AN INTRODUCTION TO CARBOXYLIC ACIDS AND THEIR DERIVATIVES
AN INTRODUCTION TO CARBOXYLIC ACIDS AND THEIR DERIVATIVES KNOCKHARDY PUBLISHING 2015 SPECIFICATIONS
KNOCKHARDY PUBLISHING CARBOXYLIC ACIDS INTRODUCTION This Powerpoint show is one of several produced to help students understand selected topics at AS and A 2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board is available. Accompanying notes on this, and the full range of AS and A 2 topics, are available from the KNOCKHARDY SCIENCE WEBSITE at. . . www. knockhardy. org. uk/sci. htm Navigation is achieved by. . . either or clicking on the grey arrows at the foot of each page using the left and right arrow keys on the keyboard
CARBOXYLIC ACIDS CONTENTS • Structure of carboxylic acids • Nomenclature • Physical properties of carboxylic acids • Preparation of carboxylic acids • Chemical properties of carboxylic acids • Acyl chlorides • Esters • Triglycerides and fats • Biofuels
CARBOXYLIC ACIDS Before you start it would be helpful to… • Recall the definition of a covalent bond • Recall the difference types of physical bonding • Be able to balance simple equations • Be able to write out structures for simple organic molecules • Understand the IUPAC nomenclature rules for simple organic compounds • Recall the chemical properties of alkanes and alkenes
STRUCTURE OF CARBOXYLIC ACIDS • contain the carboxyl functional group COOH • the bonds are in a planar arrangement
STRUCTURE OF CARBOXYLIC ACIDS • contain the carboxyl functional group COOH • the bonds are in a planar arrangement • include a carbonyl (C=O) group a hydroxyl (O-H) group and
STRUCTURE OF CARBOXYLIC ACIDS • contain the carboxyl functional group COOH • the bonds are in a planar arrangement • include a carbonyl (C=O) group a hydroxyl (O-H) group • are isomeric with esters : - RCOOR’ and
HOMOLOGOUS SERIES Carboxylic acids form a homologous series HCOOH CH 3 COOH C 2 H 5 COOH
HOMOLOGOUS SERIES Carboxylic acids form a homologous series HCOOH CH 3 COOH C 2 H 5 COOH With more carbon atoms, there can be structural isomers C 3 H 7 COOH (CH 3)2 CHCOOH
INFRA-RED SPECTROSCOPY IDENTIFYING CARBOXYLIC ACIDS USING INFRA RED SPECTROSCOPY Differentiation ALCOHOL O-H absorption Compound O-H C=O ALCOHOL YES NO CARBOXYLIC ACID YES ESTER NO YES CARBOXYLIC ACID O-H + C=O absorption ESTER C=O absorption
NAMING CARBOXYLIC ACIDS Acids are named according to standard IUPAC rules • select the longest chain of C atoms containing the COOH group; • remove the e and add oic acid after the basic name • number the chain starting from the end nearer the COOH group • as in alkanes, prefix with alkyl substituents • side chain positions are based on the C in COOH being 1 e. g. CH 3 - CH(CH 3) - CH 2 - COOH is called 4 -methylpentanoic acid
NAMING CARBOXYLIC ACIDS Acids are named according to standard IUPAC rules • select the longest chain of C atoms containing the COOH group; • remove the e and add oic acid after the basic name • number the chain starting from the end nearer the COOH group • as in alkanes, prefix with alkyl substituents • side chain positions are based on the C in COOH being 1 METHANOIC ACID PROPANOIC ACID
NAMING CARBOXYLIC ACIDS Acids are named according to standard IUPAC rules • select the longest chain of C atoms containing the COOH group; • remove the e and add oic acid after the basic name • number the chain starting from the end nearer the COOH group • as in alkanes, prefix with alkyl substituents • side chain positions are based on the C in COOH being 1 BUTANOIC ACID 2 -METHYLPROPANOIC ACID
