An expert is someone who has made all
- Slides: 20
An expert is someone who has made all of the possible mistakes in a very narrow field of study – Niels Bohr
Nylons O O H 2 N - (CH 2)6 - NH 2 + HO - C - (CH 2)4 - C - OH Hexamethylene Diamine Adipic Acid O O H 2 N - (CH 2)6 - N - C - (CH 2)4 - C - OH + H 2 O Amide Group H
O - N - (CH 2)6 - N - C - (CH 2)4 - C H “I am making the announcement of a brand new chemical textile fiber ---derivable from coal, air and water -- and characterized by extreme toughness and strength --” Charles Stine V. P. for research, Du Pont, 1938 6 H Nylon 6, 6 O 6 n
Nylon “I am making the announcement of a brand new chemical textile fiber ---derivable from coal, air and water -- and characterized by extreme toughness and strength --” Charles Stine V. P. for research, Du Pont, 1938
Nylon May 15 1940 - “Nylon Day” Four million pairs go on sale throughout US Supply exhausted in 4 days.
Nylon Parachute WWII
Post WWII stocking sale, San Francisco
Polyurethanes Reaction does not involve splitting out of a small molecule O = C = N - (CH 2)6 - N = C = O + HO - (CH 2)2 - OH Hexamethylene Diisocyanate Ethylene Glycol O O = C = N - (CH 2)6 - N - C - O - (CH 2)2 - OH H usw. Urethane Linkage
Linear & branched polymers ex: polyethylene Linear Branched - short branches
Linear & branched polymers ex: polyethylene CH 2 - CH 2 ~~~CH 2 - CH CH 2. CH H 2 CH 2 - CH 2 ~~~CH 2 - CH CH 2 H Formation of short chain branches in polyethylene CH 2 = CH 2 C 4 H 9 - - ~~~CH 2 - CH 2 - CH 2 = CH 2
Low density polyethylene (LDPE) (short branches)
Other types of branching short long star Branching suppresses or prevents chain movement & "crystallization" in polymers
Branching Another way to make chains branch Use multifunctional (f>2) monomers OH OH * * CH 2 + CH 2 O OH CH 2 OH * CH 2 OH OH
The phenol + formaldehyde rxn
Network formation Further reaction under heat & pressure builds up densely cross-linked network. This is Bakelite, a thermosetting polymer. Once reaction is complete, material cannot be reheated and/or reformed Bakelite
Bakelite - Material of a Thousand Uses Clear Bakelite items Bakelite camera Phenolic resin/celluloid clock Bakelite telephone Bakelite radio Bakelite microphone
Crosslinking Take linear polymer chains & link using covalent bonds
Crosslinking Ex: rxn of natural rubber or poly(isoprene) CH - CH 2 CH - 2 - 2 -C=C CH 3 H - - - CH 2 - - with sulfur - interconnects the chains by reacting with the double bonds (vulcanization)
Crosslinking
Assignment: Review today's classnotes a. nylons b. polyurethanes c. branching d. networks e. Bakelite f. crosslinking g. vulcanization Read: chapter 14
- Evening standard cartoon
- Uses of bakelite
- Genesis 41 50 52
- Someone made this antique table in 1734
- Opposite rays
- It's all fun and games until someone loses an i
- I'm a perfect example of someone who has math anxiety
- Analysis/solution mindset
- When someone has been drinking they may drive poorly
- Epilepsy
- Find someone who kids
- Saying exactly what someone has said is called
- 適配度指標
- All matter
- All matter is made up of
- Slave to myself
- All matter is made up of
- Nuclear fission
- If the law has made you a witness
- A square plate made of lead has an oval shaped hole
- He has made us kings and priest