p 6

 electron behavior • The periodic table can be classified by the behavior of

electron behavior • The periodic table can be classified by the behavior of their electrons

Warm Up 1) Where are metals located below? 2) What group is known as

Warm Up 1) Where are metals located below? 2) What group is known as the halogens? 3) Where are the metalloids located?

Dmitri Mendeleev (1869) Based on atomic mass Today's periodic table organized by? http: //www.

Dmitri Mendeleev (1869) Based on atomic mass Today's periodic table organized by? http: //www. chem. msu. su/eng/misc/mendeleev/welcome. html

Periodic Trends • Today we will rationalize observed trends in – Atomic radius –

Periodic Trends • Today we will rationalize observed trends in – Atomic radius – Ionization energy. – Electronegativity

Periodic trends based on behavior of (-) electrons and (+) protons

Periodic trends based on behavior of (-) electrons and (+) protons

Valence Electrons- the outermost electrons that surround an atom

Valence Electrons- the outermost electrons that surround an atom

Valence Electrons- starting with group 1 = 1 valence e group 2 = 2

Valence Electrons- starting with group 1 = 1 valence e group 2 = 2 valence e group 3 A = 3 valence e- trend continues to group 8 A

 Trends in Atomic Radius • Atomic Radius: • size of atom determine by

Trends in Atomic Radius • Atomic Radius: • size of atom determine by boundaries of the valence e-. • Atomic radius increases as you move down a group. Why? • Atomic radius decreases as you move across a period. Why?

 Trends in Atomic Radius • Atomic Radius: • size of atom determine by

Trends in Atomic Radius • Atomic Radius: • size of atom determine by boundaries of the valence e-. • Atomic radius increases as you move down a group. Why? • Because you are adding more electrons to outer orbits • Atomic radius decreases as you move across a period. Why?

 Trends in Atomic Radius • Atomic Radius: • size of atom determine by

Trends in Atomic Radius • Atomic Radius: • size of atom determine by boundaries of the valence e-. • Atomic radius increases as you move down a group. Why? • Because you are adding more electrons to outer orbits • Atomic radius decreases as you move across a period. Why? • Adding more e- BUT also adding MORE P+ which pull in e-

 Trends in Atomic Radius • Atomic Radius: • size of atom determine by

Trends in Atomic Radius • Atomic Radius: • size of atom determine by boundaries of the valence e-. • Atomic radius increases as you move down a group. Why? • Because you are adding more electrons to outer orbits • Atomic radius decreases as you move across a period. Why? • Adding more e- BUT also adding MORE P+ which pull in e-

 Trends in Atomic Radius • Place the following in order of increasing atomic

Trends in Atomic Radius • Place the following in order of increasing atomic radius • S, P, Ar, Cl, Si

 Trends in Atomic Radius • Place the following in order of increasing atomic

Trends in Atomic Radius • Place the following in order of increasing atomic radius • Ar, Cl, S, P, Si

 Trends in Atomic Radius • Atomic Radius:

Trends in Atomic Radius • Atomic Radius:

Trends in Ionization Potential Ionization potential: Energy required to remove valence electron from atom.

Trends in Ionization Potential Ionization potential: Energy required to remove valence electron from atom.

Trends in Ionization Potential As you move across a period, ionization energy increases. WHY?

Trends in Ionization Potential As you move across a period, ionization energy increases. WHY? - As you move across a period, the atomic radius decreases, (atom gets smaller). The outer electrons are closer to + nucleus and more strongly attracted to + center. Therefore, it requires more energy to remove electron

Trends in Ionization Potential As you move down a group, ionization energy decreases. WHY?

Trends in Ionization Potential As you move down a group, ionization energy decreases. WHY? Electrons are further from the nucleus and thus easier to remove “e- SHIELDING" - Inner electrons block protons force of attraction on outer e-. therefore easier to remove outer electron

Trends in Ionization Potential Place the following in order of increasing ionization energy: Mg,

Trends in Ionization Potential Place the following in order of increasing ionization energy: Mg, Ra, Sr, Ca, Be

Trends in Ionization Potential Place the following in order of increasing ionization energy: Ra,

Trends in Ionization Potential Place the following in order of increasing ionization energy: Ra, Ba, Sr, Ca, Mg, Be

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself:

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself:

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself:

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself: Which is more electronegative? K or S and why?

