Chapter 6 Inorganic and Organic Compounds Names and

  • Slides: 88
Download presentation
Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 1 1 Basic Chemistry

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 1 1 Basic Chemistry Octet Rule and Ions Copyright © 2011 Pearson Education, Inc.

Octet Rule An octet • is 8 valence electrons • is associated with the

Octet Rule An octet • is 8 valence electrons • is associated with the stability of the noble gases • does not occur with He, which is stable with two valence electrons (duet) Valence electrons He 1 s 2 2 2 Ne 1 s 22 p 6 8 Ar 1 s 22 p 63 s 23 p 6 8 Kr 1 s 22 p 63 s 23 p 64 s 23 d 104 p 6 8 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Forming Octets Atoms acquire octets • to become more stable • by losing, gaining,

Forming Octets Atoms acquire octets • to become more stable • by losing, gaining, or sharing valence electrons • by forming ionic or covalent bonds 3 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Ionic and Covalent Bonds Ionic bonds involve • loss of electrons by a metal

Ionic and Covalent Bonds Ionic bonds involve • loss of electrons by a metal • gain of electrons by a nonmetal Covalent bonds involve • a sharing of electrons 4 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Metals Form Positive Ions Metals form positive ions (CATIONS) • by a loss of

Metals Form Positive Ions Metals form positive ions (CATIONS) • by a loss of their valence electrons • with the electron configuration of their nearest noble gas • that have fewer electrons than protons. Group 1 A (1) metals Group 2 A (2) metals Group 3 A (13) metals 5 Basic Chemistry ion+ ion 2+ ion 3+ Copyright © 2011 Pearson Education, Inc.

Formation of a Sodium Ion, Na+ Sodium achieves an octet by losing its one

Formation of a Sodium Ion, Na+ Sodium achieves an octet by losing its one valence electron. 6 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge of Sodium Ion, Na+ With the loss of its valence electron, the sodium

Charge of Sodium Ion, Na+ With the loss of its valence electron, the sodium ion has a 1+ charge. Sodium atom 11 p+ 11 e 0 7 Basic Chemistry Sodium ion 11 p+ 10 e 1+ Copyright © 2011 Pearson Education, Inc.

Formation of Mg 2+ • Magnesium achieves an octet by losing its two valence

Formation of Mg 2+ • Magnesium achieves an octet by losing its two valence electrons. 8 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge of Magnesium Ion, Mg 2+ With the loss of two valence electrons, magnesium

Charge of Magnesium Ion, Mg 2+ With the loss of two valence electrons, magnesium forms a positive ion with a 2+ charge. Mg atom 12 p+ 12 e 0 9 Basic Chemistry Mg 2+ ion 12 p+ 10 e 2+ Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct answer for aluminum. A. The number of valence electrons

Learning Check Select the correct answer for aluminum. A. The number of valence electrons is _____. 1) 1 e 2) 2 e 3) 3 e B. The electron change for the octet is _____. 1) loss of 3 e 2) gain of 3 e 3) gain of 5 e C. The ionic charge of the aluminum ion is _____. 1) 3 2) 5 3) 3+ D. The symbol for the aluminum ion is _____. 1) Al 3+ 2) Al 33) Al+ 10 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Select the correct answer for aluminum. The number of valence electrons is ___. 1)

Select the correct answer for aluminum. The number of valence electrons is ___. 1) 2) 3) 1 e 2 e 3 e 11 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Select the correct answer for aluminum. The electron change for the octet is _.

Select the correct answer for aluminum. The electron change for the octet is _. 1) 2) 3) loss of 3 e gain of 5 e 12 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Select the correct answer for aluminum. The ionic charge of the aluminum ion is

Select the correct answer for aluminum. The ionic charge of the aluminum ion is 1) 2) 3) 3 5 3+ 13 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Select the correct answer for aluminum. The symbol for the aluminum ion is __.

