Drill Name the following Alkenes Alkenes Hydrocarbons with
Drill: Name the following:
Alkenes
Alkenes • Hydrocarbons with at least one double bond
Alkenes • Each double bond reduces the number of hydrogens in the hydrocarbon by two
Alkenes • All alkenes are unsaturated hydrocarbons
Unsaturated Hydrocarbons • Contain less than the maximum number of hydrogens
Alkenes
Naming Alkenes • Number the carbons on the chain; so that, the double bond has the lowest possible number
Naming Alkenes • The double bond will always fall between two numbered carbons
Naming Alkenes • Apply the lower of those two numbers to the double bond
Naming Alkenes 4 2 1 3 2 -butene or Buta-2 -ene
Problems 4 2 1 3 4
Geometric Isomers 4 2 1 3 4
Geometric Isomers • Isomers whose arrangement is same side (cis) or opposite side (trans) of a stationary bond
Naming Alkenes • Draw a line through the double bond parallel to each of the bonds in the double bond
Naming Alkenes 4 2 1 3
Naming Alkenes • If the two ends of the chain are on the same side of the line, it is a cis-double bond
Naming Alkenes • If the two ends of the chain are on opposite sides of the line, it is a trans-double bond
Naming Alkenes • Place cis or trans at the start of the name in the organic compound
trans-2 -butene trans-buta-2 -ene 4 2 1 3
Draw the Following: trans-3 -ethyl-4, 6 dimethyl-5 cyclopentyl-2 -octene
Drill: Draw the condensed, skeletal, & stick structures for: cis-3 -ethyl-4, 6 -dimethyl-5 cyclopropyl-2 -octene
Review Alkenes & Cycloalkanes
Name:
Main chain
Name ending
Branches
trans-3, 4 -dimethyl 3 -hexene
Name:
Main Chain
Name ending
Branches
trans-3 -methyl-2 cyclopropyl-3 -heptene
Name:
Main Chain
Name Ending
Branches
cis, trans-7 -methyl 2, 4 -nonadiene
Name:
Main chain or cycle:
Branches:
1, 1, 2, 2, 4, 4 hexamethylcyclohexane:
Name:
Main chain or cycle:
Branches:
Cyclohexylcyclohexane:
Name:
Main chain or cycle:
Branches:
1, 4 -dicyclohexyl cyclohexane:
Draw: • trans-1 cyclobutyl-2 methyl-3 -hexene
Draw: cis-2 -methyl-1 octylcyclohexene
Draw & Name isomers of: • C 5 H 10
Naming Alkenes • Name the alkenes on the board
- Slides: 55