FLUCO FLUids incl gases vapors and COmplex fluids

FLUCO FLUids incl. gases, vapors and COmplex fluids - H. Schneider - WP In Kind Started/Start at In Kind Planned In house / Cash External collaboration Started, ongoing FINISHED Partner Gas-processingsystem U. Tartu(EE) Laser Pump Probe U. Tartu(EE) 16 17 18 19 Pool Equipment FINISHED U. Tartu(EE) Humidity Chamber U. Tartu(EE) Rheometer FZJ , (Ge) Light scattering Flexi. Prob 5 x SANS Peltier RUC, (DK) Rotating cells Thermalizing Bl. 22 23 24 25 Ready to run at instruments ESS FZJ , (Ge) Chem. Cell ESS Cells/solid-liquid ESS Lab Equipment ESS El. Chem. Dev. /Cell ESS Lab building available Note: 21 Equipment available Testet/integrated Technicians trained Laser Pump Probe 2 U. Tartu(EE) Stopped-flow-Cell 20 Hot commissioning first instruments Available means running (tested), integrated (remote enabled) , staff trained Ready for means available and adapted to instrument (x, y, z), triggered by final sample area design of instrument (x, y, z)

FLUCO FLUids incl. gases, vapors and COmplex fluids - H. Schneider - Toolbox capability for individual setup’s - Sample environment is strongly user focused. - Different experimental setup’s , using special customer cells/chambers. - FLUCO acts as a toolbox to provide physical standard parameter. - Gases/Temperature/mechanical movement/humidity/light(laser)/. . - Focus on In Situ / (In) Operando - techniques - Gas manifolds (also corrosive gases) started, manual <=100 bar done. - Devices procured Consumables (all kinds) and “Julabos” procurement started, 6 available. Solartron -Potentiostat/RF response analyzer Precision Resistance bridge HPLC Pump Syringe pumps Peristaltic pump 12 channel temperature monitor

FLUCO changer FLUids incl. gases, Sample vapors and COmplex fluids - H. Schneider - Possible principles of “non human driven” sample changer 1. ) SANS – changer , also possible for Reflectometer 3 • Thermalized magazine for SANS e. g. 50 pos. at the same Temperature. • Driven by open water bath circulator , appr. 10˚C – 80˚C. • Individual positions can have up 5 % error. • Useful for “rough” thermalization • All samples at the same Temperature • Magazine with individual T. -control , e. g. RUC/ESS project • Driven by Peltier element on each position, open water bath circulator rough base temp. • Each position is independent , from 5 ˚C to 120˚C (with dry gas atmosphere down to -20˚C) • More work needed for mechanical upgrade and electronics • Also tumbler magazines , with or without temperature control

FLUCO FLUids incl. gases, vapors and COmplex fluids - H. Schneider - Possible principles of “non human driven” sample changer For diffractometer and spectrometer 2. ) Sample changers / Sample environment system changers. - e. g. Cells/sample sticks/cuvettes/troughs, … Robotics / translation- / rotational stage , and/or chain transport Examples : Changer at POWGEN / VISION / TOSCA Before starting two requirements have to be defined. v Sample area of instruments has to be fixed/defined. v Devices (SES) have to be defined in ü Shape ü Weight ü Connected pipes/cables ü Risc assessment q Sample environment itself will be changed, ambient temperatures, He flow cryostat q Most changer systems will be related to one instrument 4

FLUCO FLUids incl. gases, vapors and COmplex fluids - H. Schneider - Temperature range 5˚C – 120˚C Base plate thermalized by circulator - In “dry” atmosphere: temperatures down to – 20˚C Cuvette holder SANS-Peltier-changer Channel - 5 - Thermalised base plate Channel - 4 Each position with individual controlled T performed by Peltier elements Cuvette holder w. Peltier elements Channel - 3 - Principle sketch of the device Channel - 2 Magazine 5 positions, up to 10 possible Different sizes of quartz /sapphire cuvettes Stackable to 4 (5) x 10 Positions Dedicated for SANS applications Channel - 1 - BOOSTER 5 IK Partner: B Jakobson, C Niss, RUC 5

FLUCO changer FLUids incl. gases, Sample vapors and COmplex fluids - H. Schneider - Planned suite of sample environment equipment, started Provided as internal R&D , FLUCO & Basque intern Sonia G. Scheifler 7 position rotating sample holder magazine 6

FLUCO changer FLUids incl. gases, Sample vapors and COmplex fluids - H. Schneider - 7