Select the correct answer for aluminum. The symbol for the aluminum ion is __. 1) 2) 3) Al 3+ Al 3 Al+ 14 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Select the correct answer for aluminum: A. The number of valence electrons is

Solution Select the correct answer for aluminum: A. The number of valence electrons is 3) 3 e B. The electron change for the octet is 1) loss of 3 e C. The ionic charge of the aluminum ion is 3) 3+ D. The symbol for the aluminum ion is 1) Al 3+ 15 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Formation of Negative Ions In ionic compounds, nonmetals (FORM ANIONS) • achieve an octet

Formation of Negative Ions In ionic compounds, nonmetals (FORM ANIONS) • achieve an octet arrangement • gain electrons • form negatively charged ions with 3 , 2 , or 1 charges 16 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Formation of Chloride Ion, Cl • Chlorine achieves an octet by adding an electron

Formation of Chloride Ion, Cl • Chlorine achieves an octet by adding an electron to its valence electrons. 17 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge of a Chloride Ion, Cl. A chloride ion forms • when Cl gains

Charge of a Chloride Ion, Cl. A chloride ion forms • when Cl gains one electron • with a 1 charge Chlorine atom 17 p+ 17 e 0 18 Basic Chemistry Chloride ion 17 p+ 18 e 1 Copyright © 2011 Pearson Education, Inc.

Some Typical Ionic Charges 19 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Typical Ionic Charges 19 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Ionic Charge from Group Numbers Ions • achieve the electron configuration of their nearest

Ionic Charge from Group Numbers Ions • achieve the electron configuration of their nearest noble gas • of metals in Group 1 A (1), Group 2 A (2), or Group 3 A (13) have positive 1+. 2+, or 3+ charges • of nonmetals in Groups 5 A (15), 6 A (16), or 7 A (17) have negative 3 , 2 , or 1 charges The charge of an ion is obtained by subtracting 8 or 18 from its Group number. Example: Group 6 A (16) = 6 8 = 2 or 16 18 = 2 20 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Ions and Their Nearest Noble Gases 21 Basic Chemistry Copyright © 2011 Pearson

Some Ions and Their Nearest Noble Gases 21 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct answer for sulfur. A. The group number for sulfur

Learning Check Select the correct answer for sulfur. A. The group number for sulfur is _____. B. The number of valence electrons in sulfur is ____. 1) 4 e 2) 6 e 3) 8 e. C. The change in electrons for an octet requires a 1) loss of 2 e 2) gain of 2 e 3) gain of 4 e D. The ionic charge of a sulfide ion is _____. 1) 2+ 2) 2 3) 4 22 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution A. The group number for sulfur is 3) 6 A (16) B. The

Solution A. The group number for sulfur is 3) 6 A (16) B. The number of valence electrons in sulfur is 2) 6 e C. The change in electrons for an octet requires a 2) gain of 2 e D. The ionic charge of a sulfide ion 2) 2 23 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 2 Ionic Compounds 24

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 2 Ionic Compounds 24 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Ionic Compounds Ionic compounds • consist of positive and negative ions • have attractions

Ionic Compounds Ionic compounds • consist of positive and negative ions • have attractions called ionic bonds between positively and negatively charged ions • have high melting and boiling points • are solids at room temperature 25 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Salt is an Ionic Compound Sodium chloride (table salt) is an example of an

Salt is an Ionic Compound Sodium chloride (table salt) is an example of an ionic compound. 26 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Ionic Formulas An ionic formula • consists of positively and negatively charged ions •

Ionic Formulas An ionic formula • consists of positively and negatively charged ions • is neutral • has charge balance (net charge of zero) total positive charge = total negative charge • uses subscripts to indicate the number of ions needed to give charge balance 27 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge Balance for Na. Cl, “Salt” In Na. Cl, • a Na atom loses