NAMING CARBOXYLIC ACIDS Acids are named according to standard IUPAC rules Many carboxylic acids are still known under their trivial names, some having been called after characteristic properties or their origin. Formula HCOOH CH 3 COOH C 6 H 5 COOH Systematic name methanoic acid benzenecarboxylic acid (trivial name) formic acid acetic acid benzoic acid origin of name latin for ant latin for vinegar from benzene
PHYSICAL PROPERTIES BOILING POINT Increases as size increases - higher induced dipole-dipole interactions 101°C 118°C 141°C 164°C
PHYSICAL PROPERTIES BOILING POINT Increases as size increases - higher induced dipole-dipole interactions 101°C 118°C 141°C 164°C Boiling point is higher for “straight” chain isomers. 164°C 154°C Greater branching = lower inter-molecular forces = lower boiling point
PHYSICAL PROPERTIES BOILING POINT Increases as size increases - higher induced dipole-dipole interactions Carboxylic acids have high boiling points for their relative mass The effect of hydrogen bonding on the boiling point of compounds of similar mass Compound ethanoic acid propan-1 -ol propanal butane Formula CH 3 COOH C 3 H 7 OH C 2 H 5 CHO C 4 H 10 Mr 60 60 58 58 b. pt. (°C) Comments 118 + h-bonding 97 + h-bonding 49 + permanent dipole-dipole - 0. 5 induced dipole-dipole
PHYSICAL PROPERTIES BOILING POINT Increases as size increases - higher induced dipole-dipole interactions Carboxylic acids have high boiling points for their relative mass • arises from inter-molecular hydrogen bonding due to polar O—H bonds HYDROGEN BONDING AN EXTREME CASE. . . DIMERISATION • extra inter-molecular attraction = more energy to separate molecules
PHYSICAL PROPERTIES SOLUBILITY • carboxylic acids are soluble in organic solvents • they are also soluble in water due to hydrogen bonding HYDROGEN BONDING
PHYSICAL PROPERTIES SOLUBILITY • carboxylic acids are soluble in organic solvents • they are also soluble in water due to hydrogen bonding HYDROGEN BONDING • small ones dissolve readily in cold water • as mass increases, the solubility decreases • benzoic acid is fairly insoluble in cold but soluble in hot water
PREPARATION OF CARBOXYLIC ACIDS Oxidation of aldehydes RCHO + [O] Hydrolysis of esters RCOOR + H 2 O Hydrolysis of acyl chlorides RCOCl + Hydrolysis of nitriles RCN Hydrolysis of amides ——> RCOOH + ROH H 2 O ——> RCOOH + HCl 2 H 2 O ——> RCOOH + NH 3 RCONH 2 + H 2 O ——> RCOOH + NH 3 +
CHEMICAL PROPERTIES ACIDITY weak acids RCOOH + H 2 O(l) RCOO¯(aq) + H 3 O+(aq) form salts RCOOH + Na. OH(aq) ——> RCOO¯Na+(aq) + H 2 O(l) 2 RCOOH + Mg(s) ——> (RCOO¯)2 Mg 2+(aq) + H 2(g)
CHEMICAL PROPERTIES ACIDITY weak acids RCOOH + H 2 O(l) RCOO¯(aq) + H 3 O+(aq) form salts RCOOH + Na. OH(aq) ——> RCOO¯Na+(aq) + H 2 O(l) 2 RCOOH + Mg(s) ——> (RCOO¯)2 Mg 2+(aq) + H 2(g) The acid can be liberated from its salt by treatment with a stronger acid. e. g. RCOO¯ Na+(aq) + HCl(aq) ——> RCOOH + Na. Cl(aq) Conversion of an acid to its water soluble salt followed by acidification of the salt to restore the acid is often used to separate acids from a mixture.
CHEMICAL PROPERTIES ACIDITY weak acids RCOOH + H 2 O(l) RCOO¯(aq) + H 3 O+(aq) form salts RCOOH + Na. OH(aq) ——> RCOO¯Na+(aq) + H 2 O(l) 2 RCOOH + Mg(s) ——> (RCOO¯)2 Mg 2+(aq) + H 2(g) The acid can be liberated from its salt by treatment with a stronger acid. e. g. RCOO¯ Na+(aq) + HCl(aq) ——> RCOOH + Na. Cl(aq) Conversion of an acid to its water soluble salt followed by acidification of the salt to restore the acid is often used to separate acids from a mixture. QUALITATIVE ANALYSIS Carboxylic acids are strong enough acids to liberate CO 2 from carbonates Phenols are also acidic but not are not strong enough to liberate CO 2.
