3 Novec 1230 Fire Protection Fluid 3 Novec

3 Novec™ 1230 Fire Protection Fluid

3 Novec™ 1230 Fire Protection Fluid

3 Novec™ 1230 Fire Protection Fluid

3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ 1230 Fire Protection Fluid Sustainable technology for special hazards A new opportunity from 3 M 3 Novec™ 1230 Fire Protection Fluid

Market Definition: “For fire protection of special hazards” • High value • Must continue operations • Life safety is paramount – Including emergency phones & control centers – Area protected is usually occupied • Must be a clean agent 3 Novec™ 1230 Fire Protection Fluid

A Breakthrough in Fire Protection Science C F O C 6 Fluoroketone 3 Novec™ 1230 Fire Protection Fluid

Introduction to 3 M 3 Novec™ 1230 Fire Protection Fluid

Global Focus • Operations in more than 60 countries • Sales in nearly 200 countries • 50%+ of sales • 50% of employees 3 Novec™ 1230 Fire Protection Fluid

3 M Facts Year-end 2001 Sales Worldwide. . . . . $16. 1 billion International (53% of total). . …. . $8. 5 billion Earnings Net income. . . …. . . $1. 7 billion Contributions • 3 M and 3 M Foundation More than $47 million 3 M Performance Initiative • Six Sigma R&D Expenditures • 3 M Acceleration For 2001. . . ……. . . $1. 1 billion Total last 5 years…. . $5. 27 billion • e. Productivity Employees • Sourcing Effectiveness • Indirect-cost Control Worldwide…. . . 71, 669 United States……. . 36, 102 3 Novec™ 1230 Fire Protection Fluid

3 M Brands 3 Novec™ 1230 Fire Protection Fluid

3 M Performance Materials Division Paints, Coatings, Construction & Consumer Oil, Gas & Mining Electronic Materials 3 Novec™ 1230 Fire Protection Fluid

3 M Performance Materials Division Government/ Polymer. Commercialization Melt Additives Polymer Melt Additives Transportation Commercialization Transportation NEW 3 M™ Novec™ 1230 Fire Protection Fluid 3 Novec™ 1230 Fire Protection Fluid

General Properties 3 Novec™ 1230 Fire Protection Fluid

The “Next Generation” Halon Replacement Meeting industry concerns for safety, performance and the environment § Zero Ozone Depletion Potential § Very low GWP / Short atmospheric lifetime § Low toxicity § Effective for flooding & streaming § Safe for sensitive, valuable assets 3 Novec™ 1230 Fire Protection Fluid

The long-term, sustainable solution 3 Novec™ 1230 Fire Protection Fluid

Novec™ 1230 Fluid Safety Margin 3 Novec™ 1230 Fire Protection Fluid

Performance Tests NAWC China Lake, California USA Novec 1230 HFC-236 fa 3 Novec™ 1230 Fire Protection Fluid

UL/FM Flooding Application Approval Tests Under-floor 3 Novec™ 1230 Fire Protection Fluid

UL/FM Flooding Application Approval Tests Large Room 3 Novec™ 1230 Fire Protection Fluid

Easy to fill, easy to transport • Boiling point 49ºC (Liquid @ room temp. ) • Can be shipped by air • Low vapor pressure • Simple fill station requirements • Multiple uses (includes streaming & flooding) 3 Novec™ 1230 Fire Protection Fluid

Cylinders needed for typical Class A System Halon 1301 HFC-227 ea Novec 1230 3 Novec™ 1230 Fire Protection Fluid

Cylinders needed for typical Class B System Halon 1301 HFC-227 ea Novec 1230 3 Novec™ 1230 Fire Protection Fluid

Compatible with fire system materials • Non-corrosive • Long term (12 week, six month) tests complete • Testing with plastics in process • Not for use with fluoroelastomers 3 Novec™ 1230 Fire Protection Fluid

Compatible with fire system materials Cray super computer 3 Novec™ 1230 Fire Protection Fluid

Regulatory Status ü USA TSCA registration complete SNAP: free to sell for streaming and flooding (Awaiting final publication) ü Europe ELINCS registered ü Canada Notified to CEPA Q 1/2002 ü Korea Registered ü Australia Estimated Q 2/2002 ü Japan Estimated Q 4/2002 ü China Complete 3 Novec™ 1230 Fire Protection Fluid

Sales & Marketing Support 3 Novec™ 1230 Fire Protection Fluid

Leveraging the 3 M & Novec brands The 3 M brand stands for… • Innovative, quality products and services that make your life easier; a company you can trust The Novec brand stands for… • Safe, effective, sustainable, environmentally responsible solutions 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products General Brochure 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products Sales Bulletin 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products Public Relations 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products Technical Papers 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products Trade Ad 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ Branded Products Electronic Newsletter 3 Novec™ 1230 Fire Protection Fluid

Focus Group Research Participants Oct. 19, 2001 • Loss Prevention Specialist • Fire Protection Engineer • Insurance Administrator • Security & Safety Manager • Facilities Manager • Others • VP of Worldwide Operations • Facilities & Business Contract Manager • Chief Building Engineer 3 Novec™ 1230 Fire Protection Fluid