Charge Balance for Na. Cl, “Salt” In Na. Cl, • a Na atom loses its valence electron • a Cl atom gains an electron • the symbol of the metal is written first followed by the symbol of the nonmetal • the charges of the ions in the compound are not shown 28 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge Balance in Na. F • The formulas of ionic compounds are determined from

Charge Balance in Na. F • The formulas of ionic compounds are determined from the charges on the ions. atoms ions Na + F : Na+ sodium fluorine : F: Na. F sodium fluoride The overall charge of Na. F is zero (0). Na+ F 1(1+ ) + 1(1 ) 29 Basic Chemistry = Na. F = 0 Copyright © 2011 Pearson Education, Inc.

Charge Balance In Mg. Cl 2 • a Mg atom loses two valence electrons

Charge Balance In Mg. Cl 2 • a Mg atom loses two valence electrons • two Cl atoms each gain one electron • subscripts indicate the number of ions needed to give charge balance 30 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Charge Balance In Na 2 S, • two Na atoms lose one valence electron

Charge Balance In Na 2 S, • two Na atoms lose one valence electron each • one S atom gains two electrons • subscripts show the number of ions needed to give charge balance 31 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Writing Ionic Formulas from Charges Charge balance is used to write the formula for

Writing Ionic Formulas from Charges Charge balance is used to write the formula for sodium nitride, a compound containing Na+ and N 3−. 3 32 Na+ Na+ + N 3− = 3(+1) + 1(3 ) = Basic Chemistry Na 3 N 0 Copyright © 2011 Pearson Education, Inc.

Formula from Ionic Charges Write the ionic formula of the compound containing Ba 2+

Formula from Ionic Charges Write the ionic formula of the compound containing Ba 2+ and Cl. • Write the symbols of the ions. Ba 2+ Cl • Balance the charges. Ba 2+ Cl Cl two Cl needed • Write the ionic formula using a subscript 2 for two chloride ions that give charge balance. Ba. Cl 2 33 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct formula for each of the following ionic compounds: A.

Learning Check Select the correct formula for each of the following ionic compounds: A. Li+ and O 2 1) Li. O 2) Li 2 O 3) Li. O 2 B. Al 3+ and Cl 1) Al. Cl 3 2) Al. Cl 3) Al 3 Cl C. Mg 2+ and N 3 1) Mg. N 2) Mg 2 N 3 3) Mg 3 N 2 34 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

What is the chemical formula for 1. 2. 3. Li. O Li 2 O

What is the chemical formula for 1. 2. 3. Li. O Li 2 O Li. O 2 35 + Li and Basic Chemistry 2 O Copyright © 2011 Pearson Education, Inc.

What is the chemical formula for 1. 2. 3. Al. Cl 3 Al. Cl

What is the chemical formula for 1. 2. 3. Al. Cl 3 Al. Cl Al 3 Cl 36 3+ Al and Basic Chemistry Cl Copyright © 2011 Pearson Education, Inc.

What is the chemical formula for 1. 2. 3. Mg. N Mg 2 N

What is the chemical formula for 1. 2. 3. Mg. N Mg 2 N 3 Mg 3 N 2 37 2+ Mg Basic Chemistry and 3 N Copyright © 2011 Pearson Education, Inc.

Solution A. Li+ and O 2 2) Li 2 O check: 2 Li+ +

Solution A. Li+ and O 2 2) Li 2 O check: 2 Li+ + O 2– = 2(1+) + 1(2–) = 0 B. Al 3+ and Cl 1) Al. Cl 3 check: Al 3+ + 3 Cl– = (3+) + 3(1–) = 0 C. Mg 2+ and N 3 3) Mg 3 N 2 check: 3 Mg 2+ +2 N 3– = 3(2+) + 2(3–) = 0 38 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 3 Naming and Writing

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 3 Naming and Writing Ionic Formulas 39 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming of Ionic Compounds In the name of an ionic compound, • the positive