ESTERIFICATION Reagent(s) alcohol + strong acid catalyst (e. g. conc. H 2 SO 4 ) Conditions reflux Product ester Equation e. g. CH 3 CH 2 OH(l) + CH 3 COOH(l) ethanol ethanoic acid CH 3 COOC 2 H 5(l) + H 2 O(l) ethyl ethanoate
ESTERIFICATION Reagent(s) alcohol + strong acid catalyst (e. g. conc. H 2 SO 4 ) Conditions reflux Product ester Equation Notes e. g. CH 3 CH 2 OH(l) + CH 3 COOH(l) ethanol ethanoic acid CH 3 COOC 2 H 5(l) + H 2 O(l) ethyl ethanoate Conc. H 2 SO 4 is a dehydrating agent - it removes water causing the equilibrium to move to the right and thus increases the yield of the ester
ESTERIFICATION Reagent(s) alcohol + strong acid catalyst (e. g conc. H 2 SO 4 ) Conditions reflux Product ester Equation e. g. CH 3 CH 2 OH(l) + CH 3 COOH(l) ethanol ethanoic acid CH 3 COOC 2 H 5(l) + H 2 O(l) ethyl ethanoate Notes Conc. H 2 SO 4 is a dehydrating agent - it removes water causing the equilibrium to move to the right and thus increases the yield of the ester Naming esters Named from the original alcohol and carboxylic acid CH 3 OH + CH 3 COOH from ethanoic acid CH 3 COOCH 3 + H 2 O CH 3 COOCH 3 METHYL ETHANOATE from methanol
CHLORINATION OF CARBOXYLIC ACIDS Chlorination involves replacing the OH with a Cl Product acyl chloride Reagent thionyl chloride SOCl 2 Conditions DRY conditions Equation CH 3 COOH Alternative method CH 3 COOH + PCl 5 + SOCl 2 ——> CH 3 COCl + phosphorus(V) chloride SO 2 + HCl POCl 3 + HCl
ACYL CHLORIDES Structure Replace the OH of a carboxylic acid with a Cl atom ETHANOYL CHLORIDE Nomenclature Named from corresponding acid … remove -ic add -yl chloride CH 3 COCl C 6 H 5 COCl ethanoyl (acetyl) chloride benzene carbonyl (benzoyl) chloride
ACYL CHLORIDES - PROPERTIES Physical • polar, colourless liquids which fume in moist air d+ dd-
ACYL CHLORIDES - PROPERTIES Physical • polar, colourless liquids which fume in moist air d+ dd- Chemical • attacked at the positive carbon centre by nucleophiles such as water, alcohols, ammonia and amines • undergo addition-elimination reactions • MUCH MORE REACTIVE THAN… CARBOXYLIC ACIDS AND ACID ANHYDRIDES
ACYL CHLORIDES - REACTIONS WATER Product(s) carboxylic acid + HCl Conditions cold water Equation CH 3 COCl(l) Mechanism addition-elimination (fume in moist air / strong acidic solution formed) + H 2 O(l) —> CH 3 COOH(aq) + HCl(aq)
ACYL CHLORIDES - REACTIONS WATER Product(s) carboxylic acid + HCl Conditions cold water Equation CH 3 COCl(l) Mechanism addition-elimination (fume in moist air / strong acidic solution formed) + H 2 O(l) —> CH 3 COOH(aq) + HCl(aq) ALCOHOLS Product(s) ester + hydrogen chloride Conditions reflux in dry (anhydrous) conditions Equation CH 3 COCl(l) + CH 3 OH(l) Mechanism addition-elimination —> CH 3 COOCH 3(l) + HCl(g)
ACYL CHLORIDES - REACTIONS AMMONIA Product(s) Amide + hydrogen chloride Conditions Low temperature and excess ammonia. Vigorous reaction. Equation CH 3 COCl(l) or Mechanism + NH 3(aq) —> CH 3 CONH 2(s) + HCl(g) CH 3 COCl(l) + 2 NH 3(aq) —> CH 3 CONH 2(s) + NH 4 Cl(s) addition-elimination