Typical Comments On the value of the environmental benefits: “Even if (the system) was a little more expensive, it would be acceptable, just because of the environmental issues. ” “From a PR standpoint, anything we can do to demonstrate that we are a ‘green’ company is helpful. ” 3 Novec™ 1230 Fire Protection Fluid

Typical Comments Will the 3 M Brand help sell the system? “Yes…you want to know when you call for service, the company will be there; that they’re responsive; that they’ll back the product. ” “And, is this company going to be around 10 years from now? ” 3 Novec™ 1230 Fire Protection Fluid

Typical Comments On the properties of Novec 1230: “Very good…cylinder space is the same as FM-200, instead of over 7 times as much, as inert gas is. Design concentration about 5% and toxicity is 10%. That’s very good. ” “Low design concentration is nice. You almost have a two times safety factor. ” 3 Novec™ 1230 Fire Protection Fluid

Typical Comments How interested are you in learning more? “On a scale of 1 to 10, I’d definitely say 10. ” “It sounds very compelling. Now show me the numbers. ” “I’ll probably be contacting my research scientists tomorrow to look into this. ” 3 Novec™ 1230 Fire Protection Fluid

Typical Comments On sustainability: “One of the issues is…you may have an agent that’s legal today, but 10 years from now it might not be. ” 3 Novec™ 1230 Fire Protection Fluid

Typical Comments On priorities when selecting a system: “Protecting assets and our employees. Those are paramount. ” 3 Novec™ 1230 Fire Protection Fluid

Telling the environmental story 3 Novec™ 1230 Fire Protection Fluid

Environmental Properties • Zero Ozone Depletion Potential • Atmospheric lifetime of 5 days • Global Warming Potential of 1 (100 year ITH) • Ultimate Environmental Degradation Products are CO 2, HF and TFA 3 Novec™ 1230 Fire Protection Fluid

Fluorochemicals & the environment Environmental Persistence Cl + O 3 Atm. Lifetime + IR Absorbance Ozone Depletion Climate Change 3 Novec™ 1230 Fire Protection Fluid

Fluorochemicals containing Cl or Br Potential contributors to ozone depletion R-Cl + hn R • + Cl • (l<260 nm) O 3 + Cl • Cl. O • + O 2 + hn O + O 2 Cl • + O 2 (l<1140 nm) Cl. O • + O § F has a catalytic efficiency <10 -4 that of Cl (<10 -5 Br) § Compounds containing only F are considered nonozone depleting § Novec 1230 fluid is non-ozone depleting 3 Novec™ 1230 Fire Protection Fluid

Atmospheric Residence Time Controlling Factors Oxidation Rain Out Photolysis Reactivity with Hydroxyl Radical Novec 1230 fluid is unreactive w/ • OH Water Solubility Novec 1230 fluid is water insoluble (~1 ppmw) UV Absorbance Novec 1230 fluid has strong absorbance in the near UV 3 Novec™ 1230 Fire Protection Fluid

UV Absorbance Novec 1230 fluid vs. non-fluorinated ketones 3 Novec™ 1230 Fire Protection Fluid

Penetration of Solar Radiation 3 Novec™ 1230 Fire Protection Fluid

UV Absorbance Novec 1230 fluid compared to various light sources 3 Novec™ 1230 Fire Protection Fluid

Photolysis of Novec 1230 fluid C 2 F 5 C(O)CF(CF 3)2 24 hours exposure to 6500 W Xenon Arc using borosilicate glass filter (Artificial sunlight via ASTM G 26 light source) Equivalent to approximately 3 days of natural sunlight 69 % decomposed 3 Novec™ 1230 Fire Protection Fluid

Photolysis of Novec 1230 fluid C 2 F 5 C(O)CF(CF 3)2 Relative rate experiments using Xenon UV lamp with lime glass filter Acetaldehyde, which has 5 day atmospheric lifetime via photolysis used as reference Photodissociation rate of Novec 1230 fluid comparable to Acetaldehyde Atmospheric Lifetime of Novec 1230 fluid is 5 days 3 Novec™ 1230 Fire Protection Fluid

Infrared Cross-Section of Novec 1230 fluid 3 Novec™ 1230 Fire Protection Fluid

Global Warming Potential (GWP) § § Calculated using WMO 1998 method Basis of 1 kg of compound x released Calculated over a specified integration time horizon (ITH) Result is equivalent number of kg of CO 2 released Results for Novec 1230 fluid GWP 20 yr ITH 4 100 yr ITH 1 500 yr ITH 0 3 Novec™ 1230 Fire Protection Fluid

GWP of Various Compound CO 2 N 2 O CH 4 CF 3 CH 2 F (HFC-134 a) CF 3 CFHCF 3 (HFC-227 ea) CF 3 H (HFC-23) C 2 F 6 C 3 F 8, C 4 F 10, C 6 F 14 SF 6 C 4 F 9 OCH 3 (HFE-7100) C 4 F 9 OC 2 H 5 (HFE-7200) C 2 F 5 C(O)CF(CF 3)2 GWP (100 Yr ITH) 1 Naturally occurring 296 compounds 23 1, 300 3, 500 HFCs 12, 000 11, 900 PFCs 8, 600 - 9, 000 22, 200 320 HFEs 55 1 Novec 1230 fluid 3 Novec™ 1230 Fire Protection Fluid