Naming of Ionic Compounds In the name of an ionic compound, • the positive ion (first ion) is named as the element • the negative ion (second ion) is named by changing the end of the element name to –ide 40 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Complete the names of the following ions: Ba 2+ Al 3+ K+

Learning Check Complete the names of the following ions: Ba 2+ Al 3+ K+ __________ N 3 _____ O 2 _____ F _____ P 3 _____ S 2 _____ Cl _____ 41 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Ba 2+ barium Al 3+ aluminum K+ potassium N 3 O 2 F

Solution Ba 2+ barium Al 3+ aluminum K+ potassium N 3 O 2 F nitride oxide fluoride P 3 S 2 Cl phosphide sulfide chloride 42 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Ionic Compounds with Two Elements 43 Basic Chemistry Copyright © 2011 Pearson Education,

Naming Ionic Compounds with Two Elements 43 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Examples of Ionic Compounds with Two Elements Formula Name Na. Cl Ions Cation Anion

Examples of Ionic Compounds with Two Elements Formula Name Na. Cl Ions Cation Anion Na+ Cl K 2 S K+ S 2 potassium sulfide Mg. O Mg 2+ O 2 magnesium oxide Ca. I 2 Ca 2+ I calcium iodide Al 2 O 3 Al 3+ O 2 aluminum oxide 44 Basic Chemistry sodium chloride Copyright © 2011 Pearson Education, Inc.

Some Ionic Compounds 45 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Ionic Compounds 45 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Write the formulas and names for compounds of the following ions: Br−

Learning Check Write the formulas and names for compounds of the following ions: Br− S 2− N 3− Na+ Al 3+ 46 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Br− 47 S 2− N 3− Na+ Na. Br sodium bromide Na 2

Solution Br− 47 S 2− N 3− Na+ Na. Br sodium bromide Na 2 S sodium sulfide Na 3 N sodium nitride Al 3+ Al. Br 3 aluminum bromide Al 2 S 3 aluminum sulfide Al. N aluminum nitride Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Write the names of each of the following compounds: 1) Ca. O

Learning Check Write the names of each of the following compounds: 1) Ca. O ______ 2) KBr ______ 3) Al 2 O 3 ______ 4) Mg. Cl 2 ______ 48 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Write the names of each of the following compounds: 1) Ca. O calcium

Solution Write the names of each of the following compounds: 1) Ca. O calcium oxide 2) KBr potassium bromide 3) Al 2 O 3 aluminum oxide 4) Mg. Cl 2 magnesium chloride 49 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Transition Metals That Form Two or More Positive Ions Most transition metals and Group

Transition Metals That Form Two or More Positive Ions Most transition metals and Group 4 (14) metals • form two or more positive ions • Zn 2+, Ag+, and Cd 2+ form only one ion Examples: Copper forms Cu+ and Cu 2+ Iron forms Fe 2+ and Fe 3+ Gold forms Au+ and Au 3+ 50 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Metals with Variable Charge 51 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Metals with Variable Charge 51 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Periodic Table and Typical Ions 52 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Periodic Table and Typical Ions 52 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Examples of Names of Compounds with Variable Charge Metals Transition metals • with two

Examples of Names of Compounds with Variable Charge Metals Transition metals • with two different ions use a Roman numeral after the name of the metal to indicate the ionic charge • only zinc, silver, and cadmium do not use a Roman numeral because they form only one ion (Zn 2+, Ag+, and Cd 2+) 53 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Ionic Compounds with Variable Charge Metals 54 Basic Chemistry Copyright © 2011 Pearson

Naming Ionic Compounds with Variable Charge Metals 54 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Fe. Cl 2 STEP 1 Determine the charge of the cation from the

Naming Fe. Cl 2 STEP 1 Determine the charge of the cation from the anion. Fe (? ) + 2 Cl = Fe (? ) + 2(1 ) = 0 Fe (? ) = 2+ = Fe 2+ STEP 2 Name the cation by its element name and use a Roman numeral in parentheses for the charge. Fe 2+ = iron(II) 55 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Fe. Cl 2 (continued) STEP 3 Name the anion by using the first

