Chapter 17 Lipids 17 3 Waxes Fats and
- Slides: 12
Chapter 17 Lipids 17. 3 Waxes, Fats, and Oils General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1
Waxes are § esters of saturated fatty acids and long-chain alcohols § coatings that prevent loss of water from leaves of plants General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2
Fats and Oils: Triacylglycerols Fats and oils are § also called triacylglycerols § esters of glycerol § produced by esterification § formed when the hydroxyl groups of glycerol react with the carboxyl groups of fatty acids General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 3
Triacylglycerols In a triacylglycerol, § glycerol forms ester bonds with three fatty acids General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 4
Formation of a Triacylglycerol Glycerol and three stearic acid molecules form a triacylglycerol named § glyceryl tristearate § tristearin General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 5
Olive Oil Olive oil § contains a high percentage of oleic acid, which is a monounsaturated fatty acid with one cis double bond General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6
Learning Check What are the fatty acids in the following triacylglycerol? General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7
Solution Stearic acid Oleic acid Myristic acid General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 8
Melting Points of Fats and Oils A triacylglycerol that is usually called a fat § is solid at room temperature § is prevalent in meats, whole milk, butter, and cheese A triacylglycerol that is usually called an oil § is liquid at room temperature § is prevalent in plants such as olive and safflower General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 9
Oils with Unsaturated Fatty Acids Oils § have more unsaturated fats § have cis double bonds that cause “kinks” in the fatty acid chains § cannot pack triacylglycerol molecules as close together as in fats § have lower melting points than do saturated fats § are liquids at room temperature General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10
Diagram of Triacylglycerol with Unsaturated Fatty Acids Unsaturated fatty acid chains have kinks that do not allow close packing. General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 11
Saturated and Unsaturated Fatty Acids In Fats and Oils General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 12
- Fats, oils, and waxes
- Fats, oils, and waxes
- Which biomolecule group includes fats oils and waxes
- Are fats and lipids the same thing
- Neutral fat
- Fats and lipids
- Lost wax technique dentistry
- Sticky wax uses
- Physical properties of gypsum products
- Phosphatylcholine
- Beading wax uses in dentistry
- Waxes
- Compound lipids