Chapter Fifteen Aldehydes And Ketones Aldehydes and Ketones

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Chapter Fifteen Aldehydes And Ketones

Chapter Fifteen Aldehydes And Ketones

Aldehydes and Ketones → CO 15. 1 Benzaldehyde is the main flavor component of

Aldehydes and Ketones → CO 15. 1 Benzaldehyde is the main flavor component of almonds. Photo. Disc Copyright © Houghton Mifflin Company. All rights reserved. 2

Aldehydes and Ketones cont’d ← Fig. 15. 1 Aldehydes and ketones are related to

Aldehydes and Ketones cont’d ← Fig. 15. 1 Aldehydes and ketones are related to alcohols in the same manner that alkenes are related to alkanes. Copyright © Houghton Mifflin Company. All rights reserved. 3

Aldehydes and Ketones cont’d ← Fig. 15. 2 Benzaldehyde, the simplest aromatic aldehyde. .

Aldehydes and Ketones cont’d ← Fig. 15. 2 Benzaldehyde, the simplest aromatic aldehyde. . Copyright © Houghton Mifflin Company. All rights reserved. 4

Aldehydes and Ketones cont’d ←C. C 15. 1 © Harvey Lloyd/Peter Arnold, Inc. Copyright

Aldehydes and Ketones cont’d ←C. C 15. 1 © Harvey Lloyd/Peter Arnold, Inc. Copyright © Houghton Mifflin Company. All rights reserved. 5

Aldehydes and Ketones → Fig. 15. 3 Aldehydes and ketones with the same number

Aldehydes and Ketones → Fig. 15. 3 Aldehydes and ketones with the same number of carbon atoms and the same degree of saturation are structural isomers. Copyright © Houghton Mifflin Company. All rights reserved. 6

Aldehydes and Ketones cont’d ← Fig. 15. 4 Formalin is used to preserve biological

Aldehydes and Ketones cont’d ← Fig. 15. 4 Formalin is used to preserve biological specimens. © 2005 Norbert Wu / www. norbertwu. com Copyright © Houghton Mifflin Company. All rights reserved. 7

Aldehydes and Ketones cont’d ← Table 15. 1 © 2005 Norbert Wu / www.

Aldehydes and Ketones cont’d ← Table 15. 1 © 2005 Norbert Wu / www. norbertwu. com Copyright © Houghton Mifflin Company. All rights reserved. 8

Aldehydes and Ketones → Fig. 15. 5 The delightful odor of melted butter is

Aldehydes and Ketones → Fig. 15. 5 The delightful odor of melted butter is largely due to butanedione. © Steven Needham / Envision Copyright © Houghton Mifflin Company. All rights reserved. 9

Aldehydes and Ketones cont’d ← Table 15. 2 Copyright © Houghton Mifflin Company. All

Aldehydes and Ketones cont’d ← Table 15. 2 Copyright © Houghton Mifflin Company. All rights reserved. 10

Aldehydes and Ketones cont’d ← Fig. 15. 6 Physical-state summary for unbranched aldehydes and

Aldehydes and Ketones cont’d ← Fig. 15. 6 Physical-state summary for unbranched aldehydes and unbranched 2 -ketones at room temperature and pressure. Copyright © Houghton Mifflin Company. All rights reserved. 11

Aldehydes and Ketones cont’d ←CC 15. 2 © S. Mc. Cutcheon / Visuals Unlimited

Aldehydes and Ketones cont’d ←CC 15. 2 © S. Mc. Cutcheon / Visuals Unlimited Copyright © Houghton Mifflin Company. All rights reserved. 12

Aldehydes and Ketones Fig. 15. 7 Copyright © Houghton Mifflin Company. All rights reserved.

Aldehydes and Ketones Fig. 15. 7 Copyright © Houghton Mifflin Company. All rights reserved. 13

Aldehydes and Ketones Table 15. 3 Copyright © Houghton Mifflin Company. All rights reserved.

Aldehydes and Ketones Table 15. 3 Copyright © Houghton Mifflin Company. All rights reserved. 14

Aldehydes and Ketones CC 15. 3 Diabetes, aldehyde oxidation, and glucose testing Copyright ©

Aldehydes and Ketones CC 15. 3 Diabetes, aldehyde oxidation, and glucose testing Copyright © Houghton Mifflin Company. All rights reserved. 15

Aldehydes and Ketones cont’d Figs. 15. 8 a-c (a) An aqueous solution of ethanal

Aldehydes and Ketones cont’d Figs. 15. 8 a-c (a) An aqueous solution of ethanal is added to a solution of silver nitrate. (b) The solution darkens as ethanal is oxidized to ethanoic acid. Copyright © Houghton Mifflin Company. All rights reserved. (c) The inside of the beaker becomes coated with metallic silver. 16

Aldehydes and Ketones → Fig. 15. 9 Benedict’s solution turns brick red when an

Aldehydes and Ketones → Fig. 15. 9 Benedict’s solution turns brick red when an aldehyde reacts with it. Copyright © Houghton Mifflin Company. All rights reserved. 17

Aldehydes and Ketones cont’d Fig. 15. 10 Acetaldehyde and its hemiacetal and acetal formed

Aldehydes and Ketones cont’d Fig. 15. 10 Acetaldehyde and its hemiacetal and acetal formed by reaction with ethyl alcohol. Copyright © Houghton Mifflin Company. All rights reserved. 18

Aldehydes and Ketones Fig. 15. 11 When a mixture of phenol and formaldehyde dissolved

Aldehydes and Ketones Fig. 15. 11 When a mixture of phenol and formaldehyde dissolved in acetic acid is treated with concentrated hydrocloric acid, a cross-linked phenolformaldehyde network polymer is formed. Copyright © Houghton Mifflin Company. All rights reserved. 19

Aldehydes and Ketones CC 15. 4 Copyright © Houghton Mifflin Company. All rights reserved.

Aldehydes and Ketones CC 15. 4 Copyright © Houghton Mifflin Company. All rights reserved. 20

Aldehydes and Ketones cont’d ← Fig. 15. 12 Bakelite jewelry in use during the

Aldehydes and Ketones cont’d ← Fig. 15. 12 Bakelite jewelry in use during the 1930 -1950 time period. © Coco Mc. Coy / Rainbow Copyright © Houghton Mifflin Company. All rights reserved. 21