Naming Fe. Cl 2 (continued) STEP 3 Name the anion by using the first syllable of its element name followed by ide. chloride STEP 4 Write the name of the cation first and the name of the anion second. iron(II) chloride = Fe. Cl 2 56 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Cr 2 O 3 STEP 1 Determine the charge of the cation from

Naming Cr 2 O 3 STEP 1 Determine the charge of the cation from the anion. 2 Cr(? ) + 3 O 2 = 2 Cr (? ) + 3(2 ) = 0 2 Cr(? ) = 6+ Cr(? ) = 3+ = Cr 3+ STEP 2 Name the cation by its element name and use a Roman numeral in parentheses for the charge. Cr 3+ = chromium(III) 57 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Naming Fe. Cl 2 (continued) STEP 3 Name the anion by using the first

Naming Fe. Cl 2 (continued) STEP 3 Name the anion by using the first syllable of its element name followed by ide. oxide STEP 4 Write the name of the cation first and the name of the anion second. chromium(III) oxide 58 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct name for each. A. Fe 2 S 3 1)

Learning Check Select the correct name for each. A. Fe 2 S 3 1) iron sulfide 2) iron(II) sulfide 3) iron (III) sulfide B. Cu. O 1) copper oxide 2) copper(I) oxide 3) copper (II) oxide 59 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Select the correct name for each. A. Fe 2 S 3 3) iron

Solution Select the correct name for each. A. Fe 2 S 3 3) iron (III) sulfide Fe 3+ S 2 B. Cu. O 3) copper (II) oxide 60 Basic Chemistry Cu 2+ O 2 Copyright © 2011 Pearson Education, Inc.

Guide to Writing Formulas from the Name 61 Basic Chemistry Copyright © 2011 Pearson

Guide to Writing Formulas from the Name 61 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Writing Formulas Write the formula of potassium sulfide. STEP 1 STEP 2 STEP 3

Writing Formulas Write the formula of potassium sulfide. STEP 1 STEP 2 STEP 3 62 Basic Chemistry Identify the cation and anion. potassium = K+ sulfide = S 2− Balance the charges. K+ S 2− K+ 2(1+) + 2(1 ) = 0 Write the formula, cation first, using the subscripts from the charge balance. 2 K+ and 1 S 2− = K 2 S Copyright © 2011 Pearson Education, Inc.

Writing Formulas Write the formula of cobalt(III) chloride. STEP 1 Identify the cation and

Writing Formulas Write the formula of cobalt(III) chloride. STEP 1 Identify the cation and anion. cobalt (III) = Co 3+ (III = charge of 3+) chloride = Cl− Balance the charges. STEP 2 Co 3+ and 3 Cl− = (3+) + 3(1 -) = 0 STEP 3 Write the formula, cation first, using the subscripts from the charge balance. 1 Co 3+ and 3 Cl− 63 Basic Chemistry = Co. Cl 3 Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct formula for each of the following: A. copper (I)

Learning Check Select the correct formula for each of the following: A. copper (I) nitride 1) Cu. N 2) Cu. N 3 3) Cu 3 N 2) Pb. O 3) Pb 2 O 4 B. lead (IV) oxide 1) Pb. O 2 64 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution A. copper (I) nitride 3) Cu 3 N 3 Cu+ and N 3−

Solution A. copper (I) nitride 3) Cu 3 N 3 Cu+ and N 3− B. lead (IV) oxide 1) Pb. O 2 Pb 4+ and 2 O 2− 65 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 4 Polyatomic Ions 66

Chapter 6 Inorganic and Organic Compounds: Names and Formulas 6. 4 Polyatomic Ions 66 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Polyatomic Ions A polyatomic ion • is a group of atoms • has an