ACYL CHLORIDES - REACTIONS AMMONIA Product(s) Amide + hydrogen chloride Conditions Low temperature and excess ammonia. Vigorous reaction. Equation CH 3 COCl(l) or Mechanism + NH 3(aq) —> CH 3 CONH 2(s) + HCl(g) CH 3 COCl(l) + 2 NH 3(aq) —> CH 3 CONH 2(s) + NH 4 Cl(s) addition-elimination AMINES Product(s) N-substituted amide + hydrogen chloride Conditions anhydrous Equation CH 3 COCl(l) + C 2 H 5 NH 2(aq) —> CH 3 CONHC 2 H 5(s) + HCl(g) or CH 3 COCl(l) + 2 C 2 H 5 NH 2(aq) —> CH 3 CONHC 2 H 5(l) + C 2 H 5 NH 3 Cl(s) Mechanism addition-elimination
ESTERS Structure Substitute an organic group for the H in carboxylic acids Nomenclature first part from alcohol, second part from acid e. g. methyl ethanoate CH 3 COOCH 3 METHYL ETHANOATE ETHYL METHANOATE
ESTERS Structure Substitute an organic group for the H in carboxylic acids Nomenclature first part from alcohol, second part from acid e. g. methyl ethanoate CH 3 COOCH 3 METHYL ETHANOATE ETHYL METHANOATE Preparation From carboxylic acids, acyl chlorides and acid anhydrides Reactivity Unreactive compared with acids and acyl chlorides
ESTERS Structure Substitute an organic group for the H in carboxylic acids Nomenclature first part from alcohol, second part from acid e. g. methyl ethanoate CH 3 COOCH 3 METHYL ETHANOATE ETHYL METHANOATE Preparation From carboxylic acids, acyl chlorides and acid anhydrides Reactivity Unreactive compared with acids and acyl chlorides Isomerism Esters are structural isomers of carboxylic acids
STRUCTURAL ISOMERISM – FUNCTIONAL GROUP Classification Functional Group Name CARBOXYLIC ACID ESTER R-COOH R-COOR PROPANOIC ACID METHYL ETHANOATE Physical properties O-H bond gives rise to hydrogen bonding; get higher boiling point and solubility in water No hydrogen bonding insoluble in water Chemical properties acidic react with alcohols fairly unreactive hydrolysed to acids
PREPARATION OF ESTERS - 1 Reagent(s) alcohol + carboxylic acid Conditions reflux with a strong acid catalyst (e. g. conc. H 2 SO 4 ) Equation Notes e. g. CH 3 CH 2 OH(l) + CH 3 COOH(l) ethanol ethanoic acid CH 3 COOC 2 H 5(l) + H 2 O(l) ethyl ethanoate Conc. H 2 SO 4 is a dehydrating agent - it removes water causing the equilibrium to move to the right and thus increases the yield of the ester For more details see under ‘Reactions of carboxylic acids’
PREPARATION OF ESTERS - 2 Reagent(s) alcohol + acyl chloride Conditions reflux under dry conditons Equation Notes e. g. CH 3 OH(l) + CH 3 COCl(l) ——> CH 3 COOCH 3(l) + HCl(g) methanol ethanoyl methyl chloride ethanoate Acyl chlorides are very reactive but must be kept dry as they react with water.
PREPARATION OF ESTERS - 3 Reagent(s) alcohol + acid anhydride Conditions reflux under dry conditons Equation Notes e. g. CH 3 OH(l) + (CH 3 CO)2 O(l) ——> CH 3 COOCH 3(l) + CH 3 COOH(l) methanol ethanoic methyl ethanoic anhydride ethanoate acid Acid anhydrides are not as reactive as acyl chlorides so the reaction is slower. The reaction is safer - it is less exothermic. Acid anhydrides are less toxic.
