CHAPTER 11 Terpenes Learning outcomes Terpenes are unsaturated
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CHAPTER 11 Terpenes
Learning outcomes ¢ Terpenes are unsaturated compounds formed by joining together isoprene units. ¢ Terpenes are components of a wide variety of fruit and floral flavours and aromas. ¢ Terpene derivatives are responsible for the distinctive aroma of spices.
Terpenes ¢ The name ‘terpene’ is derived from the Greek word ‘terebinth’. ¢ Terebinth is a type of pine tree from which terpene-containing resins are obtained.
What are terpenes? ¢ Natural organic compounds. ¢ Components of a variety of fruit and floral flavours and aromas. ¢ Used in perfumes, essential oils and medicines.
Essential oils contain terpenes ¢ Lavender – used to relieve tension. ¢ Ylang-ylang – used to treat anxiety. ¢ Lemon oil – aids good circulation. ¢ Essential oils often contain a mixture of terpenes.
Spices contain terpenes ¢ Terpenes in plants can be oxidised to produce the compounds responsible for the distinctive aroma of spices. ¢ Terpenes containing oxygen or other functional groups are known as ‘terpenoids’. ¢ Common spices containing terpenes include cloves, cinnamon and ginger.
Terpenes are unsaturated ¢ Terpenes are unsaturated compounds. ¢ All terpenes are built up from units of isoprene.
Isoprene ¢ Isoprene is the common name for 2 -methylbuta-1, 3 -diene
Building terpenes from isoprene Isoprene units can be linked: ¢ head to tail to form linear terpenes ¢ in rings to form cyclic terpenes.
Isoprene
Head Tail Isoprene Head Tail
Head Tail Isoprene Head Tail
Classification of Terpenes Isoprene Carbon units atoms 1 Monoterpenes 2 10 2 Sesquiterpenes 3 15 3 Diterpenes 4 20 4 Sesterterpenes 5 25 5 Triterpenes 6 30 6 Carotenoids 8 40 7 Rubber > 100 > 500
The Isoprene Unit ¢ The isoprene units of myrcene are joined "head-to-tail. " head tail head
Representative Monoterpenes OH O H a-Phellandrene Menthol (eucalyptus) (peppermint) Citral (lemon grass)
Representative Monoterpenes OH O H a-Phellandrene Menthol (eucalyptus) (peppermint) Citral (lemon grass)
Representative Monoterpenes a-Phellandrene Menthol (eucalyptus) (peppermint) Citral (lemon grass)
Limonene – a cyclic terpene
Menthol – a cyclic terpenoid This terpene has been oxidised to a terpenoid
Representative Sesquiterpenes H a-Selinene (celery)
Representative Sesquiterpenes H a-Selinene (celery)
Representative Sesquiterpenes a-Selinene (celery)
a-Selinene – a cyclic terpene 3 isoprene units 15 carbon atoms
Representative Diterpenes OH Vitamin A
Representative Diterpenes OH Vitamin A
Representative Diterpenes Vitamin A
Diterpenes
Representative Triterpene tail-to-tail linkage of isoprene units Squalene (shark liver oil)
β-carotene – a linear terpene 8 isoprene units 40 carbon atoms
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