Polyatomic Ions A polyatomic ion • is a group of atoms • has an overall ionic charge Examples: 67 NH 4+ ammonium OH− hydroxide NO 3− nitrate NO 2− nitrite CO 32− HCO 3− carbonate PO 43− phosphate hydrogen carbonate (bicarbonate) Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Compounds with Polyatomic Ions 68 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Compounds with Polyatomic Ions 68 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

More Names of Polyatomic Ions The names of the common polyatomic anions • end

More Names of Polyatomic Ions The names of the common polyatomic anions • end in ate NO 3− nitrate PO 43− phosphate • with one oxygen less end in ite NO 2− • nitrite PO 33− phosphite with hydrogen use prefix hydrogen (or bi) HCO 3− hydrogen carbonate (bicarbonate) HSO 3− hydrogen sulfite (bisulfite) 69 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Names and Formulas of Common Polyatomic Ions 70 Basic Chemistry Copyright © 2011 Pearson

Names and Formulas of Common Polyatomic Ions 70 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Compounds Containing Polyatomic Ions 71 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Some Compounds Containing Polyatomic Ions 71 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Prefixes for Names of Polyatomic Ions of Halogens Some polyatomic ions of the halogens

Prefixes for Names of Polyatomic Ions of Halogens Some polyatomic ions of the halogens require prefixes. Cl. O 4− perchlorate one oxygen more Cl. O 3− chlorate most common form Cl. O 2− chlorite one oxygen less Cl. O− hypochlorite two oxygens less 72 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Guide to Naming Compounds with Polyatomic Ions 73 Basic Chemistry Copyright © 2011 Pearson

Guide to Naming Compounds with Polyatomic Ions 73 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Examples of Naming Compounds with Polyatomic Ions In a compound with a negatively charged

Examples of Naming Compounds with Polyatomic Ions In a compound with a negatively charged polyatomic, • the positive ion is named first • followed by the name of the polyatomic ion Na. NO 3 sodium nitrate K 2 SO 4 potassium sulfate Fe(HCO 3)3 iron(III) bicarbonate or iron(III) hydrogen carbonate (NH 4)3 PO 3 74 Basic Chemistry ammonium phosphite Copyright © 2011 Pearson Education, Inc.

Learning Check Select the correct formula for each: A. aluminum nitrate 1) Al. NO

Learning Check Select the correct formula for each: A. aluminum nitrate 1) Al. NO 3 2) Al(NO)3 3) Al(NO 3)3 2) Cu(NO 3)2 3) Cu 2(NO 3) B. copper(II) nitrate 1) Cu. NO 3 C. iron (III) hydroxide 1) Fe. OH 2) Fe 3 OH 3) Fe(OH)3 2) Sn(OH)2 3) Sn 4(OH) D. tin(IV) hydroxide 1) Sn(OH)4 75 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Select the correct formula for each: A. aluminum nitrate 3) Al(NO 3)3 B.

Solution Select the correct formula for each: A. aluminum nitrate 3) Al(NO 3)3 B. copper(II) nitrate 2) Cu(NO 3)2 C. iron(III) hydroxide 3) Fe(OH)3 D. tin(IV) hydroxide 1) Sn(OH)4 76 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Match each formula with the correct name: A. Mg. S 1) magnesium

Learning Check Match each formula with the correct name: A. Mg. S 1) magnesium sulfite Mg. SO 3 2) magnesium sulfate Mg. SO 4 3) magnesium sulfide B. Ca(Cl. O 3)2 77 1) calcium chlorate Ca(Cl. O)2 2) calcium chlorite Ca(Cl. O 2)2 3) calcium hypochlorite Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Match each formula with the correct name: A. Mg. S 3) magnesium sulfide

