Chapter 3 Spectral lines in stars Emission and

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Chapter 3: Spectral lines in stars

Chapter 3: Spectral lines in stars

Emission and absorption of light Continuous spectrum (thermal, blackbody) Independent of composition Emission line

Emission and absorption of light Continuous spectrum (thermal, blackbody) Independent of composition Emission line spectrum Dependent on composition

Each element has its own unique spectrum

Each element has its own unique spectrum

Absorption lines in the Sun’s spectrum

Absorption lines in the Sun’s spectrum

Absorption Line Spectrum Gustav Kirchhoff (1824 -1887)

Absorption Line Spectrum Gustav Kirchhoff (1824 -1887)

absorption lines of hydrogen

absorption lines of hydrogen

Emission Line Spectrum • Produced by a lowdensity gas • depends on composition and

Emission Line Spectrum • Produced by a lowdensity gas • depends on composition and temperature

Emission lines

Emission lines

The Balmer series for hydrogen: Visible light electrons falling to n=2 Rydberg formula (Balmer

The Balmer series for hydrogen: Visible light electrons falling to n=2 Rydberg formula (Balmer for nf = 2) : 1 / = R (1/nf 2 - 1/ni 2) R = Rydberg constant = 1. 097 x 107 m-1

The hydrogen atom

The hydrogen atom

Energy levels and transitions of the many-electron atom: Sodium Quantum states of the valence

Energy levels and transitions of the many-electron atom: Sodium Quantum states of the valence electron

The Bohr Model • • Classical physics predicts that the electron should spiral into

The Bohr Model • • Classical physics predicts that the electron should spiral into the nucleus Cannot explain emission spectra

The Bohr model: • The e- stays in certain stable orbits, emits no radiation

The Bohr model: • The e- stays in certain stable orbits, emits no radiation unless it jumps to a lower level • The angular momentum of the e- is quantized • the attaction between p and e- provides the centripetal acceleration n = principal quantum number

From Coulomb’s law, the force between the proton and electron is F = 1

From Coulomb’s law, the force between the proton and electron is F = 1 4 0 q 1 q 2 r 2 This is the centripetal force, Where q 1 = q 2 = e for the hydrogen atom mv 2 / r

So when the electron is in any energy level n: Bohr radius a 0

So when the electron is in any energy level n: Bohr radius a 0 = 0 h 2 / me 2 = 5. 29 x 10 -11 m KE of the electron in the nth level: Kn = 1/2 mv 2 PE of the electron in the nth level: Un = -1 4 0 Total energy En = Kn + Un = ? ? ? Compare to Rydberg formula! e 2 r

Reduced mass: the nucleus is not infinite in mass, Bohr model is off by

Reduced mass: the nucleus is not infinite in mass, Bohr model is off by 0. 1% m 1 m 2 mr = m 1 + m 2 isotopes

Ionized Helium is also a 1 -electron atom

Ionized Helium is also a 1 -electron atom

Why is the emission spectrum of ionized helium similar to that of hydrogen? 1.

Why is the emission spectrum of ionized helium similar to that of hydrogen? 1. Because hydrogen and helium are similar chemically 2. Because several of the energy levels of hydrogen and helium are the same 3. Because hydrogen and helium have similar atomic masses 4. It is a total coincidence

Energy Level Transitions Not Allowed • Continuum • Ionization • Differences between elements •

Energy Level Transitions Not Allowed • Continuum • Ionization • Differences between elements • isotopes

Stellar classification scheme

Stellar classification scheme

Is this star hotter or cooler than the Sun?

Is this star hotter or cooler than the Sun?

Spectrum of Arcturus

Spectrum of Arcturus

Luminosity The Hertzsprung. Russell diagram plots the luminosity vs. temperature of stars Temperature

Luminosity The Hertzsprung. Russell diagram plots the luminosity vs. temperature of stars Temperature

B - V is a measure of color: the smaller B-V, the hotter the

B - V is a measure of color: the smaller B-V, the hotter the star (magnitudes, remember!)

Lines in a star’s spectrum correspond to a spectral type that reveals its temperature

Lines in a star’s spectrum correspond to a spectral type that reveals its temperature (Hottest) O B A F G K M (Coolest)