Aldehyde and Ketone Reactions Review Oxidation Reaction 8 Slides: 12 Download presentation Aldehyde and Ketone Reactions • • Review - Oxidation Reaction: 8. Oxidation primary alcohol --> aldehyde 9. Oxidation secondary alchol --> ketone 10. Oxidation aldehyde --> acid New Reactions: 6. Reduction: aldehyde + hydrogen --> pri. Alcohol. 6. Reduction: ketone + hydrogen --> sec. Alcohol 14. Hemiacetal Synthesis: alcohol + aldehyde or ketone --> hemiacetal • 15. Acetal Synthesis: hemiacetal + alcohol --> acetal Aldehyde and Ketone Reactions Aldehyde and Ketone Reactions • Reduction: aldehyde + hydrogen --> pri. Alcohol • Form of addition reaction. Reduction: aldehyde + hydrogen • Break hydrogen bond Reduction: aldehyde + hydrogen • Break double bond and use electrons to bond with hydrogen. Reduction: aldehyde + hydrogen • Brief Method Hemiacetal and Acetal Functional Groups • Hemiacetal: alcohol and ether on same carbon • Acetal: Two ethers on same carbon Hemiacetal Synthesis: aldehyde + hydrogen • • Alcohol + aldehyde --> hemiacetal Ethanal + methanol Alcohol oxygen becomes an ether Carbon double bond oxygen becomes an alcohol Synthesis of Acetal Functional Group • Acetal: alcohol plus hemiacetal (ether synthesis) • Acetal: Two ethers on same carbon Aldehyde and Ketone Reactions Aldehyde and Ketone Reactions Hemiacetal and Acetal Reactions • Ques. 13: Complete the following reactions: Oxidation of ketonesPolyhydroxy aldehyde and ketoneAldehyde and ketone solubility in waterKetone vs aldehydeAldehyde and ketone solubility in waterCarbonyl group aldehyde and ketoneOksidasi aldehidDifference between ketone and aldehydeChemical properties of aldehydes and ketonesButansäureethylester strukturformelChiral moleculesBenzaldehyde aldehyde or ketoneAldehyd keton unterschied