Solution Match each formula with the correct name: A. Mg. S 3) magnesium sulfide Mg. SO 3 1) magnesium sulfite Mg. SO 4 2) magnesium sulfate B. Ca(Cl. O 3)2 78 1) calcium chlorate Ca(Cl. O)2 3) calcium hypochlorite Ca(Cl. O 2)2 2) calcium chlorite Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Name each of the following compounds: A. Mg(NO 3)2 B. Cu(Cl. O

Learning Check Name each of the following compounds: A. Mg(NO 3)2 B. Cu(Cl. O 3)2 C. Pb. O 2 D. Fe 2(SO 4)3 E. Ba 3(PO 3)2 79 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Name each of the following compounds: A. Mg(NO 3)2 magnesium nitrate B. Cu(Cl.

Solution Name each of the following compounds: A. Mg(NO 3)2 magnesium nitrate B. Cu(Cl. O 3)2 copper(II) chlorate C. Pb. O 2 lead (IV) oxide D. Fe 2(SO 4)3 iron(III) sulfate E. Ba 3(PO 3)2 barium phosphite 80 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Writing Formulas with Polyatomic Ions The formula of an ionic compound • containing a

Writing Formulas with Polyatomic Ions The formula of an ionic compound • containing a polyatomic ion must have a charge balance that equals zero(0) Na+ and NO 3− → Na. NO 3 • with two or more polyatomic ions encloses the polyatomic ions in parentheses Mg 2+ and 2 NO 3− → Mg(NO 3)2 subscript 2 for charge balance 81 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Write the correct formula for each: A. potassium bromate B. calcium carbonate

Learning Check Write the correct formula for each: A. potassium bromate B. calcium carbonate C. sodium phosphate D. iron(III) oxide E. iron (II) nitrite 82 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Write the correct formula for each: A. potassium bromate KBr. O 3 B.

Solution Write the correct formula for each: A. potassium bromate KBr. O 3 B. calcium carbonate Ca. CO 3 C. sodium phosphate Na 3 PO 4 D. iron(III) oxide Fe 2 O 3 E. iron (II) nitrite Fe(NO 2)2 83 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Flowchart for Naming Ionic Compounds 84 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Flowchart for Naming Ionic Compounds 84 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Name the following compounds: A. Ca 3(PO 4)2 B. Fe. Br 3

Learning Check Name the following compounds: A. Ca 3(PO 4)2 B. Fe. Br 3 C. Al 2 S 3 D. Mn(NO 2)2 E. Na. HCO 3 85 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Name the following compounds: A. Ca 3(PO 4)2 Ca 2+ PO 43− calcium

Solution Name the following compounds: A. Ca 3(PO 4)2 Ca 2+ PO 43− calcium phosphate B. Fe. Br 3 Fe 3+ Br − iron(III) bromide C. Al 2 S 3 Al 3+ S 2− aluminum sulfide D. Mn(NO 2)2 Mn 2+ NO 2− manganese(II) nitrite E. Na. HCO 3 Na+ HCO 3− sodium hydrogen carbonate (sodium bicarbonate) 86 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Learning Check Write the formulas for the following: A. calcium nitrate B. iron(II) hydroxide

Learning Check Write the formulas for the following: A. calcium nitrate B. iron(II) hydroxide C. aluminum carbonate D. copper(II) hypobromite E. lithium phosphate 87 Basic Chemistry Copyright © 2011 Pearson Education, Inc.

Solution Write the formulas for the following: A. calcium nitrate Ca 2+, NO 3−

Solution Write the formulas for the following: A. calcium nitrate Ca 2+, NO 3− Ca(NO 3)2 B. iron(II) hydroxide Fe 2+, OH− Fe(OH)2 C. aluminum carbonate Al 3+, CO 32− Al 2(CO 3) 3 D. copper(II) hypobromite Cu 2+, Br. O− Cu(Br. O)2 E. lithium phosphate Li 3 PO 4 88 Basic Chemistry Li+, PO 43− Copyright © 2011 Pearson Education, Inc.