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL HCOOH METHANOIC ACID ETHYL METHANOATE + C 2 H 5 OH ETHANOL
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL HCOOH METHANOIC ACID ETHYL METHANOATE METHYL ETHANOATE + C 2 H 5 OH ETHANOL
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL HCOOH + METHANOIC ACID C 2 H 5 OH ETHANOL ETHYL METHANOATE CH 3 COOH ETHANOIC ACID METHYL ETHANOATE + CH 3 OH METHANOL
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL The products of hydrolysis depend on the conditions used. . . acidic CH 3 COOCH 3 + H 2 O alkaline CH 3 COOCH 3 + Na. OH CH 3 COOH + CH 3 OH ——> CH 3 COO¯ Na+ + CH 3 OH
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL The products of hydrolysis depend on the conditions used. . . acidic CH 3 COOCH 3 + H 2 O alkaline CH 3 COOCH 3 + Na. OH CH 3 COOH + CH 3 OH ——> CH 3 COO¯ Na+ + CH 3 OH
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL The products of hydrolysis depend on the conditions used. . . acidic CH 3 COOCH 3 + H 2 O alkaline CH 3 COOCH 3 + Na. OH CH 3 COOH + CH 3 OH ——> CH 3 COO¯ Na+ + CH 3 OH If the hydrolysis takes place under alkaline conditions, the organic product is a water soluble ionic salt
HYDROLYSIS OF ESTERS Hydrolysis is the opposite of esterification ESTER + WATER CARBOXYLIC ACID + ALCOHOL The products of hydrolysis depend on the conditions used. . . acidic CH 3 COOCH 3 + H 2 O alkaline CH 3 COOCH 3 + Na. OH CH 3 COOH + CH 3 OH ——> CH 3 COO¯ Na+ + CH 3 OH If the hydrolysis takes place under alkaline conditions, the organic product is a water soluble ionic salt The carboxylic acid can be made by treating the salt with HCl CH 3 COO¯ Na+ + HCl ——> CH 3 COOH + Na. Cl
USES OF ESTERS Despite being fairly chemically unreactive, esters are useful as. . . • flavourings apple pear banana pineapple rum • solvents nail varnish remover - ethyl ethanoate • plasticisers 2 -methylbutanoate 3 -methylbutylethanoate 1 -methylbutylethanoate butylbutanoate 2 -methylpropanoate
TRIGLYCERIDES AND FATS Triglycerides • are the most common component of edible fats and oils • are triesters of the alcohol glycerol, (propane-1, 2, 3 -triol) and fatty acids a triglyceride glycerol
TRIGLYCERIDES AND FATS Triglycerides • are the most common component of edible fats and oils • are triesters of the alcohol glycerol, (propane-1, 2, 3 -triol) and fatty acids Saponification • alkaline hydrolysis of triglycerol esters produces soaps • a simple soap is the salt of a fatty acid • as most oils contain a mixture of triglycerols, soaps are not compounds • the quality of a soap depends on the oils from which it is made
FATTY ACIDS Carboxylic acids that are obtained from natural oils and fats; they can be… Saturated CH 3(CH 2)16 COOH octadecanoic acid (stearic acid)
FATTY ACIDS Carboxylic acids that are obtained from natural oils and fats; they can be… Saturated CH 3(CH 2)16 COOH octadecanoic acid (stearic acid) 9 Unsaturated CH 3(CH 2)7 CH=CH(CH 2)7 COOH octadec-9 -enoic acid (oleic acid) cis (Z) isomer trans (E) isomer
FATTY ACIDS Carboxylic acids that are obtained from natural oils and fats; they can be… Saturated CH 3(CH 2)16 COOH octadecanoic acid (stearic acid) 9 Unsaturated CH 3(CH 2)7 CH=CH(CH 2)7 COOH octadec-9 -enoic acid (oleic acid) cis (Z) isomer trans (E) isomer 12 9 CH 3(CH 2)4 CH=CHCH 2 CH=CH(CH 2)7 COOH octadec-9, 12 -dienoic acid (linoleic acid)
FATTY ACIDS AND HEALTH Saturated • • solids at room temperature found in meat and dairy products are bad for health increase cholesterol levels - can lead to heart problems
FATTY ACIDS AND HEALTH Saturated Mono unsaturated • • solids at room temperature found in meat and dairy products are bad for health increase cholesterol levels - can lead to heart problems • contain just one C=C • thought to be neutral to our health • found in olives, olive oil, groundnut oil, nuts, avocados
FATTY ACIDS AND HEALTH Saturated Mono unsaturated Poly unsaturated • • solids at room temperature found in meat and dairy products are bad for health increase cholesterol levels - can lead to heart problems • contain just one C=C • thought to be neutral to our health • found in olives, olive oil, groundnut oil, nuts, avocados • • are considered to be ‘good fats’ contain more than one C=C bond tend to be liquids at room temperature, eg olive oil. can be split into two main types. . . Omega 3 - fatty acids Omega 6 - fatty acids