Atmospheric Degradation Pathways Novec 1230 fluid C 2 F 5 C(O)CF(CF 3)2 (lmax=306 nm) hn (days) • C 2 F 5 C(O) O 2 3 CO 2 + 5 HF + • CF(CF 3)2 O 2 (ms to weeks) CF 3 • + CF 3 CF(O) H 2 O CO 2 + 3 HF CF 3 COOH + HF 3 Novec™ 1230 Fire Protection Fluid

Environmental Footprint Comparison Global Warming Potential Halogenated Compounds 10000 HFC-236 fa 9000 8000 halon 1301 7000 6000 5000 4000 HFC 227 ea 3000 2000 0 halon 1211 1000 0 Novec 1230 0 Ozone Depletion Potential Area of the circle is proportional to the atmospheric lifetime of the compound. 3 Novec™ 1230 Fire Protection Fluid

System Design Considerations 3 Novec™ 1230 Fire Protection Fluid

Typical Physical Properties Chemical formula CF 3 CF 2 C(O)CF(CF 3)2 Molecular weight 316. 04 Boiling point @ 1 atm 49ºC (120. 2º F) Freezing point -108ºC (-162. 4ºF) Density, sat. Liquid @ 25ºC 1. 60 g/ml (99. 9 lbm/ft 3) Density, gas 1 ATM @ 25ºC 0. 0184 g/ml (1. 15 lbm/ft 3) Specific volume, 1 ATM @ 25ºC 0. 0543 m 3/kg (0. 870 ft 3/lb) Liquid viscosity @ 25ºC 0. 41/0. 56 centistokes Heat of vaporization @ BP 88. 1 k. J/kg (37. 9 BTU/lb) Solubility of H 20 in Novec 1230 @ 25ºC <0. 001% by wt. Vapor pressure @ 25ºC 0. 40 bar (5. 87 psig) Dielectric strength (dry conditions) ~60 k. V 3 Novec™ 1230 Fire Protection Fluid

Elastomer Compatibility Novec 1230 fluid is compatible with normal materials of construction 3 Novec™ 1230 Fire Protection Fluid

Metals Compatibility Effects of Boiling C 6 F-ketone on Various Metals Product C 6 F-ketone Boiling Point (49°C) Metals (10 days minimum exposure) Aluminum Alloy 6262 T 6511 A* Brass Alloy UNS C 36000 A AISI Type 304 L stainless steel A AISI Type 316 L stainless steel A Copper UNS C 12200 A ASTM A 516, Grade 70 carbon steel A * A= no discoloration or destruction of fluid or metal at temperature indicated 3 Novec™ 1230 Fire Protection Fluid

Standard UL/FM ISO Test Enclosures 3 M Fire Test Facility, Mendota Heights MN 3 Novec™ 1230 Fire Protection Fluid

Flooding Opportunity Can Novec 1230 fluid be made to flood? The answer is… …Yes! 3 Novec™ 1230 Fire Protection Fluid

3 M™ Novec™ 1230 Fire Protection Fluid Design parameters expected to be achieved § Max fill density >1. 0 kg/l (61 lb/ft 3) § Min nozzle pressure < 7 bar (100 psig) § Max discharge Standard UL 10 sec § Min temperature condition 0º C (32º F) § Min extinguishing concentration 4 -6% v/v 3 Novec™ 1230 Fire Protection Fluid

Packaging • 5 kg (11 lb) 1 gal glass jug • 160 kg (353 lb) 30 gal lined drum • 1, 200 kg (2645. 5 lb) 220 gal HDPE ICB • 18, 000 kg (39, 600 lb) ISO (Future) 3 Novec™ 1230 Fire Protection Fluid

Sustainable Technology For special hazards • Addresses environmental concerns: Zero ODP, GWP of 1, Atmospheric Lifetime of 5 days • Safe for people—up to 150% margin of safety • Fast, effective extinguishment for flooding and streaming • Allows efficient use of space • Easy to handle: compact, low-pressure, easily transportable • Global regulatory approvals • Leverages the power of the 3 M and Novec brands • 3 M technical and marketing support 3 Novec™ 1230 Fire Protection Fluid

Thank you for your interest! 3 Novec™ 1230 Fire Protection Fluid

Gas/Aqueous-Phase Distribution in the Atmosphere A(g) A(aq) Henry’s Constant (HA) = [A(aq)] / p. A • For compounds with HA < 400 M/atm, < 1% dissolve into aqueous phase • A significant fraction of a compound ( > 10%) partitions into the aqueous phase only if HA > 5000 M/atm • HA of Novec 1230 fluid ~ 8 x 10 -6 M/atm • As a result, rainout is not a significant removal mechanism for Novec 1230 fluid 3 Novec™ 1230 Fire Protection Fluid