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself:

Trends in Electronegativity The ability of an atom to attract (steal) electrons to itself: Which is more electronegative? S why? b/c small radius of atom means the + nucleus can attract the –e from other atoms

Summary of Trend • Periodic Table and Periodic Trends • 1. Electron Configuration 3.

Summary of Trend • Periodic Table and Periodic Trends • 1. Electron Configuration 3. Ionization Energy: Largest toward NE of PT 4. Electron Negativity: Most favorable NE of PT 2. Atomic Radius: Largest toward SW corner of PT

Periodic Table Patterns • Elements in the same group generally have similar chemical properties.

Periodic Table Patterns • Elements in the same group generally have similar chemical properties. • Properties are not identical, however.

Periodic Table Patterns Dmitri Mendeleev came to the conclusion that Elements in the same

Periodic Table Patterns Dmitri Mendeleev came to the conclusion that Elements in the same group generally have similar chemical properties.

Periodic Table Predictions Mendeleev, for instance, predicted the discovery of germanium (which he called

Periodic Table Predictions Mendeleev, for instance, predicted the discovery of germanium (which he called ekasilicon) as an element with an atomic weight between that of zinc and arsenic, but with chemical properties similar to those of silicon.

Electron Configuration- energy stair levels

Electron Configuration- energy stair levels

Electrons are found in orbits. an orbital is the shape of the space where

Electrons are found in orbits. an orbital is the shape of the space where there is a high probability of finding electrons The s orbitals are spheres

This is the shape of p orbitals

This is the shape of p orbitals

z The three 2 p orbitals, 2 px, 2 py, 2 pz y x

z The three 2 p orbitals, 2 px, 2 py, 2 pz y x

once each 2 p orbital is filled with a pair of electrons, then

once each 2 p orbital is filled with a pair of electrons, then

the 3 s orbital gets the next two electrons

the 3 s orbital gets the next two electrons

the 3 s electrons have a higher energy than 1 s, 2 s, or

the 3 s electrons have a higher energy than 1 s, 2 s, or 2 p electrons,

so 3 s electrons are generally found further from the nucleus than 1 s,

so 3 s electrons are generally found further from the nucleus than 1 s, 2 s, or 2 p electrons

Summary of Trend • Periodic Table and Periodic Trends • 1. Electron Configuration 3.

Summary of Trend • Periodic Table and Periodic Trends • 1. Electron Configuration 3. Ionization Energy: Largest toward NE of PT 4. Electron Negativity: Most favorable NE of PT 2. Atomic Radius: Largest toward SW corner of PT

once each 2 p orbital is filled with a pair of electrons, then

once each 2 p orbital is filled with a pair of electrons, then

Electron Configuration- energy stair levels

Electron Configuration- energy stair levels

 General Rules • Aufbau Principle – Electrons fill lowest energy orbitals first. –

General Rules • Aufbau Principle – Electrons fill lowest energy orbitals first. – “Lazy Occupant Rule”

 General Rules • Hund’s Rule – Within a sublevel, place one e- per

General Rules • Hund’s Rule – Within a sublevel, place one e- per orbital before pairing them e- repel each other – “Empty Room Rule” WRONG RIGHT

 General Rules • Pauli Exclusion Principle – Each orbital can hold TWO electrons

General Rules • Pauli Exclusion Principle – Each orbital can hold TWO electrons with opposite spins.