FATTY ACIDS AND HEALTH Saturated Mono unsaturated Poly unsaturated • • solids at room temperature found in meat and dairy products are bad for health increase cholesterol levels - can lead to heart problems • contain just one C=C • thought to be neutral to our health • found in olives, olive oil, groundnut oil, nuts, avocados • • are considered to be ‘good fats’ contain more than one C=C bond tend to be liquids at room temperature, eg olive oil. can be split into two main types. . . Omega 3 - fatty acids Omega 6 - fatty acids
OMEGA 3 and 6 FATTY ACIDS Omega 3 - fatty acids W (omega) end lower the total amount of fat in the blood and can lower blood pressure and decrease the risk of cardiovascular disease 3 CH 3 CH 2 CH=CHCH 2 CH 2 CH=CH(CH 2)7 COOH The omega numbering system starts from the opposite end to the carboxylic acid group
OMEGA 3 and 6 FATTY ACIDS Omega 3 - fatty acids W (omega) end Omega 6 - fatty acids W (omega) end lower the total amount of fat in the blood and can lower blood pressure and decrease the risk of cardiovascular disease 3 CH 3 CH 2 CH=CHCH 2 CH 2 CH=CH(CH 2)7 COOH reduce the risk of cardiovascular disease but can contribute to allergies and inflammation 6 CH 3 CH 2 CH 2 CH=CHCH 2 CH=CH(CH 2)7 COOH
CHOLESTEROL • • • a fatty substance which is found in the blood it is mainly made in the body plays an essential role in how every cell in the body works eating too much saturated fat increases cholesterol levels too much cholesterol in the blood can increase the risk of heart problems
CHOLESTEROL • • • a fatty substance which is found in the blood it is mainly made in the body plays an essential role in how every cell in the body works eating too much saturated fat increases cholesterol levels too much cholesterol in the blood can increase the risk of heart problems Ways to reduce cholesterol levels • cut down on saturated fats and trans fats (trans fats are more stable and difficult to break down in the body) • replace them with monounsaturated fats and polyunsaturated fats • eat oily fish • have a high fibre diet; porridge, beans, fruit and vegetables • exercise regularly
BIOFUELS What are they? Liquid fuels made from plant material and recycled elements of the food chain Biodiesel An alternative fuel which can be made from waste vegetable oil or from oil produced from seeds. It can be used in any diesel engine, either neat or mixed with petroleum diesel. vegetable oil glycerol biodiesel It is a green fuel, does not contribute to the carbon dioxide (CO 2) burden and produces drastically reduced engine emissions. It is non-toxic and biodegradable.
BIOFUELS Advantages • • • renewable - derived from sugar beet, rape seed dramatically reduces emissions carbon neutral biodegradable non-toxic fuel & exhaust emissions are less unpleasant can be used directly in unmodified diesel engine high flashpoint - safer to store & transport simple to make used neat or blended in any ratio with petroleum diesel
BIOFUELS Advantages • • • renewable - derived from sugar beet, rape seed dramatically reduces emissions carbon neutral biodegradable non-toxic fuel & exhaust emissions are less unpleasant can be used directly in unmodified diesel engine high flashpoint - safer to store & transport simple to make used neat or blended in any ratio with petroleum diesel Disadvantages • poor availability - very few outlets & manufacturers • more expensive to produce • poorly made biodiesel can cause engine problems
BIOFUELS Advantages • • • renewable - derived from sugar beet, rape seed dramatically reduces emissions carbon neutral biodegradable non-toxic fuel & exhaust emissions are less unpleasant can be used directly in unmodified diesel engine high flashpoint - safer to store & transport simple to make used neat or blended in any ratio with petroleum diesel Disadvantages • poor availability - very few outlets & manufacturers • more expensive to produce • poorly made biodiesel can cause engine problems Future problems • • there isn’t enough food waste to produce large amounts crops grown for biodiesel use land for food crops a suitable climate is needed to grow most crops some countries have limited water resources
AN INTRODUCTION TO CARBOXYLIC ACIDS AND THEIR DERIVATIVES THE END © 2015 JONATHAN HOPTON & KNOCKHARDY PUBLISHING
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