Electron Notations • Orbital Diagram O 8 e- 1 s 2 s • Electron

Electron Notations • Orbital Diagram O 8 e- 1 s 2 s • Electron Configuration 2 2 4 1 s 2 s 2 p 2 p

 • Longhand e- Configuration S 16 e 6 2 2 2 1 s

• Longhand e- Configuration S 16 e 6 2 2 2 1 s 2 s 2 p 3 s Core Electrons Valence Electrons • Shorthand e- Configuration S 16 e 4 3 p 2 4 [Ne] 3 s 3 p

J. J. Thomson used cathode ray tube to discover electron Atomic Review Atomic Nomenclature

J. J. Thomson used cathode ray tube to discover electron Atomic Review Atomic Nomenclature 35 Mass # Cl Symbol 17 # protons Periodic Law- elements increase by atomic number and have a periodic trend or repetition of physical & chemical properties Average atomic mass- mass on PT Based on abundance of isotopes 1)Change % to decimal 2)Multiply decimal by the mass 3)Add the numbers together Electron Configuration Al 1 s 22 p 63 s 23 p 1

s p d © 1998 by Harcourt Brace & Company

s p d © 1998 by Harcourt Brace & Company

e- configuration table 1 s 1 s 2 s 2 p 3 s 3

e- configuration table 1 s 1 s 2 s 2 p 3 s 3 p 4 s 3 d 4 p 5 s 4 d 5 p 6 p 6 s La 5 d 7 s Ac 6 d 4 f 5 f

The Periodic Table s 1 1 2 3 4 5 6 7 s 2

The Periodic Table s 1 1 2 3 4 5 6 7 s 2 d 1 d 2 d 3 d 4 d 5 d 6 d 7 d 8 d 9 d 10 p 1 p 2 p 3 p 4 p 5 p 6 1 2 H He 3 4 Li Be 11 12 Na Mg 19 20 5 6 7 8 B C N O F Ne 13 14 15 16 17 P S 33 34 Al Si 21 22 23 24 25 26 27 28 29 30 31 32 9 10 18 Cl Ar 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te 55 56 57 72 73 74 75 76 77 78 Cs Ba La Hf Ta W Re Os Ir 87 88 89 104 105 106 107 108 79 80 81 d p f 83 84 54 I Xe 85 86 Pt Au Hg Tl Pb Bi Po At Rn 109 110 111 114 116 118 Uuq Uuh Uuo 112 Fr Ra Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub s 82 53 f 1 f 2 f 3 f 4 f 5 f 6 f 7 f 8 f 9 f 1 f 1 f 1 4 5 58 59 60 61 62 63 64 65 66 067 168 269 370 471 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

C. Periodic Patterns • Example - Hydrogen 1 1 s 1 st Period 1

C. Periodic Patterns • Example - Hydrogen 1 1 s 1 st Period 1 st column of s-block

Electron Configuration • F • Cl • Al • Br

Electron Configuration • F • Cl • Al • Br

Orbital Diagrams F Cl Al Br 1 s 2 s 2 p 3 s

Orbital Diagrams F Cl Al Br 1 s 2 s 2 p 3 s 3 p 1 s 2 s 2 p 3 s 1 s 2 s 2 p 1 s 2 s 4 s 3 d 4 p 3 p 4 s 3 d 4 p 3 s 3 p 4 s 3 d 4 p 2 p 3 s 3 p 4 s 3 d 4 p

Electron Configuration • F 1 s 22 p 5 • Cl 1 s 22

Electron Configuration • F 1 s 22 p 5 • Cl 1 s 22 p 63 s 23 p 5 • Al 1 s 22 p 63 s 23 p 1 • Br 1 s 22 p 63 s 23 p 64 s 23 d 104 p 5

Write Orbital and Electron Configurations • N • Si • Mg • Ga

Write Orbital and Electron Configurations • N • Si • Mg • Ga

Orbital Diagrams N Si Mg Ga 1 s 2 s 2 p 3 s

Orbital Diagrams N Si Mg Ga 1 s 2 s 2 p 3 s 1 s 2 s 2 p 1 s 2 s 3 p 4 s 3 d 4 p 3 s 3 p 4 s 3 d 4 p 2 p 3 s 3 p 4 s 3 d 4 p

Electron Configuration • N 1 s 22 p 3 • Si 1 s 22

Electron Configuration • N 1 s 22 p 3 • Si 1 s 22 p 63 s 23 p 2 • Mg 1 s 22 p 63 s 2 • Ga 1 s 22 p 63 s 23 p 64 s 23 d 104 p 1 • Now write the above in short hand configuration

Electron Configuration • N [He]2 s 22 p 3

Electron Configuration • N [He]2 s 22 p 3

Electron Configuration • Si [Ne]3 s 23 p 2

Electron Configuration • Si [Ne]3 s 23 p 2

Electron Configuration • Mg [Ne]3 s 2

Electron Configuration • Mg [Ne]3 s 2

Electron Configuration • Ga [Ar]4 s 23 d 104 p 1

Electron Configuration • Ga [Ar]4 s 23 d 104 p 1

 Periodic Patterns • Example - Germanium [Ar] 2 4 s 10 3 d

Periodic Patterns • Example - Germanium [Ar] 2 4 s 10 3 d 2 4 p

 • Notable families of the Periodic Table Halogen Noble Gas Chalcogens Alkaline (earth)

• Notable families of the Periodic Table Halogen Noble Gas Chalcogens Alkaline (earth) Transition Metals

Electron Stability • Full energy level • Full sublevel (s, p, d, f) •

Electron Stability • Full energy level • Full sublevel (s, p, d, f) • Half-full sublevel

Stability • Electron Configuration Exceptions – Copper EXPECT: ACTUALLY: [Ar] 4 s 2 3

Stability • Electron Configuration Exceptions – Copper EXPECT: ACTUALLY: [Ar] 4 s 2 3 d 9 [Ar] 4 s 1 3 d 10 – Copper gains stability with a full d-sublevel.

“ 5 Facts 5 Pictures” Review Interesting Fact 1 - define or explain Interesting

“ 5 Facts 5 Pictures” Review Interesting Fact 1 - define or explain Interesting Fact 3 define or explain [picture] [Picture] Most Important Concept or Fact 5 Describe and explain What you learned [Picture] Interesting Fact 2 - define or explain [picture] Interesting Fact 4 - define or explain [picture]

J. J. Thomson used cathode ray tube to discover electron Atomic Review Atomic Nomenclature

J. J. Thomson used cathode ray tube to discover electron Atomic Review Atomic Nomenclature 35 Mass # Cl Symbol 17 # protons Periodic Law- elements increase by atomic number and have a periodic trend or repetition of physical & chemical properties Average atomic mass- mass on PT Based on abundance of isotopes 1)Change % to decimal 2)Multiply decimal by the mass 3)Add the numbers together Electron Configuration Al 1 s 22 p 63 s 23 p 1

D. Stability • Electron Configuration Exceptions – Chromium EXPECT: ACTUALLY: [Ar] 4 s 2

D. Stability • Electron Configuration Exceptions – Chromium EXPECT: ACTUALLY: [Ar] 4 s 2 3 d 4 [Ar] 4 s 1 3 d 5 – Chromium gains stability with a half-full dsublevel.

 Stability • Ion Formation – Atoms gain or lose electrons to become more

Stability • Ion Formation – Atoms gain or lose electrons to become more stable. – Noble Gases.

D. Stability • Ion Electron Configuration – Write the e- config for the closest

D. Stability • Ion Electron Configuration – Write the e- config for the closest Noble Gas – EX: Oxygen ion O 2 - Ne O 2 - 10 e- [He] 2 s 2 2 p 6

4. Trend in Electron Affinity: The energy release when an electron is added to

4. Trend in Electron Affinity: The energy release when an electron is added to an atom. Most favorable toward NE corner of PT since these atoms have a great affinity for e-.

Periods- left to right Groups- up & down, numbered 1 -18 or 1 A-8

Periods- left to right Groups- up & down, numbered 1 -18 or 1 A-8 A, Representative Elements- Group A Elements, Group 1, 2, & 13 -18 (8 groups represented)